Complexes Bearing
컴플렉스 베어링
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Complexes Bearing sentence examples within type pincer ligand
A series of rhenium complexes bearing a pyridine-based PNP-type pincer ligand are synthesized from rhenium phosphine complexes as precursors.
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A series of rhenium complexes bearing a pyridine-based PNP-type pincer ligand are synthesized from rhenium phosphine complexes as precursors.
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Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions.
음이온성 피롤 기반 PNP형 집게 리간드를 포함하는 로듐 착물이 합성되고 온화한 반응 조건에서 분자 이질소를 트리스(트리메틸실릴)아민으로 변환하기 위한 효과적인 촉매로 작동하는 것으로 밝혀졌습니다.
Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions.
음이온성 피롤 기반 PNP형 집게 리간드를 포함하는 로듐 착물이 합성되고 온화한 반응 조건에서 분자 이질소를 트리스(트리메틸실릴)아민으로 변환하기 위한 효과적인 촉매로 작동하는 것으로 밝혀졌습니다.
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Complexes Bearing sentence examples within rare earth metal
In the quest for rare earth metal complexes with enhanced cancer chemotherapeutic properties, the discovery of seven lanthanide(iii) complexes bearing 8-hydroxyquinoline-N-oxide (NQ) and 1,10-phenanthroline (phen) ligands, i.
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In the quest for rare earth metal complexes with enhanced cancer chemotherapeutic properties, the discovery of seven lanthanide(iii) complexes bearing 8-hydroxyquinoline-N-oxide (NQ) and 1,10-phenanthroline (phen) ligands, i.
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A series of fluorenyl-based constrained-geometry-configuration (CGC) allyl-type rare earth metal monoalkyl complexes bearing the divalent anionic η3:η1-tert-butyl(dimethylfluorenylsilyl)amido (η3:η1-FluSiMe2NtBu) ligand (η3:η1-FluSiMe2NtBu)Ln(CH2SiMe3)(THF)2 (1–3) have been synthesized via the alkane elimination reaction between the FluHSiMe2NHtBu ligand and rare earth metal tri(trimethylsilylmethyl) complexes Ln(CH2SiMe3)3(THF)n.
2가 음이온 η3:η1-tert-부틸(디메틸플루오레닐실릴)아미도(η3:η1-FluSiMe2NtBu) 리간드(η3:η1- FluSiMe2NtBu)Ln(CH2SiMe3)(THF)2(1-3)은 FluHSiMe2NHtBu 리간드와 희토류 금속 tri(trimethylsilylmethyl) 착물 Ln(CH2SiMe3)3(THF)n 사이의 알칸 제거 반응을 통해 합성되었습니다.
A series of fluorenyl-based constrained-geometry-configuration (CGC) allyl-type rare earth metal monoalkyl complexes bearing the divalent anionic η3:η1-tert-butyl(dimethylfluorenylsilyl)amido (η3:η1-FluSiMe2NtBu) ligand (η3:η1-FluSiMe2NtBu)Ln(CH2SiMe3)(THF)2 (1–3) have been synthesized via the alkane elimination reaction between the FluHSiMe2NHtBu ligand and rare earth metal tri(trimethylsilylmethyl) complexes Ln(CH2SiMe3)3(THF)n.
2가 음이온 η3:η1-tert-부틸(디메틸플루오레닐실릴)아미도(η3:η1-FluSiMe2NtBu) 리간드(η3:η1- FluSiMe2NtBu)Ln(CH2SiMe3)(THF)2(1-3)은 FluHSiMe2NHtBu 리간드와 희토류 금속 tri(trimethylsilylmethyl) 착물 Ln(CH2SiMe3)3(THF)n 사이의 알칸 제거 반응을 통해 합성되었습니다.
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Complexes Bearing sentence examples within ring opening polymerization
A series of Al complexes bearing diethyl 2-((arylamino)methylene)malonate and diethyl 2-((alkylamino)methylene)malonate ligands (AMM ligands) were synthesized and their application in the ring-opening polymerization of e-caprolactone was studied.
디에틸 2-((아릴아미노)메틸렌)말로네이트 및 디에틸 2-((알킬아미노)메틸렌)말로네이트 리간드(AMM 리간드)를 함유하는 일련의 Al 착물을 합성하고 e-카프로락톤의 개환 중합에서의 적용을 연구하였다.
A series of Al complexes bearing diethyl 2-((arylamino)methylene)malonate and diethyl 2-((alkylamino)methylene)malonate ligands (AMM ligands) were synthesized and their application in the ring-opening polymerization of e-caprolactone was studied.
