Conjugated Organic
共轭有机

Conjugated Organic(共轭有机)研究综述

Conjugated Organic 共轭有机 - However, the ions trapping mechanism is still not fully understood, especially for conjugated organic/polymer films. ^[1] 5, in the form of conjugated organic and inorganic ions. ^[2] First-principles calculations show that the π-conjugated organic (4HP)+ cation governs the optical anisotropy, whereas the synergy of the organic and inorganic moieties dominates the SHG process. ^[3] 3 A cm-2 at 50 mV for MtrF), on par with conjugated organics, suggesting a heme-assisted coherent tunneling mechanism. ^[4] The first area represents a primary focus for the materials chemistry community, where a collection of papers covers, for example, progress in stretchable block copolymers and conjugated organics for structural materials and active layers, respectively, and associated techniques in processing such as spin-casting, printing, and vapor phase deposition onto both planar and textile substrates. ^[5]
然而，离子捕获机制仍未完全了解，特别是对于共轭有机/聚合物薄膜。 ^[1] 5、以共轭有机和无机离子的形式存在。 ^[2] 第一性原理计算表明，π-共轭有机 (4HP)+ 阳离子控制光学各向异性，而有机和无机部分的协同作用主导 SHG 过程。 ^[3] 3 A cm-2 at 50 mV for MtrF)，与共轭有机物相当，表明血红素辅助的相干隧道机制。 ^[4] 第一个领域代表了材料化学界的主要关注点，其中一系列论文涵盖了，例如，分别用于结构材料和活性层的可拉伸嵌段共聚物和共轭有机物的进展，以及旋转浇铸等相关加工技术、印刷和气相沉积到平面和纺织基材上。 ^[5]

Highly Conjugated Organic 高度共轭有机

The unique [3+2] cyclization product was used for the synthesis of a highly conjugated organic molecule, which is hard to access or even inaccessible by conventional methods. ^[1] The composite materials are synthesized by the functionalization of CNTs with highly conjugated organic dye-sensitized polymeric molecules. ^[2] To the best of our knowledge, our hcc-COF film shows the highest reported electrical conductivity for highly conjugated organic porous polymers. ^[3] Here we report a highly conjugated organic framework, poly(imine-anthraquinone) (PIAQ), as the anode material of LIBs. ^[4]
独特的 [3+2] 环化产物用于合成高度共轭的有机分子，这是传统方法难以获得甚至无法获得的。 ^[1] 该复合材料是通过用高度共轭的有机染料敏化聚合物分子对碳纳米管进行功能化合成的。 ^[2] 据我们所知，我们的 hcc-COF 薄膜显示出报道的高度共轭有机多孔聚合物的最高电导率。 ^[3] 在这里，我们报告了一种高度共轭的有机骨架聚（亚胺-蒽醌）（PIAQ）作为锂离子电池的负极材料。 ^[4]

Type Conjugated Organic

A series of porphyrin-based D-A type conjugated organic polymer (COP) nanotubes MTAPP-BT (M= H2, Zn, Cu, Fe) were synthesized through acid-catalyzed Schiff base reaction between metalloporphyrins (MTAPP) and benzothiadiazole (BT) units. ^[1] Based on diketopyrrolopyrrole (DPP) and (E)-3-phenyl-2-(thiophen-2-yl)acrylonitrile (BVCNT)-linked conjugated backbones, three donor–acceptor type conjugated organic small-molecule compounds DPP-BVCNT, DPP-2FBVCNT, and DPP-3FBVCNT were designed and synthesized. ^[2] Donor–acceptor (D–A) type conjugated organic polymers exhibited great potential for photocatalytic hydrogen evolution due to their diverse synthetic approaches, tunable energy band, and electronic structure. ^[3]
通过金属卟啉（MTAPP）与苯并噻二唑（BT）单元之间的酸催化席夫碱反应，合成了一系列基于卟啉的D-A型共轭有机聚合物（COP）纳米管MTAPP-BT（M=H2、Zn、Cu、Fe）。 ^[1] 基于二酮吡咯并吡咯（DPP）和（E）-3-苯基-2-（噻吩-2-基）丙烯腈（BVCNT）连接的共轭骨架，三种供体-受体型共轭有机小分子化合物DPP-BVCNT、DPP-设计并合成了2FBVCNT和DPP-3FBVCNT。 ^[2] 供体-受体（D-A）型共轭有机聚合物由于其多样化的合成方法、可调谐的能带和电子结构，在光催化析氢方面表现出巨大的潜力。 ^[3]

