Salt Synthesis(盐合成)研究综述
Salt Synthesis 盐合成 - To mitigate these technical challenges, we utilize molten-salt synthesis based on alkali metal iodide. [1] 01Eu3+ phosphors were synthesized by molten-salt synthesis (MSS) process at 700°C for 3 h using NaCl and KCl as the reaction medium. [2] Experimental results of polymer-salt synthesis of Yb:YAG nanopowders and analysis of their structure and luminescent properties are presented. [3] Here we show that dopants traditionally used for modifying crystal lattices can also function as growth mediators in molten-salt synthesis by altering the surface energy and thus the nucleation barrier and the critical nuclei size. [4] This research work presents the preparation of TiB2 nanopowders by molten-salt synthesis (MSS) technique from TiO2 and MgB2 as starting active materials and MgCl2 as a molten salt. [5] One of the interesting synthesis methods which may be used for manufacturing either fine ceramic powders [4] or even single crystals is molten-salt synthesis. [6] Lanthanide pyrogermanates of general formula Ln2Ge2O7 (Ln = Tb, Dy, Ho, Er) were synthesized by molten-salt synthesis. [7] In this study, we investigate the process of synthesis, crystal structure stabilization, and phase transition in a series of RE hafnate compounds, synthesized by the coprecipitation process of a single-source complex hydroxide precursor followed with direct calcination or molten-salt synthesis (MSS) method. [8]为了缓解这些技术挑战，我们利用基于碱金属碘化物的熔盐合成。 [1] 01Eu3+ 荧光粉采用熔盐合成 (MSS) 工艺在 700°C 下合成 3 小时，使用 NaCl 和 KCl 作为反应介质。 [2] 介绍了 Yb:YAG 纳米粉末的聚合物盐合成实验结果及其结构和发光性能分析。 [3] 在这里，我们展示了传统上用于修饰晶格的掺杂剂也可以通过改变表面能，从而改变成核势垒和临界核尺寸，在熔盐合成中充当生长介质。 [4] 本研究工作介绍了 TiB2 纳米粉体的制备方法 以 TiO2 和 MgB2 为起始活性物质的熔盐合成 (MSS) 技术 材料和 MgCl2 作为熔盐。 [5] 可用于制造精细陶瓷粉末 [4] 甚至单晶的有趣合成方法之一是熔盐合成。 [6] 通过熔盐合成法合成了通式Ln2Ge2O7（Ln=Tb、Dy、Ho、Er）的镧系元素焦锗酸盐。 [7] 在这项研究中，我们研究了一系列稀土铪酸盐化合物的合成、晶体结构稳定和相变过程，这些化合物是通过单源复合氢氧化物前体的共沉淀过程，然后直接煅烧或熔盐合成（MSS ） 方法。 [8]
Molten Salt Synthesis 熔盐合成
, nanocubes, nanocuboids, and quasi-nanospheres, were prepared via a facile molten salt synthesis method. [1] Furthermore, with the incorporation of electrochemical technology, molten salt synthesis of porous carbon has become flexible and diversiform. [2] TaB2 nanopowder has been prepared by the molten salt synthesis (MSS) technique. [3] In this paper, potassium titanate whiskers was prepared via the Molten salt synthesis on the surface of cordierite ceramics for the regeneration of diesel particulate filters (DPFs). [4] For the successful molten salt synthesis of La0. [5] In this article, we report simple and scalable one-pot molten salt synthesis of CoFe2O4 as electrode material for Lithium ion batteries. [6] 5Nb2O6 nanorods fabricated by a molten salt synthesis method. [7] 16 times higher than that of molten salt synthesis of carbon nitride (MS-CN), even 14. [8] Herein, we employ density functional theory to examine the impact of growth media on NiO crystal faceting in line with experimental findings showing that molten salt synthesis in alkali chlorides (KCl, LiCl, and NaCl) imposes shape selectivity of NiO particles. [9] Here, we have employed the strategy of combining rare earth ion Tb3+ and transition metal ion Mn3+ with completely different