Liquid Interfaces(液体界面)研究综述
Liquid Interfaces 液体界面 - In particular, we focus on experimental research and computational and numerical approaches which demonstrate how surface-active chemical based intervention, based on competition with blood-borne or cell surface-borne macromolecules for surface occupancy of gas-liquid interfaces, alters cellular mechanics, mechanosensing and signaling coupled to fluid stress exposures occurring in gas embolism. [1] The inability of this film to accommodate thermally and/or mechanically induced stresses experience during cooling results in grain boundary microfissuring through decohesion along one of the solid-liquid interfaces on the grain boundary and, thus, it is sometimes referred to as liquation cracking, hot cracking or hot tearing. [2] Biopharmaceutical formulations may be compromised by freezing, which has been attributed to protein conformational changes at a low temperature, and adsorption to ice-liquid interfaces. [3] We believe that this work is of great interest when using electrical discharge plasma on liquid interfaces in food, agricultural, and medical industries. [4] However, the knowledge of interfacial structures that significantly affect ion transport through liquid-liquid interfaces is still lacking due to the difficulty of observing nanoscale interfaces. [5] I will present an alternate route facilitating interfacial self-assembly and jamming of superparamagnetic nanoparticles at curved liquid-liquid interfaces to create macrospin systems. [6] Component density profiles at vapour–liquid interfaces of mixtures can exhibit a non-monotonic behaviour with a maximum that can be many times larger than the densities in the bulk phases. [7] The assembly of disc-shaped particles at curved liquid-liquid interfaces was studied by using confocal microscopy. [8] The open-source multiphase flow solver, PARIS, is used for the simulations and the mass–momentum consistent volume-of-fluid method is used to capture the sharp gas–liquid interfaces. [9] The adsorption of colloidal particles at liquid interfaces is of great importance scientifically and industrially, but the dynamics of the adsorption process is still poorly understood. [10] Despite progress in solid-state battery engineering, our understanding of the chemo-mechanical phenomena that govern electrochemical behaviour and stability at solid–solid interfaces remains limited compared to at solid–liquid interfaces. [11] Triboelectrochemical reactions occur on solid–liquid interfaces in wide range of applications when an electric field strong enough and a frictional stress high enough are simultaneously imposed on the interfaces. [12] Scanning electrochemical microscopy (SECM) is used to measure the local electrochemical behavior of liquid/solid, liquid/gas and liquid/liquid interfaces. [13] For biosensing applications at solid-liquid interfaces, recent efforts to boost surface sensitivity have narrowly focused on laterally isotropic nanostructures, while there is an outstanding need to explore laterally anisotropic nanostructures such as nanorods that have distinct plasmonic properties. [14] Self-assembly, complexation, agglomeration and precipitation phenomena relevant to biological, electrocatalytic and technological processes are strongly influenced by changes of the local pH at the solid-liquid interfaces where they occur. [15] A novel neutron and X-ray reflectometry sample environment is presented for the study of surface-active molecules at solid–liquid interfaces under shear. [16] The effect of Fresnel dispersion becomes significant when the SFG spectrum involves a sharp and intense vibrational band as well as a large non-resonant background susceptibility, typically in some solid-liquid interfaces. [17] Enrichment at the vapor-liquid interfaces and density inversion can also be observed. [18] Here, the impact of macromolecular crowding on htt aggregation in bulk solution and at solid/liquid or membrane/liquid interfaces was investigated. [19] We use hydrodynamics experiments to probe how the magnetization of ferromagnetic liquid droplets, governed by the assembly and jamming of magnetic nanoparticles at liquid–liquid