Fully Conjugated Organic

In this Concept, we discuss the key features of saddle-shaped COT-based derivatives and present the current development of using the COT derivatives as building blocks to construct the 3D fully conjugated organic small compound- and polymer-based OSMs. ^[1] Herein, we report an organic hybridized photocatalyst (termed as COP-TF@CNi2P), carbon-encapsulated nickel phosphide as cocatalyst loaded on fully conjugated organic polymer, which is applied for stable and efficient H2 generation from seawater splitting. ^[2]
在这个概念中，我们讨论了基于马鞍形 COT 衍生物的关键特征，并介绍了使用 COT 衍生物作为构建块来构建 3D 全共轭有机小化合物和聚合物基 OSM 的当前发展。 ^[1] nan ^[2]

Novel Conjugated Organic 新型共轭有机物

A novel conjugated organic molecule was constructed from an electron-donating unit (electron-donating benzo[1,2-b:5,4-b′]dithiophene) and electron-withdrawing groups (cyano and pyridine) and fabricated into sheet-shaped crystals. ^[1] This paper primarily deals with the design and synthesis of three novel conjugated organic molecules containing 1,3,4-oxadiazole unit (abbreviated as CHEM-6(a-c)) with Donor-π-Acceptor-π’-Donor’ structures by utilizing palladium catalyzed Suzuki cross coupling reaction. ^[2]
一种新型共轭有机分子由给电子单元（给电子苯并[1,2-b:5,4-b']二噻吩）和吸电子基团（氰基和吡啶）构建并制成片状晶体。 ^[1] 本文主要涉及利用钯设计和合成三种新型的含有1,3,4-恶二唑单元的共轭有机分子（简称CHEM-6(a-c)），具有Donor-π-Acceptor-π'-Donor'结构。催化铃木交叉偶联反应。 ^[2]

Simple Conjugated Organic 简单共轭有机

We find that quantum mechanical calculations using B3LYP/aug-cc-pVTZ model chemistry involving anharmonic correction on simple conjugated organic compounds without rotating moieties provide the dipole moment values and molecular geometries with high accuracy. ^[1] In this study, a novel, simple conjugated organic dye, N-tert-butyldimethylsilyl-3,6-diiodocarbazole (CA-TBMDS) was developed and used for the first time as a colorimetric sensor for fluoride. ^[2]
我们发现，使用 B3LYP/aug-cc-pVTZ 模型化学的量子力学计算涉及对没有旋转部分的简单共轭有机化合物进行非谐波校正，从而提供了高精度的偶极矩值和分子几何形状。 ^[1] 在这项研究中，开发了一种新型的简单共轭有机染料 N-叔丁基二甲基甲硅烷基-3,6-二碘咔唑 (CA-TBMDS)，并首次将其用作氟化物的比色传感器。 ^[2]

