Introduction to Chelation Enhanced

What is/are Chelation Enhanced?

Chelation Enhanced - The involvement of chelation enhanced fluorescence (CHEF), aggregation induced emmision (AIE) and aggregation caused quenching (ACQ) during the course of gelation has been well established by fluorescence experiments. ^[1] The NABI forms chelate with Zn2+ to inhibit internal charge transfer (ICT) and CHN isomerisation resulting chelation enhanced fluorescence (CHEF). ^[2] In this report, we develop a novel Zn2+-specific light-up fluorescent probe based on intramolecular charge transfer combined with chelation enhanced fluorescence induced by structural transformation. ^[3] Phenylenevinylene terpyridine (mepvpt) shows chelation enhanced fluorescence (CHEF) with Cd(II) and chelation quenched fluorescence (CHQF) with Zn(II), respectively. ^[4] In DMSO : H2O (1 : 1, v/v), the fluorescence of DA at 483 nm was blue shifted and enhanced at 474 nm along with a new shoulder peak appearing at 411 nm selectively in the presence of Cu2+ among the other tested metal ions due to the chelation enhanced fluorescence (CHEF) effect. ^[5] The results of DFT/B3LYP calculations showed that the binding with Al3+ and Fe3+ makes the sensor L accompanied a mechanism with the inhibition of C N isomerization (cis-trans) and the activation of chelation enhanced fluorescence (CHEF). ^[6] The sequential binding of chromate ions to 2 inhibits the ESIPT and causes chelation enhanced quenching (CHEQ) of the fluorescence. ^[7] The fluorescence enhancement response of L towards Al3+ along with a large blue shift (Δλ = ∼157 nm) may be attributed to the formation of the L–Al3+ complex, which results in the inhibition of excited state intramolecular proton transfer (ESIPT) and CN isomerisation as well as the chelation enhanced fluorescence (CHEF). ^[8] The interaction of Hg2+ ions with functionalized MMT@TiO2 induced aggregation of nanoparticles causing chelation enhanced fluorescence. ^[9] The results demonstrate instant, stable in time and reproducible, colorimetric turn-on response with superb selectivity and sensitivity of Hbdhn towards Zn2+ , based on chelation enhanced fluorescence mechanism. ^[10] Based on the chelation enhanced fluorescence (CHEF) mechanisms, Probe 1 exhibited a fluorescence “turn-on” switch signal for Cu2+. ^[11] This chelation enhanced fluorescence - photoinduced electron transfer (CHEF-PET) based TAAC probe has been applied for its analytical application in real samples such as Mn2+ from blood serum, Cr3+ and F- from industrial effluent with 94–99% recovery. ^[12] The sensor (L) form a 1:2 complex with Al3+ (L-Al3+) which resulted in the significant fluorescence enhancement at 544 nm due to the chelation enhanced fluorescence (CHEF) effect. ^[13] The results of experiments and DFT/TDDFT calculations revealed that the chemosensor SQ-BH obeyed a turn on mechanism which was associated with the inhibited photoinduced electron transfer (PET), the enhanced intramolecular charge transfer (ICT) and the activated chelation enhanced fluorescence (CHEF). ^[14] The turn off sensor of BENZPYR is related to chelation enhanced quenching (CHEQ) and intramolecular charge transfer (ICT) processes were serve as excellent fluorescent detection of Cu2+ ions in DMF medium. ^[15] The recognition mode of peptide-based fluorescent chemical sensors can be easily realized by different recognition mechanisms, such as photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET) and chelation enhanced fluorescence (CHEF). ^[16] Upon interaction with various f-metal and other selected metals from s, p, and d-block elements, the fluorescence of L is selectively enhanced in the presence of Lu3+ due to the chelation enhanced fluorescence (CHEF) effects. ^[17] Chelation enhanced fluorescence by Cd(II) has been established by fluorescence experiments. ^[18] Chemosensor Z showed highly selective and sensitive for the detection of Al3+ in DMF/H2O (v/v, 4/6) attributed to the combined contribution of excited-state intramolecular proton transfer (ESIPT), C N isomerization and chelation enhanced fluorescence (CHEF). ^[19]

photoinduced electron transfer

This chelation enhanced fluorescence - photoinduced electron transfer (CHEF-PET) based TAAC probe has been applied for its analytical application in real samples such as Mn2+ from blood serum, Cr3+ and F- from industrial effluent with 94–99% recovery. ^[1] The results of experiments and DFT/TDDFT calculations revealed that the chemosensor SQ-BH obeyed a turn on mechanism which was associated with the inhibited photoinduced electron transfer (PET), the enhanced intramolecular charge transfer (ICT) and the activated chelation enhanced fluorescence (CHEF). ^[2] The recognition mode of peptide-based fluorescent chemical sensors can be easily realized by different recognition mechanisms, such as photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET) and chelation enhanced fluorescence (CHEF). ^[3]