디에틸 2-((아릴아미노)메틸렌)말로네이트 및 디에틸 2-((알킬아미노)메틸렌)말로네이트 리간드(AMM 리간드)를 함유하는 일련의 Al 착물을 합성하고 e-카프로락톤의 개환 중합에서의 적용을 연구하였다.
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Three-coordinated Zn(II) complexes bearing sterically encumbered bidentate monoanionic [N,N−] pyridylamido ligands efficiently catalyze the ring opening polymerization of lactide (LA) and e-caprolactone (CL).
입체적으로 방해가 되는 두자리 모노음이온 [N,N-] 피리딜아미도 리간드를 포함하는 3-배위 Zn(II) 착물은 락티드(LA)와 e-카프로락톤(CL)의 개환 중합을 효율적으로 촉매합니다.
Three-coordinated Zn(II) complexes bearing sterically encumbered bidentate monoanionic [N,N−] pyridylamido ligands efficiently catalyze the ring opening polymerization of lactide (LA) and e-caprolactone (CL).
입체적으로 방해가 되는 두자리 모노음이온 [N,N-] 피리딜아미도 리간드를 포함하는 3-배위 Zn(II) 착물은 락티드(LA)와 e-카프로락톤(CL)의 개환 중합을 효율적으로 촉매합니다.
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Complexes Bearing sentence examples within 47 diphenyl 110
Here, we investigated the effects of the structure of the diphosphine ligands on the photosensitizing abilities using a series of Cu(I) complexes bearing 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (dmpp) and various diphosphine ligands in order to explore the suitable structure for the photosensitizing reactions.
여기에서 우리는 2,9-디메틸-4,7-디페닐-1,10-페난트롤린(dmpp)과 다양한 디포스핀을 함유하는 일련의 Cu(I) 착물을 사용하여 디포스핀 리간드의 구조가 감광 능력에 미치는 영향을 조사했습니다. 감광 반응에 적합한 구조를 탐색하기 위해 리간드.
Here, we investigated the effects of the structure of the diphosphine ligands on the photosensitizing abilities using a series of Cu(I) complexes bearing 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (dmpp) and various diphosphine ligands in order to explore the suitable structure for the photosensitizing reactions.
여기에서 우리는 2,9-디메틸-4,7-디페닐-1,10-페난트롤린(dmpp)과 다양한 디포스핀을 함유하는 일련의 Cu(I) 착물을 사용하여 디포스핀 리간드의 구조가 감광 능력에 미치는 영향을 조사했습니다. 감광 반응에 적합한 구조를 탐색하기 위해 리간드.
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Nine new copper(I) complexes bearing 1,3-bis(diphenylphosphino)propane (dppp) and 4,7-diphenyl-1,10-phenanthroline (batho) or 2,9-dimethyl-1,10-phenanthroline (neo) have been synthesized and characterized.
1,3-비스(디페닐포스피노)프로판(dppp) 및 4,7-디페닐-1,10-페난트롤린(바토) 또는 2,9-디메틸-1,10-페난트롤린(neo)을 포함하는 9개의 새로운 구리(I) 착물 합성 및 특성화되었습니다.
Nine new copper(I) complexes bearing 1,3-bis(diphenylphosphino)propane (dppp) and 4,7-diphenyl-1,10-phenanthroline (batho) or 2,9-dimethyl-1,10-phenanthroline (neo) have been synthesized and characterized.
1,3-비스(디페닐포스피노)프로판(dppp) 및 4,7-디페닐-1,10-페난트롤린(바토) 또는 2,9-디메틸-1,10-페난트롤린(neo)을 포함하는 9개의 새로운 구리(I) 착물 합성 및 특성화되었습니다.
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Complexes Bearing sentence examples within synthesized fully characterized
In the quest for therapeutic iron-based metallodrugs, two new mixed-ligand iron(iii) complexes bearing the tripodal aminobisphenolate ligand N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine (H2L) and hydroxyquinoline co-ligands, 8-hydroxyquinoline (8HQ) or 5-chloro-8-hydroxyquinoline (Cl8HQ), are synthesized, fully characterized and formulated as [Fe(L)(8HQ)] (1) and [Fe(L)(Cl8HQ)] (2), respectively.