conjugated organic molecule 共轭有机分子

As far as we know, this current work first provides a convenient method to improve the photocatalytic performance of titanium metal–organic frameworks (MOFs) by surface coating with amino conjugated organic molecule, and provides a new idea for the degradation of organic matter by hybrid MOFs materials in wastewater. ^[1] Biradicaloids in π-conjugated organic molecules have been extensively studied in recent years because of the fundamental insights into the chemical bonds and unique optical, electrical, and magnetic properties. ^[2] Recent advances in sustainable optoelectronics including photovoltaics, light-emitting diodes, transistors, and semiconductors have been enabled by π-conjugated organic molecules. ^[3] The delocalized conjugated π bond in the graphene/Cu interface is successfully established through the bridging of graphene and metal with conjugated organic molecule possessing p orbits, which leads to the construction of a new electron thermal conductive route. ^[4] A novel conjugated organic molecule was constructed from an electron-donating unit (electron-donating benzo[1,2-b:5,4-b′]dithiophene) and electron-withdrawing groups (cyano and pyridine) and fabricated into sheet-shaped crystals. ^[5] Without the additional processes, the organic nano-lens array (NLA, a capping layer with a curved surface) formed by vacuum deposition that causes the spontaneous crystallization of π-conjugated organic molecules and a resulting increase in surface tension, has been recently introduced to achieve high mass producibility and high light extraction efficiency of top emitting organic light-emitting diodes. ^[6] This paper primarily deals with the design and synthesis of three novel conjugated organic molecules containing 1,3,4-oxadiazole unit (abbreviated as CHEM-6(a-c)) with Donor-π-Acceptor-π’-Donor’ structures by utilizing palladium catalyzed Suzuki cross coupling reaction. ^[7] Linear, sp-hybridised, 1-dimensional (1D) all-carbon wires are conceptually the simplest π-conjugated organic molecules. ^[8] The method is tested by computing spin-state energies and gaps in conjugated organic molecules and a bimetallic compound and comparing to the corresponding CAS-PDFT values. ^[9] The unique [3+2] cyclization product was used for the synthesis of a highly conjugated organic molecule, which is hard to access or even inaccessible by conventional methods. ^[10] A diphenylphosphine-oxide-based conjugated organic molecule, ((1,3,5-triazine-2,4,6-triyl)tris(benzene-3,1-diyl))tris(diphenylphosphine oxide) (PO-T2T), was doped into ZnO to improve the characteristics of the electron transport layer (ETL) in inverted organic solar cells (OSCs). ^[11] We report a p-π* conjugated organic molecule based on triarylborane as n-type organic semiconductor with unique alcohol solubility. ^[12] Various nanofibril heterojunction structures, including inorganic metal oxides, carbon materials, conjugated organic molecules, and functional polymers, are summarized. ^[13] org , and focused on light-responsive π-conjugated organic molecules with applications in green chemistry, organic solar cells, and organic redox flow batteries. ^[14] To unveil the influence of metal coordination on charge transport and length-dependent conductance attenuation in π-conjugated organic molecules, trans-Ru(dppe)2 (dppe = 1,2-bis(diphenylphosphino)ethane) was implanted into oligoynyl chains with various number of ethynyl groups to construct Au–molecule–Au junctions using methylthiol (−SMe) as anchoring groups. ^[15] For low-cost printable electronic circuitries, n-type amorphous metal-oxide semiconductors and p-type polythiophene-based π-conjugated organic molecules are sequentially deposited via solution processes, and their corresponding p- and n-channel TFT performances exhibit relatively well-balanced ambipolar charge-transport, with high hole and electron mobilities of more than 1 cm2 V−1 s−1. ^[16] The modification of the electronic structure at the interface between 2D BP and a conjugated organic molecule through noncovalent stabilizing interactions mediated by the B atom is particularly appealing in view of creating heterojunctions for optoelectronic, photonic, and chemical sensing applications. ^[17] Herein, we report significant fluorescence quenching induced by intramolecular photoinduced electron transfer (PET) in electron donor–acceptor-type π-conjugated organic molecules with methoxy-containing donor moieties. ^[18] The aim of this study is to provide a thorough understanding of the redox pathways of a D/A/D π-conjugated organic molecule for potential application in organic electrochromic devices. ^[19] Self-aggregation