thermal-quenching behaviors to obtain high thermometric sensitivity using uniform La2Zr2O7:Tb3+,Mn3+ nanoparticles (NPs) synthesized by a molten salt synthesis method. [10] In the present work, Magnesium Nickel Oxide (MgNiO₂) solid solution is prepared by molten salt synthesis. [11] In this work, we have synthesized Lu2Hf2O7 (LuHO) and Lu2Hf2O7:Eu3+ (LuHOE) nanocrystals (NCs) using a molten salt synthesis and confirmed that both are stabilized in defect fluorite structure with a high degree of structural disordering. [12] Here in this work, we have designed Gd2Hf2O7 nanocrystals (NCs) and co-doped them with Yb3+-Er3+ (GHO-YE) and Yb3+-Tm3+ (GHO-YT) using a molten salt synthesis. [13] The molten salt synthesis is the common simple method to obtain that unique morphology. [14] The present article reviews four promising mild condition ammonia production methods: solid state synthesis, molten salt synthesis, thermochemical looping and photocatalytic routes. [15] The innovative molten salt synthesis approach proposed in this work provides exceptionally pure Na2Ti6O13 nanorods generated at 900–1100 °C in a yield ≥80 wt%. [16] In an effort to overcome this challenge, porous chromium carbide/carbon biomorphic ceramics were prepared via molten salt synthesis at as low as 700 °C by using Cr as metal source and pinewood derived porous carbon material as template. [17] Anisometric Na2Nb8O21 particles were synthesized by a molten salt synthesis (MSS). [18] Molten salt synthesis was applied in the preparation of capacitive porous carbon. [19] Molten salt synthesis afforded single phase Gd2TiO5 at 1300 °C in 2 h, via a template growth mechanism, and is effective for the synthesis of these refractory materials. [20] This study reports the statistical optimization using surface response methodology and genetic algorithms of an auto-ignited microwave molten salt synthesis of multiphase calcium phosphates, as these molecular mixtures integrate both osteoconductive and osteoinductive properties with a good capacity to control biodegradation. [21] Among them, the KSN microcrystalline were fabricated by the molten salt synthesis, which had many K+/Sr2+ vacancies. [22] Large-size Ca3Co4O9 microplates in the range of 10 μm to 18 μm, were prepared by using molten salt synthesis method. [23] Molten salt synthesis is an efficient method for preparation of photocatalyst. [24] Herein, a facile and scalable strategy combining molten salt synthesis and self-initiated polymerization is developed to in-situ generate a thin layer of polypyrrole onto the surface of MnO2/Mn2O3 nanocomposite, aiming to resolve the problems mentioned above. [25] In this work, we present a facile and effective one-step molten salt synthesis tactics to prepare self-supported 1D Ni-Mo based mixed-phase polyionic compounds nanorod arrays (NMNAs). [26] Herein, a lanthanide tetraboride nanocrystal powder CeB4 with an average particle size of 50 nm synthesized for the first time via inorganic molten salt synthesis route using cerium fluoride (CeF3) and sodium borohydride (NaBH4) as the cerium and boron precursors in argon atmosphere exhibits good performance for the adsorption of CR. [27] Plate-like Ca3Co4O9 microcrystal particles were