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10.1038/s41467-019-13679-0

As evidenced from detailed characterization and density functional theory (DFT) calculations, Y3Pd2 realizes negatively charged Pd species, a low work function and a high carrier density, which are expected to be beneficial for the efficient Suzuki coupling reaction of activated aryl halides with various coupling partners under mild conditions.

상세한 특성화 및 밀도 기능 이론(DFT) 계산에서 입증된 바와 같이, Y3Pd2는 음으로 하전된 Pd 종, 낮은 일함수 및 높은 캐리어 밀도를 실현하여 다양한 커플링을 갖는 활성 아릴 할라이드의 효율적인 스즈키 커플링 반응에 도움이 될 것으로 예상됩니다. 온화한 조건의 파트너.

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10.1039/c9ob01006h

The gem-silylboronate esters undergo efficient Suzuki-Miyaura cross-coupling with aryliodides and the silyl group of the product can be further functionalized.

gem-silylboronate esters는 아릴요오다이드와 효율적인 Suzuki-Miyaura 교차 결합을 거치며 제품의 실릴 그룹은 추가로 기능화될 수 있습니다.

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Efficient Suzuki 효율적인 스즈키

Efficient Suzuki 효율적인 스즈키

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Sep 14, 2024

Efficient Suzuki(효율적인 스즈키)란 무엇입니까?

Efficient Suzuki 효율적인 스즈키 - As evidenced from detailed characterization and density functional theory (DFT) calculations, Y3Pd2 realizes negatively charged Pd species, a low work function and a high carrier density, which are expected to be beneficial for the efficient Suzuki coupling reaction of activated aryl halides with various coupling partners under mild conditions. ^[1] The gem-silylboronate esters undergo efficient Suzuki-Miyaura cross-coupling with aryliodides and the silyl group of the product can be further functionalized. ^[2]
상세한 특성화 및 밀도 기능 이론(DFT) 계산에서 입증된 바와 같이, Y3Pd2는 음으로 하전된 Pd 종, 낮은 일함수 및 높은 캐리어 밀도를 실현하여 다양한 커플링을 갖는 활성 아릴 할라이드의 효율적인 스즈키 커플링 반응에 도움이 될 것으로 예상됩니다. 온화한 조건의 파트너. ^[1] gem-silylboronate esters는 아릴요오다이드와 효율적인 Suzuki-Miyaura 교차 결합을 거치며 제품의 실릴 그룹은 추가로 기능화될 수 있습니다. ^[2]