of the conjugated organic molecules is suppressed by functionalization with sterically demanding groups and single crystalline organic–perovskite hybrid quantum wells (down to one-unit-cell thick) are obtained. ^[20] Production of triplets of π-conjugated organic molecules without heavy atoms remains challenging. ^[21] Butadiene, being the simplest conjugated organic molecule, has been studied extensively by experiments and various high-level theoretical methods. ^[22] Intersystem crossing in conjugated organic molecules is most conveniently viewed from pure electronic perspectives; yet, vibrational displacements may often drive these transitions. ^[23] While the recent developments in this field are mainly focused on the π-conjugated organic molecules. ^[24] conjugated organic molecules with cyclic topology) is highlighted via model computations and analysis of the available crystalline structure of N,N-dimethylaza[8]CPP. ^[25] Chemosensors are the conjugated organic molecules, which upon interacting with analyte produce detectable optical responses [6]. ^[26] Thus, future coverage-dependent studies should aim to gain insights into the impact of these complex interactions on the self-assembly of π-conjugated organic molecules on metal surfaces. ^[27] Excited electronic states of small and large π-conjugated organic molecules can be described within ab initio many-body perturbation theory, notably by the GW approximation for the electron self-energy operator combined with the Bethe-Salpeter equation for correlated electron-hole excitations. ^[28] This work further illustrates that introducing conjugated organic molecules as templates is conducive to achieving semiconducting hybrid halometallates with narrow band gaps. ^[29] Particularly, luminescent π-conjugated organic molecules that possess an efficient solid-state emission are excellent candidates for optoelectronic devices. ^[30] Para-quinodimethane (pQDM) is a fundamental structural component in many π-conjugated organic molecules and materials. ^[31] A novel water-soluble D-π-A-π-D conjugated organic molecule, 3,5-di-2′,4′,6′-trihydrolxyl phenyl azo-triazole, was identified and developed, combining conjugated azo as colorimetric chromophore and multidentate hydroxyl and triazolyl groups as multiple receptors to chelate Cu2+. ^[32] We demonstrate that this approach yields accurate results in comparison to other commonly used DFT-based diabatization methods across a wide array of electron and hole transfer processes occurring in systems ranging from conjugated organic molecules, such as thiophene and pentacene, to DNA base pairs. ^[33] We study the influence of polarity on the binding and diffusion of single conjugated organic molecules on the inorganic (10-10) zinc oxide surface by means of all-atom molecular dynamics simulations at room temperature and above. ^[34]
据我们所知，这项工作首先提供了一种通过表面包覆氨基共轭有机分子来提高钛金属-有机骨架（MOFs）光催化性能的简便方法，并为混合降解有机物提供了新思路。废水中的 MOFs 材料。 ^[1] 近年来，由于对化学键和独特的光学、电学和磁学性质的基本认识，π共轭有机分子中的双自由基得到了广泛的研究。 ^[2] π-共轭有机分子使包括光伏、发光二极管、晶体管和半导体在内的可持续光电子学的最新进展成为可能。 ^[3] 通过石墨烯和金属与具有p轨道的共轭有机分子的桥接，成功地建立了石墨烯/Cu界面中的离域共轭π键，从而构建了新的电子导热途径。 ^[4] 一种新型共轭有机分子由给电子单元（给电子苯并[1,2-b:5,4-b']二噻吩）和吸电子基团（氰基和吡啶）构建并制成片状晶体。 ^[5] 在没有额外工艺的情况下，最近引入了通过真空沉积形成的有机纳米透镜阵列（NLA，具有曲面的覆盖层），它导致 π 共轭有机分子的自发结晶并导致表面张力的增加。实现顶发射有机发光二极管的高量产性和高光提取效率。 ^[6] 本文主要涉及利用钯设计和合成三种新型的含有1,3,4-恶二唑单元的共轭有机分子（简称CHEM-6(a-c)），具有Donor-π-Acceptor-π'-Donor'结构。催化铃木交叉偶联反应。 ^[7] 线性、sp 杂化、一维 (1D) 全碳线在概念上是最简单的 π 共轭有机分子。 ^[8] 该方法通过计算共轭有机分子和双金属化合物的自旋态能量和间隙并与相应的 CAS-PDFT 值进行比较来测试。 ^[9] 独特的 [3+2] 环化产物用于合成高度共轭的有机分子，这是传统方法难以获得甚至无法获得的。 ^[10] 一种基于二苯基氧化膦的共轭有机分子，((1,3,5-triazine-2,4,6-triyl)tris(benzo-3,1-diyl))tris(diphenylphosphine oxide) (PO-T2T)，掺杂到 ZnO 中以改善倒置有机太阳能电池 (OSC) 中电子传输层 (ETL) 的特性。 ^[11] 我们报告了一种基于三芳基硼烷的 p-π* 共轭有机分子作为具有独特醇溶性的 n 型有机半导体。 ^[12] 总结了各种纳米纤维异质结结构，包括无机金属氧化物、碳材料、共轭有机分子和功能聚合物。 ^[13] org ，并专注于在绿色化学、有机太阳能电池和有机氧化还原液流电池中应用的光响应 π 共轭有机分子。 ^[14] 为了揭示金属配位对 π 共轭有机分子中电荷传输和长度依赖性电导衰减的影响，将 trans-Ru(dppe)2 (dppe = 1,2-bis(diphenylphosphino)ethane) 植入具有各种使用甲硫醇（-SMe）作为锚定基团构建Au-分子-Au结的乙炔基的数量。 ^[15] 对于低成本的可印刷电子电路，通过溶液工艺顺序沉积n型非晶金属氧化物半导体和p型聚噻吩基π共轭有机分子，其对应的p沟道和n沟道TFT性能表现出较好的平衡的双极电荷传输，具有超过 1cm2V-1s-1 的高空穴和电子迁移率。 ^[16] 考虑到为光电、光子和化学传感应用创建异质结，通过由 B 原子介导的非共价稳定相互作用来修改 2D BP 和共轭有机分子之间的界面处的电子结构特别有吸引力。 ^[17] 在这里，我们报告了在具有含甲氧基的供体部分的电子供体-受体型 π- 共轭有机分子中由分子内光诱导电子转移 (PET) 引起的显着荧光猝灭。 ^[18] 本研究的目的是提供对 D/A/D π-共轭有机分子的氧化还原途径的透彻理解，以便在有机电致变色器件中具有潜在应用。 ^[19] 共轭有机分子的自聚集通过空间要求基团的功能化得到抑制，并获得了单晶有机-钙钛矿混合量子阱（低至单晶胞厚度）。 ^[20] 生产不含重原子的 π 共轭有机分子三联体仍然具有挑战性。 ^[21] 丁二烯作为最简单的共轭有机分子，通过实验和各种高级理论方法得到了广泛的研究。 ^[22] 从纯电子的角度来看，共轭有机分子中的系间交叉是最方便的。然而，振动位移可能经常推动这些转变。 ^[23] 而该领域的最新发展主要集中在π共轭有机分子上。 ^[24] nan ^[25] nan ^[26] nan ^[27] nan ^[28] nan ^[29] nan ^[30] nan ^[31] nan ^[32] nan ^[33] nan ^[34]