synthesized by molten salt synthesis. [28] There is progressive decrease in luminescence output and quantum yield as the coprecipitation pH is raised to prepare the single-source precursors for the molten salt synthesis of the NPs. [29] 5Nb2O9) with different structures (perovskite, tetragonal tungsten bronze-TTB, bismuth niobates layer structure-BNLS) have been synthesized by using the one dimensional Nb2O5 as precursor through topochemical molten salt synthesis (TMSS) method. [30] CeF3 and CeF3:Tb3+ particles have been successfully synthesized in a low temperature by the facile molten salt synthesis (MSS) method using NaNO3 and KNO3 as the reaction medium. [31] In this work, BaZrO3 (BZO) crystals with different sizes were synthesized using a molten salt synthesis method at four annealing temperatures. [32] A-site complex perovskite (Ba, Sr)TiO3 microplatelets with high aspect ratio were synthesized successfully by molten salt synthesis (MSS) and topochemical microcrystal conversion(TMC) technique. [33] By reaction of PbC2O4 and TiO2 in the eutectic NaCl-KCl salts, both sphere- and rod-like PbTiO3 (PTO) powders were synthesized via molten salt synthesis (MSS) and template MSS methods, respectively. [34] C-axis preferentially and randomly oriented Bi4NdTi3FeO15 (BNTF) ceramics were prepared by molten salt synthesis and conventional solid-state reaction methods, respectively. [35] Molten salt synthesis is a simple process, which uses low temperatures and short reaction times to obtain synthesized powders with uniform chemical composition as well as good crystal morphology and high-phase purity. [36] 9)O3] (BCZT) crystals by molten salt synthesis (MSS) method and the influence of MSS process parameters on the morphology, phase structure, dielectric and ferroelectric properties of BCZT ceramic have been reported in this investigation. [37] Common preparation methods of manganese-based Li-rich layered oxides include co-precipitation, combustion, spray pyrolysis, and molten salt synthesis. [38] In the study, ZrC-coated flake graphite was prepared by molten salt synthesis and added to the Al2O3-C refractory. [39] Here, we have explored the structural and optical properties of the NZO NPs synthesized by a molten salt synthesis method. [40] We report the synthesis of highly ordered and nanostructured h-BN at 1000 °C using molten salt synthesis. [41] The influence of reaction conditions including reaction temperature, reaction duration, and molar ratio of reactants on the morphology of products was systematically investigated, in order to prepare potassium hexatitanate (K2Ti6O13) whiskers with uniform morphology and high crystallinity by molten salt synthesis toward industrial applications. [42] LaMn1-xFexO3 perovskites were successfully synthesized via molten salt synthesis in NaCl-KCl and LiCl-KCl, for the first time. [43] Herein, the phase evolution of the calcia-alumina system via molten salt synthesis is reported as a function of the synthesis temperature and the atmospheric environment. [44] In this work, a highly crystallized lithium chloride-intercalated graphitic carbon nitride (LiCl-CN) material was fabricated through well-controlled molten salt synthesis. [45] Herein, Sr2NaNb5O15 (SNN) ceramics with a filled tungsten bronze structure were synthesized by the various methods of conventional mixed-oxide (CMO), two-step sintering (TSS), reactive sintering (RS) and molten salt synthesis (MSS). [46] A series of soft magnetic nickel ferrite (NiFe2O4) samples were successfully synthesised at 1000 °C over a period of 2 h through the molten salt synthesis method using iron oxide red as iron-bearing raw materials. [47] SrBi2NbO9 compounds were prepared through three methods: oxalate co-precipitation, molten salt synthesis and polymerizable complex. [48]，通过简便的熔盐合成方法制备了纳米立方体、纳米立方体和准纳米球。 [1] 此外，随着电化学技术的结合，多孔碳的熔盐合成变得灵活多样。 [2] 采用熔盐合成（MSS）技术制备了TaB2纳米粉体。 [3] 在本文中，通过在堇青石陶瓷表面上的熔盐合成制备钛酸钾晶须，用于柴油微粒过滤器（DPF）的再生。 [4] 为成功合成 La0 的熔盐。 [5] 在本文中，我们报告了简单且可扩展的一锅法合成 CoFe2O4 作为锂离子电池电极材料的熔盐。 [6] 采用熔盐合成法制备的 5Nb2O6 纳米棒。 [7] 比熔盐合成氮化碳（MS-CN）高16倍，甚至14倍。 [8] 在这里，我们采用密度泛函理论来检查生长介质对 NiO 晶面的影响，这与实验结果一致，表明在碱金属氯化物（KCl、LiCl 和 NaCl）中合成熔盐会施加 NiO 颗粒的形状选择性。 [9] 在这里，我们采用将具有完全不同热猝灭行为的稀土离子 Tb3+ 和过渡金属离子 Mn3+ 相结合的策略，使用通过熔盐合成法合成的均匀的 La2Zr2O7:Tb3+,Mn3+ 纳米粒子 (NPs) 获得高测温灵敏度。 [10] 在目前的工作中，通过熔盐合成制备了氧化镁（MgNiO2）固溶体。 [11] 在这项工作中，我们使用熔盐合成法合成了 Lu2Hf2O7 (LuHO) 和 Lu2Hf2O7:Eu3+ (LuHOE) 纳米晶体 (NCs)，并证实两者都稳定在具有高度结构无序的缺陷萤石结构中。 [12] 在这项工作中，我们设计了 Gd2Hf2O7 纳米晶体 (NCs)，并使用熔盐合成将它们与 Yb3+-Er3+ (GHO-YE) 和 Yb3+-Tm3+ (GHO-YT) 共掺杂。 [13] 熔盐合成是获得这种独特形态的常用简单方法。 [14] 本文回顾了四种有前景的温和条件氨生产方法：固态合成、熔盐合成、热化学循环和光催化路线。 [15] 这项工作中提出的创新熔盐合成方法提供了在 900–1100 °C 下以≥80 wt% 的产率生成的超纯 Na2Ti6O13 纳米棒。 [16] 为了克服这一挑战，以Cr为金属源，松木衍生的多孔碳材料为模板，通过熔盐合成在低至700°C的温度下制备了多孔碳化铬/碳生物形态陶瓷。 [17] 等轴测 Na2Nb8O21 颗粒通过熔盐合成 (MSS) 合成。 [18] 熔盐合成法应用于电容式多孔炭的制备。 [19] 熔盐合成通过模板生长机制在 1300°C 在 2 小时内提供单相 Gd2TiO5，并且对于这些耐火材料的合成是有效的。 [20] 本研究报告了使用表面响应方法和遗传算法对多相磷酸钙的自燃微波熔盐合成进行统计优化，因为这些分子混合物将骨传导和骨诱导特性与控制生物降解的良好能力相结合。 [21] 其中，KSN微晶采用熔盐合成法制备，具有大量K+/Sr2+空位。 [22] 采用熔盐合成法制备了10 μm～18 μm的大尺寸Ca3Co4O9微孔板。 [23] 熔盐合成是制备光催化剂的有效方法。 [24] 为了解决上述问题，本文开发了一种将熔盐合成和自引发聚合相结合的简便且可扩展的策略，以在 MnO2/Mn2O3 纳米复合材料表面原位生成聚吡咯薄层。 [25] 在这项工作中，我们提出了一种简便有效的一步熔盐合成策略来制备自支撑一维 Ni-Mo 基混合相多离子化合物纳米棒阵列 (NMNA)。 [26] 在此，以氟化铈（CeF3）和硼氢化钠（NaBH4）为铈和硼的前驱体，在氩气气氛下，首次通过无机熔盐合成路线合成了平均粒径为50 nm的镧系元素四硼化物纳米晶粉末CeB4，表现出良好的性能。 CR 的吸附性能。 [27] 采用熔盐合成法合成了片状Ca3Co4O9微晶颗粒。 [28] 随着共沉淀 pH 值升高以制备用于 NPs 熔盐合成的单源前体，发光输出和量子产率逐渐降低。 [29] 以一维Nb2O5为前驱体，采用拓扑化学熔盐合成（TMSS）法合成了不同结构（钙钛矿、四方钨青铜-TTB、铌酸铋层状结构-BNLS）的5Nb2O9）。 [30] 以 NaNO3 和 KNO3 为反应介质，采用简易熔盐合成（MSS）法在低温下成功合成了 CeF3 和 CeF3:Tb3+ 颗粒。 [31] 在这项工作中，采用熔盐合成法在四个退火温度下合成了不同尺寸的 BaZrO3 (BZO) 晶体。 [32] 采用熔盐合成(MSS)和拓扑化学微晶转化(TMC)技术成功合成了高纵横比的A位复合钙钛矿(Ba, Sr)TiO3微片。 [33] 通过 PbC2O4 和 TiO2 在共晶 NaCl-KCl 盐中的反应，分别通过熔盐合成 (MSS) 和模板 MSS 方法合成了球形和棒状 PbTiO3 (PTO) 粉末。 [34] 分别通过熔盐合成和常规固态反应方法制备了 C 轴优先和随机取向的 Bi4NdTi3FeO15 (BNTF) 陶瓷。 [35] 熔盐合成是一个简单的过程，它利用低温和短的反应时间获得化学成分均匀、晶体形态好、相纯度高的合成粉末。 [36] 9)O3] (BCZT) 晶体熔盐合成(MSS) 方法和MSS 工艺参数对BCZT 陶瓷的形貌、相结构、介电和铁电性能的影响已在本研究中得到报道。 [37] 锰基富锂层状氧化物的常用制备方法包括共沉淀法、燃烧法、喷雾热解法和熔盐合成法。 [38] 本研究采用熔盐合成法制备了ZrC包覆鳞片石墨，并将其添加到Al2O3-C耐火材料中。 [39] 在这里，我们探索了通过熔盐合成方法合成的 NZO NPs 的结构和光学性质。 [40] 我们报告了使用熔盐合成在 1000°C 下合成高度有序和纳米结构的 h-BN。 [41] 系统研究了反应温度、反应时间、反应物摩尔比等反应条件对产物形貌的影响，以期通过熔盐合成制备形貌均一、结晶度高的六钛酸钾（K2Ti6O13）晶须，实现工业化应用。 [42] 首次在 NaCl-KCl 和 LiCl-KCl 中通过熔盐合成成功合成了 LaMn1-xFexO3 钙钛矿。 [43] 在此，通过熔盐合成的氧化钙-氧化铝系统的相演化被报道为合成温度和大气环境的函数。 [44] 在这项工作中，通过良好控制的熔盐合成制备了一种高度结晶的氯化锂插层石墨氮化碳 (LiCl-CN) 材料。 [45] 本文采用传统混合氧化物（CMO）、两步烧结（TSS）、反应烧结（RS）和熔盐合成（MSS）等多种方法合成了钨青铜填充结构的Sr2NaNb5O15（SNN）陶瓷。 [46] 以氧化铁红为含铁原料，采用熔盐合成法，在1000℃、2小时内成功合成了一系列软磁性镍铁氧体（NiFe2O4）样品。 [47] SrBi2NbO9化合物通过草酸盐共沉淀法、熔盐合成法和可聚合络合物三种方法制备。 [48]
