Ii Analogues
II 아날로그

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10.1002/chem.201901237

To our surprise, contrary to their ZnII analogues, 2 and 3 were not found to be photosalient.

놀랍게도 ZnII 유사체와 달리 2와 3은 광 돌출이 발견되지 않았습니다.

Solid-State Photochemical [2+2] Cycloaddition Reaction of MnII Complexes.

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10.1002/anie.201900909

A range of FeIII analogues were also characterized.

FeIII 유사체의 범위도 특성화되었습니다.

A Brønsted-Ligand-Based Iron Complex as a Molecular Switch with Five Accessible States.

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10.1039/c9dt03292d

A family of new structurally manipulable pentagonal-bipyramidal (PBP) DyIII SMMs, with formulas [Dy(Hbpen)(Cl)3] (1), [Dy(Hbpen)Cl(OPhBr2NO2)2] (2), [Dy(Hbpen)(OPhCl2NO2)3] (3) and [Dy(Mbpen)(Cl)3] (1CH3), were controllably prepared based on a H-substituted amine-based ligand N,N'-bis(2-pyridylmethyl)-ethylenediamine (Hbpen) or a CH3-substituted amine-based ligand N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)-ethylenediamine (Mbpen) and are compared with the reported imine-based DyIII analogues (1'-3').

[Dy(Hbpen)(Cl)3](1), [Dy(Hbpen)Cl(OPhBr2NO2)2](2), [Dy(Hbpen) 공식을 사용하여 구조적으로 조작 가능한 새로운 오각형 쌍뿔형(PBP) DyIII SMM 제품군 )(OPhCl2NO2)3](3) 및 [Dy(Mbpen)(Cl)3](1CH3), H-치환된 아민계 리간드 N,N'-비스(2-피리딜메틸)-에틸렌디아민을 기반으로 제어 가능하게 제조됨 (Hbpen) 또는 CH3-치환된 아민계 리간드 N,N'-디메틸-N,N'-비스(2-피리딜메틸)-에틸렌디아민(Mbpen) 및 보고된 이민계 DyIII 유사체(1'- 삼').

Fine-tuning the type of equatorial donor atom in pentagonal bipyramidal Dy(iii) complexes to enhance single-molecule magnet properties.

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10.1002/chem.201806192

The corresponding Gd3+ complexes possess one coordinated water molecule, as confirmed by luminescence lifetime measurements on the EuIII and TbIII analogues.

상응하는 Gd3+ 복합체는 EuIII 및 TbIII 유사체에 대한 발광 수명 측정에 의해 확인된 바와 같이 하나의 조정된 물 분자를 보유합니다.

Gadolinium(III)-Based Dual 1 H/19 F Magnetic Resonance Imaging Probes.

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Ii Analogues II 아날로그 - To our surprise, contrary to their ZnII analogues, 2 and 3 were not found to be photosalient. [1] A range of FeIII analogues were also characterized. [2] A family of new structurally manipulable pentagonal-bipyramidal (PBP) DyIII SMMs, with formulas [Dy(Hbpen)(Cl)3] (1), [Dy(Hbpen)Cl(OPhBr2NO2)2] (2), [Dy(Hbpen)(OPhCl2NO2)3] (3) and [Dy(Mbpen)(Cl)3] (1CH3), were controllably prepared based on a H-substituted amine-based ligand N,N'-bis(2-pyridylmethyl)-ethylenediamine (Hbpen) or a CH3-substituted amine-based ligand N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)-ethylenediamine (Mbpen) and are compared with the reported imine-based DyIII analogues (1'-3'). [3] The corresponding Gd3+ complexes possess one coordinated water molecule, as confirmed by luminescence lifetime measurements on the EuIII and TbIII analogues. [4]
놀랍게도 ZnII 유사체와 달리 2와 3은 광 돌출이 발견되지 않았습니다. [1] FeIII 유사체의 범위도 특성화되었습니다. [2] [Dy(Hbpen)(Cl)3](1), [Dy(Hbpen)Cl(OPhBr2NO2)2](2), [Dy(Hbpen) 공식을 사용하여 구조적으로 조작 가능한 새로운 오각형 쌍뿔형(PBP) DyIII SMM 제품군 )(OPhCl2NO2)3](3) 및 [Dy(Mbpen)(Cl)3](1CH3), H-치환된 아민계 리간드 N,N'-비스(2-피리딜메틸)-에틸렌디아민을 기반으로 제어 가능하게 제조됨 (Hbpen) 또는 CH3-치환된 아민계 리간드 N,N'-디메틸-N,N'-비스(2-피리딜메틸)-에틸렌디아민(Mbpen) 및 보고된 이민계 DyIII 유사체(1'- 삼'). [3] 상응하는 Gd3+ 복합체는 EuIII 및 TbIII 유사체에 대한 발광 수명 측정에 의해 확인된 바와 같이 하나의 조정된 물 분자를 보유합니다. [4]