conjugated organic polymer 共轭有机聚合物

Here, a two-dimensional olefin-linked conjugated organic polymer was prepared via the Knoevenagel condensation reaction. ^[1] Introducing the benefits of microporous polymers into the extended π-conjugated organic polymer gives rise to novel materials, namely, conjugated microporous polymers (CMPs), which endow even more intriguing properties/applications, especially in optoelectronics, energy storage, and sensors. ^[2] Conjugated organic polymers (COPs) have been excellent candidates because the conjugated structure occupied π structure that was useful to develop light-emitting materials. ^[3] The enhancement of photoluminescence through formation of molecular aggregates in organic oligomers and conjugated organic polymers is reviewed. ^[4] Recently, great progress has been achieved in the design and preparation of conjugated organic polymer photocatalysts for hydrogen generation. ^[5] Herein, we reported a series of donor-π-acceptor conjugated organic polymers (COPs) using anthracene, cobalt-coordinated bipyridyl and benzene as donor, acceptor, and π linker units, respectively. ^[6] In the present study, we theoretically determine the optoelectronic, electronic, nonlinear optical (NLO) and thermodynamic properties of new materials from the conjugated organic polymer poly (3,4-ethylenedioxythiophene) (PEDOT) doped with halogens (fluorine and chlorine), combined with the organic semiconductor 4-[2-(2-N, N-dihydroxy amino thiophene) vinyl] benzenamine (DATVB). ^[7] Herein, alkoxylation chemistry is introduced as a "one-stone-three-birds" solution for exploring a new family of highly-fluorescent octupolar 2D-conjugated organic polymers/frameworks (OCOPs/OCOFs) combining far-red emission, high fluorescence quantum yield (QY), and strong two-photon absorption (TPA). ^[8] A series of porphyrin-based D-A type conjugated organic polymer (COP) nanotubes MTAPP-BT (M= H2, Zn, Cu, Fe) were synthesized through acid-catalyzed Schiff base reaction between metalloporphyrins (MTAPP) and benzothiadiazole (BT) units. ^[9] Conjugated organic polymers have shown potential as photocatalysts for hydrogen production by water splitting. ^[10] Herein, we present amide-bridged conjugated organic polymers (amide-COPs) prepared via self-condensation of amino nitriles in combination with hydrolysis, for the photoreduction of CO2 with H2O without any photosensitizers or sacrificial reagents under visible light irradiation. ^[11] Here, we report an aqueous polymer-air battery using conjugated organic polymer poly(1,4-anthraquinone) (P14AQ) in situ polymerized on carbon nanotubes (CNTs) as the anode and spinel cobalt manganese oxide supported on CNTs (CMO@CNT) as the catalyzed cathode. ^[12] Up to now, conjugated organic polymers as organic semiconductors have received more