Polymer Induced(聚合物诱导)研究综述
Polymer Induced 聚合物诱导 - The enhanced permeability is attributed to an improvement in the free volume of the polymer induced by larger sized ZIF-8, while the increased selectivity results from the high specific surface area of large sized ZIF-8, which can provide more active sites for CO2 capture and great mass transfer resistance for N2. [1] Thanks to the switchable Tg of azopolymer induced by reversible trans-cis isomerization, the entropic energy is trapped in low Tg state (cis-form Tg < RT) to deform into a temporary shape and fixed in high Tg state (trans-form Tg > RT). [2] However, enhanced mobility of the block copolymer induced by solvent annealing suppresses the pattern sequencing and the in-plane cylinders with a relatively high degree of ordering generated over the entire surface of the corrugated substrate. [3] Moreover, the fluorescent probe exhibited changes in fluorescence intensity with an alteration of turbidity of the block copolymer induced by temperature. [4]渗透率的提高归因于较大尺寸 ZIF-8 引起的聚合物自由体积的改善，而选择性的提高则归因于大尺寸 ZIF-8 的高比表面积，这可以为 CO2 捕获提供更多的活性位点N2 的传质阻力大。 [1] 由于可逆的反式-顺式异构化诱导偶氮聚合物的可切换Tg，熵能被困在低Tg状态（顺式Tg < RT）变形为临时形状并固定在高Tg状态（反式Tg > RT）。 [2] 然而，由溶剂退火引起的嵌段共聚物的流动性增强抑制了图案排序和在波纹基板的整个表面上产生的具有相对高有序度的面内圆柱体。 [3] 此外，荧光探针表现出荧光强度随温度引起的嵌段共聚物浊度的变化而变化。 [4]
Crystalline Polymer Induced
Bimodal polyethylene (BPE)/chitin nanocrystals (CNC) injection bars with various CNC content were prepared to explore the shish-kebab crystal structure of semi-crystalline polymer induced by bio-based nanofiller under flow field. [1] Observations of the spherulite nuclei also evidence the oriented structure of the semi-crystalline polymer induced by the injection-molding manufacturing process. [2]制备了不同CNC含量的双峰聚乙烯（BPE）/几丁质纳米晶（CNC）注射棒，以探索流场下生物基纳米填料诱导的半结晶聚合物的烤肉串晶体结构。 [1] 对球晶核的观察也证明了由注塑成型制造过程引起的半结晶聚合物的定向结构。 [2]
polymer induced liquid
Different intrafibrillar mineralization mechanisms, including polymer induced liquid precursor (PILP), capillary action, electrostatic attraction, size exclusion, Gibbs-Donnan equilibrium, and interfacial energy guided theories, are discussed. [1] Investigations of the underlying mineralization process of this method strongly suggest a polymer induced liquid precursor (PILP) process followed by a non-classical crystallization pathway. [2]讨论了不同的纤维内矿化机制，包括聚合物诱导液体前体 (PILP)、毛细作用、静电吸引、尺寸排阻、吉布斯-唐南平衡和界面能量引导理论。 [1] 对该方法的潜在矿化过程的研究强烈表明聚合物诱导液体前体 (PILP) 过程随后是非经典结晶途径。 [2]