interfaces, and their response to external stimuli can be tuned by chemical, structural, and magnetic means. [20] This enables the continuous surveillance of the amoeba-like rapid grain boundary movements of Cu 6 Sn 5 during soldering and increases the fundamental understanding of reaction mechanisms in solder solid/liquid interfaces. [21] Increasing the LaB6 addition up to 2 wt% only marginally further refined the equiaxed grains, which can be understood in terms of the concept of nucleation free zone formed in the liquid at front of the growing solid-liquid interfaces. [22] Immiscible liquid–liquid interfaces are an attractive platform to develop well-ordered self-assembled nanostructures, unattainable in bulk solution, due to the templating interaction of the interface with adsorbed molecules. [23] Additionally, this approach can offer a new platform for fundamental studies of key aspects of electronic and ionic transfers across liquid–liquid interfaces, with applications in relevant biological, technological and industrial systems. [24] These interventions had their roots in the understanding of the principles of the surface tension present at air–liquid interfaces, which were developed over 150 years before BPD's initial description. [25] However, it is unclear how the gas-liquid interface affects the protein assembly at the nanometer scale although the presence of gas-liquid interfaces is very common in in vitro experiments. [26] The findings of this study can help to better understand the adsorption impact of surfactants on the characteristics of the oil/water and solid/liquid interfaces. [27] Understanding structure and function of solid-liquid interfaces is essential for the development of nanomaterials for various applications including heterogeneous catalysis in liquid phase processes and water splitting for storage of renewable electricity. [28] In this paper, we present elaborated methodologies that allow qualitative and quantitative measurements of the stability of both the emulsion and foam films formed by a single bubble and droplet at liquid/gas and liquid/liquid interfaces, where the hydrodynamic factors are of crucial importance. [29] Transport of ions through liquid-liquid interfaces is of fundamental importance to a wide variety of applications. [30] The obtained results are important for optimum stabilization and functionalization of gas/liquid interfaces and the following applications in the multimodal biomedical imaging. [31] In this work, we report a general strategy for creating complex HIPEs that can form interfacial films at liquid interfaces. [32] This article reports the first investigation of (polymer + surfactant) complex structures at solid-liquid interfaces. [33] , aeration in biological water treatment, water disinfection, membrane defouling, and ground water and sediment remediation) in recent decades because of their superior characteristics such as the improved mass transfer at the gas-liquid interfaces, their lifetime up to a couple of weeks, the formation of reactive oxygen species (ROS) with high oxidative potential. [34] Divergent electric fields on the solid/liquid interfaces of oil-filled assets can lead to the propagation of the creeping discharges over the interface. [35] , water and oil, although not accurate, but showing ERT as a possible promising technique for analyzing liquid-liquid interfaces. [36] Based on the nature of triggering and developing instability at liquid interfaces, in combination with an equivalent electric circuit model, a novel electric capillary number method is proposed as a comprehensive critical condition for the cutting. [37] amyloliquefaciens L-17 to survive on air-liquid interfaces. [38] We investigate the density profile, dipole moment and hydrogen bonds of eight hydrophobic DES-aqueous liquid-liquid interfaces using molecular dynamics simulations. [39] Immiscible liquid|liquid interfaces are an attractive platform to develop well-ordered self-assembled nanostructures, unattainable in bulk solution, due to the templating interaction of the interface with adsorbed molecules. [40] The adsorption of two-dimensional (2-D) graphene oxide (GO) nanosheets at liquid-liquid interfaces has broad technological implications from functional material preparations to oil-water emulsification. [41]特别是，我们专注于实验研究以及计算和数值方法，这些方法展示了基于表面活性化学的干预如何基于与血液传播或细胞表面传播的大分子竞争气液界面的表面占有率，改变细胞力学、机械传感和信号与气体栓塞中发生的流体压力暴露有关。 [1] 该薄膜无法适应冷却过程中经受的热和/或机械引起的应力，导致晶界通过沿晶界上的固-液界面之一脱聚而产生微裂纹，因此，有时将其称为液化开裂、热开裂或热撕裂。 [2] 冷冻可能会影响生物制药配方，这归因于低温下的蛋白质构象变化以及冰液界面的吸附。 [3] 我们相信，当在食品、农业和医疗行业的液体界面上使用放电等离子体时，这项工作非常有趣。 [4] 然而，由于难以观察纳米级界面，仍然缺乏对通过液-液界面的离子传输有显着影响的界面结构的知识。 [5] 我将介绍一种替代途径，促进界面自组装和超顺磁性纳米颗粒在弯曲的液-液界面上的干扰，以创建宏自旋系统。 [6] 混合物气-液界面的组分密度分布可以表现出非单调行为，其最大值可能比体相中的密度大很多倍。 [7] 通过使用共聚焦显微镜研究了在弯曲的液-液界面处盘形颗粒的组装。 [8] 开源多相流求解器 PARIS 用于模拟，质量动量一致的流体体积法用于捕获尖锐的气液界面。 [9] 胶体颗粒在液体界面的吸附在科学和工业上具有重要意义，但吸附过程的动力学仍然知之甚少。 [10] 尽管固态电池工程取得了进展，但与固-液界面相比，我们对控制固-固界面电化学行为和稳定性的化学机械现象的理解仍然有限。 [11] 当足够强的电场和足够高的摩擦应力同时施加在界面上时，摩擦电化学反应会在广泛的应用中发生在固-液界面上。 [12] 扫描电化学显微镜 (SECM) 用于测量液/固、液/气和液/液界面的局部电化学行为。 [13] 对于固-液界面的生物传感应用，最近提高表面灵敏度的努力主要集中在横向各向同性纳米结构上，同时迫切需要探索横向各向异性纳米结构，例如具有不同等离子体特性的纳米棒。 [14] 与生物、电催化和技术过程相关的自组装、络合、团聚和沉淀现象受到它们发生的固-液界面的局部 pH 值变化的强烈影响。 [15] 提出了一种新的中子和 X 射线反射测量样品环境，用于研究剪切下固液界面处的表面活性分子。 [16] 当 SFG 光谱包含尖锐而强烈的振动带以及大的非共振背景磁化率时，菲涅耳色散的影响变得显着，通常在某些固液界面中。 [17] 还可以观察到气液界面处的富集和密度反转。 [18] 在这里，研究了大分子拥挤对散装溶液和固/液或膜/液界面处的 htt 聚集的影响。 [19] 我们使用流体动力学实验来探索铁磁性液滴的磁化如何通过化学、结构和磁性手段来调节，这些液滴由磁性纳米粒子在液-液界面的组装和干扰控制，以及它们对外部刺激的响应。 [20] 这使得能够在焊接过程中连续监测 Cu 6 Sn 5 的阿米巴状快速晶界运动，并增加对焊料固/液界面反应机制的基本理解。 [21] 将 LaB6 添加量增加到 2 wt% 只会稍微进一步细化等轴晶粒，这可以根据在生长的固液界面前部的液体中形成的无核区的概念来理解。 [22] 由于界面与吸附分子的模板相互作用，不混溶的液-液界面是开发有序自组装纳米结构的有吸引力的平台，在本体溶液中无法实现。 [23] 此外，这种方法可以为跨液-液界面的电子和离子转移的关键方面的基础研究提供一个新平台，并应用于相关的生物、技术和工业系统。 [24] 这些干预措施的根源在于对存在于气液界面的表面张力原理的理解，这些原理是在 BPD 最初描述之前 150 多年发展起来的。 [25] 然而，目前尚不清楚气液界面如何影响纳米尺度的蛋白质组装，尽管气液界面的存在在体外实验中非常普遍。 [26] 本研究的结果有助于更好地了解表面活性剂对油/水和固/液界面特性的吸附影响。 [27] 了解固液界面的结构和功能对于开发用于各种应用的纳米材料至关重要，包括液相过程中的多相催化和用于存储可再生电力的水分解。 [28] 在本文中，我们提出了详细的方法，允许定性和定量测量由单个气泡和液滴在液/气和液/液界面形成的乳液和泡沫膜的稳定性，其中流体动力学因素至关重要。 [29] 离子通过液-液界面的传输对于广泛的应用至关重要。 [30] 获得的结果对于气/液界面的最佳稳定性和功能化以及多模态生物医学成像中的以下应用非常重要。 [31] 在这项工作中，我们报告了一种创建复杂 HIPE 的一般策略，该 HIPE 可以在液体界面形成界面膜。 [32] 本文报道了对固液界面（聚合物+表面活性剂）复杂结构的首次研究。 [33] ，生物水处理中的曝气，水消毒，膜除污，地下水和沉积物修复），因为它们具有优越的特性，例如改善气液界面的传质，使用寿命长达几周，形成具有高氧化电位的活性氧（ROS）。 [34] 充油资产的固/液界面上的发散电场会导致爬行放电在界面上的传播。 [35] ，水和油，虽然不准确，但表明 ERT 作为分析液-液界面的一种可能有前途的技术。 [36] 基于液体界面触发和发展不稳定性的性质，结合等效电路模型，提出了一种新的电毛细管数方法作为切割的综合临界条件。 [37] 解淀粉酶 L-17 在气液界面上存活。 [38] 我们调查密度分布， 八种疏水性 DES-aqueous 的偶极矩和氢键 使用分子动力学模拟的液-液界面。 [39] 由于界面与吸附分子的模板相互作用，不混溶的液体|液体界面是开发有序自组装纳米结构的有吸引力的平台，在本体溶液中无法实现。 [40] 从功能材料制备到油水乳化，二维（2-D）氧化石墨烯（GO）纳米片在液-液界面的吸附具有广泛的技术意义。 [41]
Organic Liquid Interfaces
Complex analysis including coadsorption at the aqueous-air and aqueous-organic liquid interfaces, protein intrinsic fluorescence and enzymatic activity of lysozyme in the presence of surfactants was performed. [1] In this work, we use wave packets (WP) in molecular dynamics (MD) simulations to study the phonon energy transmission coefficients (ETCs) across different Au-self-assembled monolayer (SAM)-organic liquid interfaces. [2]进行了复杂的分析，包括在水-空气和水-有机液体界面的共吸附、蛋白质固有荧光和在表面活性剂存在下溶菌酶的酶活性。 [1] nan [2]
liquid interfaces play 液体界面播放
Liquid/liquid interfaces play a central role in scientific fields ranging from nanomaterial synthesis and soft matter electronics to nuclear waste remediation and chemical separations. [1] The attachment and dissociation of a proton from a water molecule and the proton transfers at solid-liquid interfaces play vital roles in numerous biological, chemical processes and for the development of sustainable functional materials for energy harvesting and conversion applications. [2] Soft matter at solid-liquid interfaces plays an important role in multiple scientific disciplines as well as in various technological fields. [3]液/液界面在从纳米材料合成和软物质电子学到核废料修复和化学分离等科学领域发挥着核心作用。 [1] 质子与水分子的附着和解离以及质子在固-液界面的转移在许多生物、化学过程以及开发用于能量收集和转换应用的可持续功能材料方面发挥着至关重要的作用。 [2] nan [3]
liquid interfaces vium
Large oriented electric fields spontaneously arise at all solid–liquid interfaces via the exchange of ions and/or electrons with the solution. [1] Our technique operates in two modes: “tensiometric mode” for surface tension measurements and “manipulation mode” for studying and manipulating liquid interfaces via an electric field. [2]通过离子和/或电子与溶液的交换，在所有固液界面自发产生大的定向电场。 [1] nan [2]