and more attention on the direct conversion of water to hydrogen energy. ^[13] Further assembling conjugated organic polymers with TiO2 as charge transferring mediate can remarkably boost their photocatalytic activities to more than 8 times (1333 vs. ^[14] Conjugated organic polymers have been considered interesting materials for various technological applications, mainly due to their unique optoelectronic properties and the variety of methods employed in their synthesis. ^[15] Polyindole-based hybrid composites are being recognized as a promising candidate to be used in energy storage field along with other conjugated organic polymers. ^[16] Carbon-based semiconductors such as conjugated organic polymers are of potential use in the development of spintronic devices and spin-based information processing. ^[17] Herein, we report an organic hybridized photocatalyst (termed as COP-TF@CNi2P), carbon-encapsulated nickel phosphide as cocatalyst loaded on fully conjugated organic polymer, which is applied for stable and efficient H2 generation from seawater splitting. ^[18] Donor–acceptor (D–A) type conjugated organic polymers exhibited great potential for photocatalytic hydrogen evolution due to their diverse synthetic approaches, tunable energy band, and electronic structure. ^[19] Moreover, the acetylenic carbon-rich polymer possessed the superior features of being cost-effective in preparation and machinable in device development, which sheds light on the exploration of an advanced PEC sensing platform based on conjugated organic polymers for the bioanalysis of valuable analytes. ^[20] 98×104M-1) and mimic the mechanism like conjugated organic polymer. ^[21]
在此，通过 Knoevenagel 缩合反应制备了二维烯烃连接的共轭有机聚合物。 ^[1] 将微孔聚合物的优点引入扩展的 π 共轭有机聚合物中产生了新型材料，即共轭微孔聚合物 (CMPs)，它赋予了更多有趣的特性/应用，特别是在光电子、能量存储和传感器方面。 ^[2] 共轭有机聚合物 (COP) 已成为优秀的候选者，因为共轭结构占据了可用于开发发光材料的 π 结构。 ^[3] 综述了通过在有机低聚物和共轭有机聚合物中形成分子聚集体来增强光致发光。 ^[4] 近年来，共轭有机聚合物光催化剂的设计和制备取得了很大进展。 ^[5] 在此，我们报道了一系列分别使用蒽、钴配位联吡啶和苯作为供体、受体和 π 接头单元的供体-π-受体共轭有机聚合物 (COP)。 ^[6] 在本研究中，我们从理论上确定了掺杂卤素（氟和氯）的共轭有机聚合物聚（3,4-乙烯二氧噻吩）（PEDOT）的新材料的光电、电子、非线性光学（NLO）和热力学性质，结合与有机半导体4-[2-(2-N,N-二羟基氨基噻吩)乙烯基]苯胺(DATVB)。 ^[7] 本文介绍了烷氧基化化学作为“一石三鸟”的解决方案，用于探索结合远红光发射、高荧光量子产率的新型高荧光八极二维共轭有机聚合物/框架 (OCOPs/OCOFs) （QY）和强双光子吸收（TPA）。 ^[8] 通过金属卟啉（MTAPP）与苯并噻二唑（BT）单元之间的酸催化席夫碱反应，合成了一系列基于卟啉的D-A型共轭有机聚合物（COP）纳米管MTAPP-BT（M=H2、Zn、Cu、Fe）。 ^[9] 共轭有机聚合物已显示出作为光催化剂用于水分解制氢的潜力。 ^[10] nan ^[11] 在这里，我们报告了一种水性聚合物-空气电池，使用在碳纳米管 (CNT) 上原位聚合的共轭有机聚合物聚 (1,4-蒽醌)​​ (P14AQ) 作为阳极和负载在 CNT 上的尖晶石钴锰氧化物 (CMO@CNT)作为催化阴极。 ^[12] 迄今为止，作为有机半导体的共轭有机聚合物在水直接转化为氢能方面越来越受到关注。 ^[13] 以 TiO2 作为电荷转移介质进一步组装共轭有机聚合物可以显着提高其光催化活性至 8 倍以上（1333 vs. ^[14] 共轭有机聚合物被认为是各种技术应用的有趣材料，主要是由于它们独特的光电特性和合成方法的多样性。 ^[15] 聚吲哚基杂化复合材料被认为是与其他共轭有机聚合物一起用于储能领域的有希望的候选材料。 ^[16] nan ^[17] nan ^[18] 供体-受体（D-A）型共轭有机聚合物由于其多样化的合成方法、可调谐的能带和电子结构，在光催化析氢方面表现出巨大的潜力。 ^[19] nan ^[20] nan ^[21]