치료용 철 기반 금속 약물에 대한 탐구에서 삼각 아미노비스페놀레이트 리간드 N,N-비스(3,5-디메틸-2-히드록시벤질)-N-(2-피리딜메틸)아민을 보유하는 2개의 새로운 혼합 리간드 철(iii) 착물 (H2L) 및 하이드록시퀴놀린 공동 리간드인 8-하이드록시퀴놀린(8HQ) 또는 5-클로로-8-하이드록시퀴놀린(Cl8HQ)이 합성되고, 완전히 특성화되고 [Fe(L)(8HQ)](1) 및 [Fe (L)(Cl8HQ)] (2), 각각.
In the quest for therapeutic iron-based metallodrugs, two new mixed-ligand iron(iii) complexes bearing the tripodal aminobisphenolate ligand N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine (H2L) and hydroxyquinoline co-ligands, 8-hydroxyquinoline (8HQ) or 5-chloro-8-hydroxyquinoline (Cl8HQ), are synthesized, fully characterized and formulated as [Fe(L)(8HQ)] (1) and [Fe(L)(Cl8HQ)] (2), respectively.
치료용 철 기반 금속 약물에 대한 탐구에서 삼각 아미노비스페놀레이트 리간드 N,N-비스(3,5-디메틸-2-히드록시벤질)-N-(2-피리딜메틸)아민을 보유하는 2개의 새로운 혼합 리간드 철(iii) 착물 (H2L) 및 하이드록시퀴놀린 공동 리간드인 8-하이드록시퀴놀린(8HQ) 또는 5-클로로-8-하이드록시퀴놀린(Cl8HQ)이 합성되고, 완전히 특성화되고 [Fe(L)(8HQ)](1) 및 [Fe (L)(Cl8HQ)] (2), 각각.
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Iridium complexes bearing pyridine triazolylidene ligands with variable steric hindrance, derived by the presence of an R group (R=H, Me, Et, nPr, iPr, Bu, and Oct) onto the N1‐nitrogen, have been synthesized, fully characterized and tested as water oxidation catalysts (WOCs), using chemical sacrificial oxidants (CAN and NaIO4) or in photocatalytic experiments ([Ru(bpy)3]Cl2 as phosensitizer and Na2S2O8 as an electron acceptor).
N1-질소에 대한 R 그룹(R=H, Me, Et, nPr, iPr, Bu 및 Oct)의 존재에 의해 유도된 가변 입체 장애를 갖는 피리딘 트리아졸릴리덴 리간드를 보유하는 이리듐 착물이 합성되고 완전히 특성화되었으며, 화학적 희생 산화제(CAN 및 NaIO4)를 사용하거나 광촉매 실험(감광제로 [Ru(bpy)3]Cl2 및 전자 수용체로 Na2S2O8)을 사용하여 물 산화 촉매(WOC)로 테스트되었습니다.
Iridium complexes bearing pyridine triazolylidene ligands with variable steric hindrance, derived by the presence of an R group (R=H, Me, Et, nPr, iPr, Bu, and Oct) onto the N1‐nitrogen, have been synthesized, fully characterized and tested as water oxidation catalysts (WOCs), using chemical sacrificial oxidants (CAN and NaIO4) or in photocatalytic experiments ([Ru(bpy)3]Cl2 as phosensitizer and Na2S2O8 as an electron acceptor).
N1-질소에 대한 R 그룹(R=H, Me, Et, nPr, iPr, Bu 및 Oct)의 존재에 의해 유도된 가변 입체 장애를 갖는 피리딘 트리아졸릴리덴 리간드를 보유하는 이리듐 착물이 합성되고 완전히 특성화되었으며, 화학적 희생 산화제(CAN 및 NaIO4)를 사용하거나 광촉매 실험(감광제로 [Ru(bpy)3]Cl2 및 전자 수용체로 Na2S2O8)을 사용하여 물 산화 촉매(WOC)로 테스트되었습니다.
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Complexes Bearing sentence examples within 110 phenanthroline 5
Five ternary Fe(III) complexes bearing a tripodal aminophenolate ligand L2-, H2L = N,N-bis(2-hydroxy-3,5-dimethylbenzyl)-N-(2-pyridylmethyl)amine, and different aromatic bases NN = 2,2'-bipyridine [Fe(L)(bipy)]PF6 (1), 1,10-phenanthroline [Fe(L)(phen)]PF6 (2), or a phenanthroline derivative co-ligand: [Fe(L)(amphen)]NO3 (3), [Fe(L)(amphen)]PF6 (3a), [Fe(L)(Clphen)]PF6 (4), [Fe(L)(epoxyphen)]PF6 (5) (where amphen = 1,10-phenanthroline-5-amine, epoxyphen = 5,6-epoxy-5,6-dihydro-1,10-phenanthroline, Clphen = 5-chloro-1,10-phenanthroline) and the [Fe(L)(EtOH)]NO3 (6) complex are synthesized.
