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Electrostatically enhanced π-π interactions are observed in 1–3 between the phenyl rings of 2-ClBz and pyridine ring of 3-CNpy of the monomeric units of the complexes.
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We have also studied electrostatically enhanced π⋯π (either conventional or involving the chelate ring) interactions observed in the solid state of both compounds and analyzed them using DFT calculations, molecular electrostatic potential surface and Bader's theory of atoms in molecules.
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Mechanistically, interaction of negatively charged, human plasma corona-covered, metal-based nanoparticles with pathogends was electrostatically enhanced by lowering pH-dependently bacteria's negative surface charge.
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