conjugated organic material 共轭有机材料

The optoelectronic properties of functional π-conjugated organic materials are affected by their ability to self-assemble within thin films of devices. ^[1] This work further expands the scope of this reaction to thiophenes, which were able to undergo further functionalization and polymerization, highlighting the potential of these molecules in conjugated organic materials. ^[2] Isoindigo (IID) has been developed as an electron deficient moiety for high-performance conjugated organic materials, especially for constituting donor–acceptor (D-A) type conjugated polymers. ^[3] It is crucial to understand the light absorption features and electronic structures of conjugated organic materials for their optoelectronic applications. ^[4] Electronic devices relying on the combination of different conjugated organic materials are considerably appealing for their potential use in many applications such as photovoltaics, light emission, and digital/analog circuitry. ^[5] Electronic structures, which play a key role in determining electrical and optical properties of π-conjugated organic materials, have attracted tremendous interest. ^[6] Oxidative C-H/C-H coupling is a promising synthetic route for the streamlined construction of conjugated organic materials for optoelectronic applications. ^[7] Dithienosilole (DTS) and dithienogermole (DTG) are useful building units of π-conjugated organic materials. ^[8] The advent of multiple exciton harvesting schemes and prolonging exciton lifetimes to improve performance attributes of solar cells based on conjugated organic materials presents some interesting challenges that must be overcome in order to realize the full potential of these strategies. ^[9] 73 × 104 L mol−1, respectively, which are significantly higher than those of most of the fluorescent probes based on metal–organic frameworks and conjugated organic materials. ^[10] Polarized species generally exist in conjugated organic materials and play an important role in the photophysics procedure; therefore, understanding these species is beneficial to designing novel OSL materials. ^[11] π-Conjugated organic materials possess a wide range of tunable optoelectronic properties which give rise to many device applications. ^[12] This paper describes a method for preparation of 2,6-dibromo-thieno[3,2-b]thieno[2',3':4,5]thieno[2,3-d]thiophene (tetrathienoacene), an important building block of conjugated organic materials. ^[13] Conjugated organic materials are relevant to functional photonic nanostructures because of their rich molecular structure-processing-property relationships and their propensity for strong, visible-frequency excitonic transitions. ^[14] Its synthetic value has been substantiated by concise preparation of several π-conjugated organic materials and pharmacophores. ^[15]
功能性 π 共轭有机材料的光电特性受其在器件薄膜内自组装的能力的影响。 ^[1] 这项工作进一步将该反应的范围扩大到噻吩，噻吩能够进行进一步的功能化和聚合，突出了这些分子在共轭有机材料中的潜力。 ^[2] 异靛蓝 (IID) 已被开发为高性能共轭有机材料的缺电子部分，特别是用于构成供体-受体 (D-A) 型共轭聚合物。 ^[3] nan ^[4] nan ^[5] nan ^[6] 氧化 C-H/C-H 偶联是一种有前途的合成路线，可用于流线型构建用于光电应用的共轭有机材料。 ^[7] Dithienosilole (DTS) 和 dithienogermole (DTG) 是 π- 共轭有机材料的有用构建单元。 ^[8] 多个激子收集方案的出现和延长激子寿命以提高基于共轭有机材料的太阳能电池的性能属性提出了一些有趣的挑战，必须克服这些挑战才能充分发挥这些策略的潜力。 ^[9] 73 × 104 L mol-1，显着高于大多数基于金属-有机框架和共轭有机材料的荧光探针。 ^[10] 极化物质通常存在于共轭有机材料中，并在光物理过程中发挥重要作用；因此，了解这些物种有利于设计新型 OSL 材料。 ^[11] π-共轭有机材料具有广泛的可调谐光电特性，可用于许多器件应用。 ^[12] nan ^[13] nan ^[14] nan ^[15]