삼각 아미노페놀레이트 리간드 L2-, H2L = N,N-비스(2-히드록시-3,5-디메틸벤질)-N-(2-피리딜메틸)아민 및 다양한 방향족 염기 NN=2를 갖는 5개의 삼원 Fe(III) 착물 ,2'-비피리딘[Fe(L)(bipy)]PF6(1), 1,10-페난트롤린[Fe(L)(phen)]PF6(2), 또는 페난트롤린 유도체 공리간드: [Fe(L) )(암펜)]NO3(3), [Fe(L)(암펜)]PF6(3a), [Fe(L)(Clphen)]PF6(4), [Fe(L)(에폭시펜)]PF6(5 ) (여기서, 암펜=1,10-페난트롤린-5-아민, 에폭시펜=5,6-에폭시-5,6-디하이드로-1,10-페난트롤린, Clphen=5-클로로-1,10-페난트롤린) 및 [ Fe(L)(EtOH)]NO3(6) 착물이 합성됩니다.
Five ternary Fe(III) complexes bearing a tripodal aminophenolate ligand L2-, H2L = N,N-bis(2-hydroxy-3,5-dimethylbenzyl)-N-(2-pyridylmethyl)amine, and different aromatic bases NN = 2,2'-bipyridine [Fe(L)(bipy)]PF6 (1), 1,10-phenanthroline [Fe(L)(phen)]PF6 (2), or a phenanthroline derivative co-ligand: [Fe(L)(amphen)]NO3 (3), [Fe(L)(amphen)]PF6 (3a), [Fe(L)(Clphen)]PF6 (4), [Fe(L)(epoxyphen)]PF6 (5) (where amphen = 1,10-phenanthroline-5-amine, epoxyphen = 5,6-epoxy-5,6-dihydro-1,10-phenanthroline, Clphen = 5-chloro-1,10-phenanthroline) and the [Fe(L)(EtOH)]NO3 (6) complex are synthesized.
삼각 아미노페놀레이트 리간드 L2-, H2L = N,N-비스(2-히드록시-3,5-디메틸벤질)-N-(2-피리딜메틸)아민 및 다양한 방향족 염기 NN=2를 갖는 5개의 삼원 Fe(III) 착물 ,2'-비피리딘[Fe(L)(bipy)]PF6(1), 1,10-페난트롤린[Fe(L)(phen)]PF6(2), 또는 페난트롤린 유도체 공리간드: [Fe(L) )(암펜)]NO3(3), [Fe(L)(암펜)]PF6(3a), [Fe(L)(Clphen)]PF6(4), [Fe(L)(에폭시펜)]PF6(5 ) (여기서, 암펜=1,10-페난트롤린-5-아민, 에폭시펜=5,6-에폭시-5,6-디하이드로-1,10-페난트롤린, Clphen=5-클로로-1,10-페난트롤린) 및 [ Fe(L)(EtOH)]NO3(6) 착물이 합성됩니다.
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It includes the characterization by UV–Vis absorption spectroscopy and magnetic techniques of a group of mixed ligand Fe(III) complexes bearing a tripodal aminophenolate ligand L2−, H2L = N,N-bis(2-hydroxy-3,5-dimethylbenzyl)-N-(2-pyridylmethyl)amine, and different aromatic bases (NN = 2,2′-bipyridine [Fe(L)(bipy)]PF6 (1), 1,10-phenanthroline [Fe(L)(phen)]PF6 (2), or a phenanthroline derivative co-ligand: [Fe(L)(amphen)]NO3 (3), [Fe(L)(amphen)]PF6 (3a), [Fe(L)(Clphen)]PF6 (4), [Fe(L)(epoxyphen)]PF6 (5) (where amphen = 1,10-phenanthroline-5-amine, epoxyphen = 5,6-epoxy-5,6-dihydro-1,10-phenanthroline, Clphen = 5-chloro-1,10-phenanthroline), as well as [Fe(L)(EtOH)]NO3 (6), [Fe(phen)Cl3] (7) and [Fe(amphen)Cl3] (8).
