Polyelectrolyte Layers(聚电解质层)研究综述
Polyelectrolyte Layers 聚电解质层 - Here, we cost-efficiently prepared large-area Au nanocube arrays (NCAs) using only the electrostatic forces between colloidal Au nanocubes and polyelectrolyte layers. [1] Manufacturing such “iontronic” devices generally involves classical thin film processing of polyelectrolyte layers and insulators followed by application of electrolytes. [2] Another approach that has been tested is based on coating the carbon with polyelectrolyte layers, converting them into “soft electrodes” (SEs). [3] The number of polyelectrolyte layers, the deposition technology, the nature of the interactions between the components and the chosen components, as well as the produced systems, make LbL a versatile technique. [4] Using the method of time-lapse confocal microscopy, we observed a prolonged lag phase, dependent on the number of polyelectrolyte layers. [5] For the first time, it was shown that primary modification of the Au surface influences the rate of the multilayer assembling and the shape of appropriate dependence of the SPR signal on the number of polyelectrolyte layers. [6] Three compositions were considered: with MWCNTs incorporated between polyelectrolyte layers; with MWCNTs inserted into the hollow of the microcapsule; and with MWCNTs incorporated simultaneously into the hollow and between polyelectrolyte layers. [7]在这里,我们仅使用胶体金纳米立方体和聚电解质层之间的静电力经济高效地制备了大面积金纳米立方体阵列 (NCA)。 [1] 制造这种“离子电子”设备通常涉及聚电解质层和绝缘体的经典薄膜加工,然后是电解质的应用。 [2] 另一种经过测试的方法是在碳上涂上聚电解质层,将它们转化为“软电极”(SE)。 [3] 聚电解质层的数量、沉积技术、组件与所选组件之间相互作用的性质以及所生产的系统,使 LbL 成为一种通用技术。 [4] 使用延时共聚焦显微镜的方法,我们观察到一个延长的滞后期,这取决于聚电解质层的数量。 [5] 首次表明,Au 表面的初级改性会影响多层组装的速率以及 SPR 信号对聚电解质层数的适当依赖性的形状。 [6] 考虑了三种组合物: 在聚电解质层之间加入 MWCNT;将多壁碳纳米管插入微囊的中空;并且MWCNTs同时结合到中空和聚电解质层之间。 [7]