conjugated organic ligand 共轭有机配体

This work has proven the effectiveness of improving the photoelectric performances of AIP via s-triazine and its derivatives and also suggested the potential risks of reducing the photoelectric performance of AIP due to inappropriate substituents in conjugated organic ligands. ^[1] A selenophene-containing conjugated organic ligand, 2-(4'-methyl-5'-(5-(3-methylthiophen-2-yl)selenophen-2-yl)-[2,2'-bithiophen]-5-yl)ethan-1-aminium (STm), was synthesized and incorporated into a Sn(II)-based two-dimensional perovskite, (STm)2SnI4. ^[2] Coordination polymers constructed from conjugated organic ligands and metal ions with a d10 electronic configuration exhibit intriguing properties for chemical sensing and photochemistry. ^[3] What’s more, the third-order non-linear optical (NLO) properties of the two compounds were detected in detail due to the existence of a large number of conjugated organic ligands. ^[4] A luminescent Zr(IV)-based metal-organic framework (MOF), with the underlying fcu topology, encompassing a π-conjugated organic ligand with a thiadiazole functionality, exhibits an unprecedented low detection limit of 66 nM for amines in aqueous solution. ^[5] Two novel POM-based huge clusters modified by conjugated organic ligands (DAPSC), {Fe10P4W32} and {Fe8MoW18}, have been successfully isolated. ^[6] Recently, cadmium(II) MOFs received more attentions due to their intriguing properties for chemical sensing due to the combination of conjugated organic ligands and its d10 electronic configuration. ^[7]
这项工作已经证明了通过 s-三嗪及其衍生物提高 AIP 光电性能的有效性，同时也表明了由于共轭有机配体中不合适的取代基而降低 AIP 光电性能的潜在风险。 ^[1] 含硒吩的共轭有机配体，2-(4'-methyl-5'-(5-(3-methylthiophen-2-yl)selenophen-2-yl)-[2,2'-bithiophen]-5-yl )ethan-1-aminium (STm) 被合成并结合到基于 Sn(II) 的二维钙钛矿 (STm)2SnI4 中。 ^[2] 由具有 d10 电子配置的共轭有机配体和金属离子构成的配位聚合物在化学传感和光化学方面表现出有趣的特性。 ^[3] 更重要的是，由于存在大量共轭有机配体，对这两种化合物的三阶非线性光学（NLO）特性进行了详细检测。 ^[4] 具有潜在 fcu 拓扑结构的发光 Zr(IV) 基金属有机框架 (MOF) 包含具有噻二唑官能团的 π 共轭有机配体，对水溶液中的胺表现出前所未有的低检测限 66 nM。 ^[5] 已成功分离出两个由共轭有机配体 (DAPSC) 修饰的新型 POM 基巨簇 {Fe10P4W32} 和 {Fe8MoW18}。 ^[6] nan ^[7]

conjugated organic dye 共轭有机染料

D-π-A conjugated organic dyes made of different donor/acceptor moieties namely Hexylcarbazole (HC), 4,7- Dithiophene-2-yl) benzo[c][1,2,5]thiadiazole (DTBT) and Poly-4-(5-(9-Hexyl-9H-carbazol-2-yl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole (PCTB) were prepared by coupling reactions. ^[1] The molecular structure, UV-Visible spectra, and optical properties of D-π-A conjugated organic dye molecules (Disperse Red 1 (DR1) and Disperse Red 73 (DR73)) were analyzed using Density Functional Theory (DFT) and Time-Dependent Density Functional Theory (TD-DFT) and compared with Azobenzene molecule to study the effect of Donor and Acceptor substituents on the molecular properties. ^[2] Conversely, we report here the blue-shifting effect on the absorption and emission band by employing a heavier atom in the same element group based on the conjugated organic dye. ^[3] In this study, a novel, simple conjugated organic dye, N-tert-butyldimethylsilyl-3,6-diiodocarbazole (CA-TBMDS) was developed and used for the first time as a colorimetric sensor for fluoride. ^[4] The molecular structure, UV-visible spectra, and optical properties of D-π-A conjugated organic dye molecules (Disperse Red 1 (DR1) and Disperse Red 73 (DR73)) were analyzed using density functional theory (DFT) and time-dependent density functional theory (TD-DFT) and compared with azobenzene molecule to study the effect of donor and acceptor substituents on the molecular properties. ^[5] The composite materials are synthesized by the functionalization of CNTs with highly conjugated organic dye-sensitized polymeric molecules. ^[6] We report a novel donor-acceptor-donor conjugated organic dye as the liquid gain material for the sensing of nitryl aromatic explosives by optofluidic laser. ^[7]
D-π-A 共轭有机染料由不同的供体/受体部分组成，即己基咔唑 (HC)、4,7- 二噻吩-2-基) 苯并[c][1,2,5]噻二唑 (DTBT) 和 Poly-4 -(5-(9-Hexyl-9H-carbazol-2-yl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole (PCTB) 通过偶联反应制备。