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i-Pr2NMgCl·LiCl Enables the Synthesis of Ketones by Direct Addition of Grignard Reagents to Carboxylate Anions.



One-pot, modular approach to functionalized ketones via nucleophilic addition/Buchwald-Hartwig amination strategy.



Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry.



Murahashi Cross-Coupling at -78 °C: A One-Pot Procedure for Sequential C-C/C-C, C-C/C-N, and C-C/C-S Cross-Coupling of Bromo-Chloro-Arenes.



Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones.



Water and Sodium Chloride: Essential Ingredients for Robust and Fast Pd-Catalysed Cross-Coupling Reactions between Organolithium Reagents and (Hetero)aryl Halides.



Metal-free acyl-directed electrophilic C-H borylation using just BBr3



Simple one pot synthesis of ketone from carboxylic acid using DCC as an activator



Manganese(iii) acetate-mediated direct C(sp2)-H-sulfonylation of enamides with sodium and lithium sulfinates.



Synthesis of chromophores based on the hydrazinylidene cyclic acceptor moieties via the reaction of organolithium reagents with diazo compounds


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