salt synthesis method 盐合成法
, nanocubes, nanocuboids, and quasi-nanospheres, were prepared via a facile molten salt synthesis method. [1] 5Nb2O6 nanorods fabricated by a molten salt synthesis method. [2] Here, we have employed the strategy of combining rare earth ion Tb3+ and transition metal ion Mn3+ with completely different thermal-quenching behaviors to obtain high thermometric sensitivity using uniform La2Zr2O7:Tb3+,Mn3+ nanoparticles (NPs) synthesized by a molten salt synthesis method. [3] Large-size Ca3Co4O9 microplates in the range of 10 μm to 18 μm, were prepared by using molten salt synthesis method. [4] 75, 1) double perovskites were prepared by a facile molten-salt synthesis method and examined by XRD, SEM, BET, in situ DRIFTS, and XPS. [5] Herein, La2GaMnO6 and La2CoMnO6 double perovskites with monoclinic structures were prepared via a facile molten-salt synthesis method. [6] In this work, BaZrO3 (BZO) crystals with different sizes were synthesized using a molten salt synthesis method at four annealing temperatures. [7] In this paper, we present mesoporous LaMnO3 and LaCoO3 with rhombohedral structures prepared by a facile molten-salt synthesis method. [8] Here, we have explored the structural and optical properties of the NZO NPs synthesized by a molten salt synthesis method. [9] A series of soft magnetic nickel ferrite (NiFe2O4) samples were successfully synthesised at 1000 °C over a period of 2 h through the molten salt synthesis method using iron oxide red as iron-bearing raw materials. [10]，通过简便的熔盐合成方法制备了纳米立方体、纳米立方体和准纳米球。 [1] 采用熔盐合成法制备的 5Nb2O6 纳米棒。 [2] 在这里，我们采用将具有完全不同热猝灭行为的稀土离子 Tb3+ 和过渡金属离子 Mn3+ 相结合的策略，使用通过熔盐合成法合成的均匀的 La2Zr2O7:Tb3+,Mn3+ 纳米粒子 (NPs) 获得高测温灵敏度。 [3] 采用熔盐合成法制备了10 μm～18 μm的大尺寸Ca3Co4O9微孔板。 [4] 75, 1) 通过简便的熔盐合成方法制备双钙钛矿，并通过 XRD、SEM、BET、原位 DRIFTS 和 XPS 进行检测。 [5] 在此，通过简便的熔盐合成方法制备了具有单斜结构的 La2GaMnO6 和 La2CoMnO6 双钙钛矿。 [6] 在这项工作中，采用熔盐合成法在四个退火温度下合成了不同尺寸的 BaZrO3 (BZO) 晶体。 [7] 在本文中，我们介绍了通过简便的熔盐合成方法制备的具有菱面体结构的介孔 LaMnO3 和 LaCoO3。 [8] 在这里，我们探索了通过熔盐合成方法合成的 NZO NPs 的结构和光学性质。 [9] 以氧化铁红为含铁原料，采用熔盐合成法，在1000℃、2小时内成功合成了一系列软磁性镍铁氧体（NiFe2O4）样品。 [10]
salt synthesis route 盐合成路线
This paper present, fabrication of A356 with grain refiner (TiB2) via salt synthesis route, simultaneously modified by RE (Ce and La rich) and addition of minor alloying element as Sn. [1] In this work, an ultrahigh-sensitive mixed-potential ammonia sensor was developed using a new dual-functional NiWO4 electrocatalyst, synthesized through a low-temperature molten-salt synthesis route. [2] Herein, a lanthanide tetraboride nanocrystal powder CeB4 with an average particle size of 50 nm synthesized for the first time via inorganic molten salt synthesis route using cerium fluoride (CeF3) and sodium borohydride (NaBH4) as the cerium and boron precursors in argon atmosphere exhibits good performance for the adsorption of CR. [3]本文介绍了通过盐合成路线制备具有晶粒细化剂 (TiB2) 的 A356，同时通过稀土改性（富含 Ce 和 La）并添加少量合金元素如 Sn。 [1] 在这项工作中，使用通过低温熔盐合成路线合成的新型双功能 NiWO4 电催化剂开发了一种超高灵敏度混合电位氨传感器。 [2] 在此，以氟化铈（CeF3）和硼氢化钠（NaBH4）为铈和硼的前驱体，在氩气气氛下，首次通过无机熔盐合成路线合成了平均粒径为50 nm的镧系元素四硼化物纳米晶粉末CeB4，表现出良好的性能。 CR 的吸附性能。 [3]