Organic Guest(有机客人)研究综述
Organic Guest 有机客人 - The solid-phase guest exchange in anhydrous inclusion compounds with organic guests was used in the present work to activate the inclusion properties of αCD without the presence of water. [1] Otherwise, taking advantage of the affinity of fullerenes with selected solvents, we have confirmed the ability of the C60 molecules to promote the displacement of the inorganic guest from the host. [2] The eight physicochemical parameters of the organic guests and dispersion media were extracted by sparse modeling for the construction of the size-prediction model. [3] Because aluminosilicates do not absorb most of the UV/visible wavelength region, incorporation of dyes inside these porous materials allows the development of highly efficient visible light photocatalyst due to the stabilizing effect that inclusion inside the confined space exerts on the organic guest. [4] Various analytical techniques were utilized to investigate the interaction between the inorganic and organic components and to understand how the intercalation of organic guests effects on the electrocapacitive performance of the electrodes. [5] The obtained results indicated that the type and arrangement of organic guests between layers of the LDHs influence Eu3+ luminescence in the synthesized different hybrid inorganic–organic matrixes. [6] The mesopores in these MOFs lead to fast adsorption kinetics, whereas the π-interaction between isolated porphyrin units in the MOF backbone and polycyclic structure of the organic guests provides excellent reversibility. [7]在目前的工作中，无水包合物与有机客体的固相客体交换用于在不存在水的情况下激活 αCD 的包合特性。 [1] 否则，利用富勒烯与选定溶剂的亲和力，我们已经证实了 C60 分子促进无机客体从主体中置换的能力。 [2] 通过稀疏建模提取有机客体和分散介质的8个物理化学参数，用于构建尺寸预测模型。 [3] 由于硅铝酸盐不吸收大部分紫外/可见波长区域，因此在这些多孔材料中掺入染料可以开发出高效的可见光光催化剂，因为在有限空间内的夹杂物会对有机客体产生稳定作用。 [4] 各种分析技术被用来研究无机和有机成分之间的相互作用，并了解有机客体的嵌入如何影响电极的电容性能。 [5] 所得结果表明，LDHs层间有机客体的类型和排列会影响合成的不同无机-有机杂化基体中的Eu3+发光。 [6] 这些 MOF 中的中孔导致快速吸附动力学，而 MOF 主链中孤立的卟啉单元与有机客体的多环结构之间的 π 相互作用提供了出色的可逆性。 [7]
organic guest molecule 有机客体分子
However, the direct intercalation of organic guest molecules into the gallery of LDHs using carbonate-intercalated LDHs as the starting material is still challenging. [1] Correction for 'Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer' by Purna Chandra Rao et al. [2] The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules. [3] Their unique open framework structures allow them to not only act as size-selective sieves, but to play host to an adsorbed phase of organic guest molecules. [4] The binding affinities reach micromolar values, which are among the highest known values for native CDs, and exceed those for neutral hydrophobic organic guest molecules. [5] Cyclic oligosaccharides such as cyclodextrins (CyDs) have been known as excellent host molecules for the inclusion of various organic guest molecules. [6] In addition, one-dimensional (1D) nanochanneled materials with a diameter size in the range of molecular dimensions are considered ideal hosts to induce a supramolecular organization of photoactive organic guest molecules. [7]然而，使用碳酸盐嵌入的 LDHs 作为起始材料，将有机客体分子直接嵌入 LDHs 的通道中仍然具有挑战性。 [1] Purna Chandra Rao 等人对“有机客体分子在自组装单层上外延生长的金属有机框架的超快呼吸”的校正。 [2] MOF 薄膜在吸收有机客体分子后表现出超快的结构灵活性（通过呼吸）。 [3] 它们独特的开放框架结构使它们不仅可以作为尺寸选择筛，还可以作为有机客体分子吸附相的宿主。 [4] 结合亲和力达到微摩尔值，这是天然 CD 已知的最高值之一，并超过了中性疏水有机客体分子的值。 [5] 环状寡糖如环糊精 (CyDs) 已被认为是包含各种有机客体分子的优良主体分子。 [6] 此外，直径尺寸在分子尺寸范围内的一维（1D）纳米通道材料被认为是诱导光活性有机客体分子超分子组织的理想主体。 [7]