intramolecular charge transfer

In this report, we develop a novel Zn2+-specific light-up fluorescent probe based on intramolecular charge transfer combined with chelation enhanced fluorescence induced by structural transformation. ^[1] The turn off sensor of BENZPYR is related to chelation enhanced quenching (CHEQ) and intramolecular charge transfer (ICT) processes were serve as excellent fluorescent detection of Cu2+ ions in DMF medium. ^[2]

chelation enhanced fluorescence

The involvement of chelation enhanced fluorescence (CHEF), aggregation induced emmision (AIE) and aggregation caused quenching (ACQ) during the course of gelation has been well established by fluorescence experiments. ^[1] The NABI forms chelate with Zn2+ to inhibit internal charge transfer (ICT) and CHN isomerisation resulting chelation enhanced fluorescence (CHEF). ^[2] In this report, we develop a novel Zn2+-specific light-up fluorescent probe based on intramolecular charge transfer combined with chelation enhanced fluorescence induced by structural transformation. ^[3] Phenylenevinylene terpyridine (mepvpt) shows chelation enhanced fluorescence (CHEF) with Cd(II) and chelation quenched fluorescence (CHQF) with Zn(II), respectively. ^[4] In DMSO : H2O (1 : 1, v/v), the fluorescence of DA at 483 nm was blue shifted and enhanced at 474 nm along with a new shoulder peak appearing at 411 nm selectively in the presence of Cu2+ among the other tested metal ions due to the chelation enhanced fluorescence (CHEF) effect. ^[5] The results of DFT/B3LYP calculations showed that the binding with Al3+ and Fe3+ makes the sensor L accompanied a mechanism with the inhibition of C N isomerization (cis-trans) and the activation of chelation enhanced fluorescence (CHEF). ^[6] The fluorescence enhancement response of L towards Al3+ along with a large blue shift (Δλ = ∼157 nm) may be attributed to the formation of the L–Al3+ complex, which results in the inhibition of excited state intramolecular proton transfer (ESIPT) and CN isomerisation as well as the chelation enhanced fluorescence (CHEF). ^[7] The interaction of Hg2+ ions with functionalized MMT@TiO2 induced aggregation of nanoparticles causing chelation enhanced fluorescence. ^[8] The results demonstrate instant, stable in time and reproducible, colorimetric turn-on response with superb selectivity and sensitivity of Hbdhn towards Zn2+ , based on chelation enhanced fluorescence mechanism. ^[9] Based on the chelation enhanced fluorescence (CHEF) mechanisms, Probe 1 exhibited a fluorescence “turn-on” switch signal for Cu2+. ^[10] This chelation enhanced fluorescence - photoinduced electron transfer (CHEF-PET) based TAAC probe has been applied for its analytical application in real samples such as Mn2+ from blood serum, Cr3+ and F- from industrial effluent with 94–99% recovery. ^[11] The sensor (L) form a 1:2 complex with Al3+ (L-Al3+) which resulted in the significant fluorescence enhancement at 544 nm due to the chelation enhanced fluorescence (CHEF) effect. ^[12] The results of experiments and DFT/TDDFT calculations revealed that the chemosensor SQ-BH obeyed a turn on mechanism which was associated with the inhibited photoinduced electron transfer (PET), the enhanced intramolecular charge transfer (ICT) and the activated chelation enhanced fluorescence (CHEF). ^[13] The recognition mode of peptide-based fluorescent chemical sensors can be easily realized by different recognition mechanisms, such as photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET) and chelation enhanced fluorescence (CHEF). ^[14] Upon interaction with various f-metal and other selected metals from s, p, and d-block elements, the fluorescence of L is selectively enhanced in the presence of Lu3+ due to the chelation enhanced fluorescence (CHEF) effects. ^[15] Chelation enhanced fluorescence by Cd(II) has been established by fluorescence experiments. ^[16] Chemosensor Z showed highly selective and sensitive for the detection of Al3+ in DMF/H2O (v/v, 4/6) attributed to the combined contribution of excited-state intramolecular proton transfer (ESIPT), C N isomerization and chelation enhanced fluorescence (CHEF). ^[17]

chelation enhanced quenching

The sequential binding of chromate ions to 2 inhibits the ESIPT and causes chelation enhanced quenching (CHEQ) of the fluorescence. ^[1] The turn off sensor of BENZPYR is related to chelation enhanced quenching (CHEQ) and intramolecular charge transfer (ICT) processes were serve as excellent fluorescent detection of Cu2+ ions in DMF medium. ^[2]