여기에는 삼각 아미노페놀레이트 리간드 L2-, H2L = N,N-비스(2-히드록시-3,5-디메틸벤질)을 포함하는 혼합 리간드 Fe(III) 복합체 그룹의 UV-Vis 흡수 분광법 및 자기 기술에 의한 특성화가 포함됩니다. -N-(2-피리딜메틸)아민 및 다양한 방향족 염기(NN = 2,2'-비피리딘[Fe(L)(bipy)]PF6(1), 1,10-페난트롤린[Fe(L)(phen) ]PF6(2) 또는 페난트롤린 유도체 공동 리간드: [Fe(L)(amphen)]NO3(3), [Fe(L)(amphen)]PF6(3a), [Fe(L)(Clphen) ]PF6(4), [Fe(L)(에폭시펜)]PF6(5) -phenanthroline, Clphen = 5-chloro-1,10-phenanthroline), 뿐만 아니라 [Fe(L)(EtOH)]NO3(6), [Fe(phen)Cl3](7) 및 [Fe(amphen)Cl3 ] (8).
It includes the characterization by UV–Vis absorption spectroscopy and magnetic techniques of a group of mixed ligand Fe(III) complexes bearing a tripodal aminophenolate ligand L2−, H2L = N,N-bis(2-hydroxy-3,5-dimethylbenzyl)-N-(2-pyridylmethyl)amine, and different aromatic bases (NN = 2,2′-bipyridine [Fe(L)(bipy)]PF6 (1), 1,10-phenanthroline [Fe(L)(phen)]PF6 (2), or a phenanthroline derivative co-ligand: [Fe(L)(amphen)]NO3 (3), [Fe(L)(amphen)]PF6 (3a), [Fe(L)(Clphen)]PF6 (4), [Fe(L)(epoxyphen)]PF6 (5) (where amphen = 1,10-phenanthroline-5-amine, epoxyphen = 5,6-epoxy-5,6-dihydro-1,10-phenanthroline, Clphen = 5-chloro-1,10-phenanthroline), as well as [Fe(L)(EtOH)]NO3 (6), [Fe(phen)Cl3] (7) and [Fe(amphen)Cl3] (8).
여기에는 삼각 아미노페놀레이트 리간드 L2-, H2L = N,N-비스(2-히드록시-3,5-디메틸벤질)을 포함하는 혼합 리간드 Fe(III) 복합체 그룹의 UV-Vis 흡수 분광법 및 자기 기술에 의한 특성화가 포함됩니다. -N-(2-피리딜메틸)아민 및 다양한 방향족 염기(NN = 2,2'-비피리딘[Fe(L)(bipy)]PF6(1), 1,10-페난트롤린[Fe(L)(phen) ]PF6(2) 또는 페난트롤린 유도체 공동 리간드: [Fe(L)(amphen)]NO3(3), [Fe(L)(amphen)]PF6(3a), [Fe(L)(Clphen) ]PF6(4), [Fe(L)(에폭시펜)]PF6(5) -phenanthroline, Clphen = 5-chloro-1,10-phenanthroline), 뿐만 아니라 [Fe(L)(EtOH)]NO3(6), [Fe(phen)Cl3](7) 및 [Fe(amphen)Cl3 ] (8).
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Complexes Bearing sentence examples within 5 chloro 110
Zinc(II) complexes bearing N-salicylideneglycinate (Sal-Gly) and 1,10-phenanthroline (phen) or phenanthroline derivatives [NN = 5-chloro-1,10-phenanthroline, 5-amine-1,10-phenanthroline (amphen), 4,7-diphenyl-1,10-phenanthroline (Bphen) and 5,6-epoxy-5,6-dihydro-1,10-phenanthroline] are synthesized.
N-살리실리덴글리시네이트(Sal-Gly) 및 1,10-페난트롤린(phen) 또는 페난트롤린 유도체를 함유하는 아연(II) 착물[NN=5-클로로-1,10-페난트롤린, 5-아민-1,10-페난트롤린(암펜) ), 4,7-디페닐-1,10-페난트롤린(Bphen) 및 5,6-에폭시-5,6-디히드로-1,10-페난트롤린]이 합성된다.
Zinc(II) complexes bearing N-salicylideneglycinate (Sal-Gly) and 1,10-phenanthroline (phen) or phenanthroline derivatives [NN = 5-chloro-1,10-phenanthroline, 5-amine-1,10-phenanthroline (amphen), 4,7-diphenyl-1,10-phenanthroline (Bphen) and 5,6-epoxy-5,6-dihydro-1,10-phenanthroline] are synthesized.
N-살리실리덴글리시네이트(Sal-Gly) 및 1,10-페난트롤린(phen) 또는 페난트롤린 유도체를 함유하는 아연(II) 착물[NN=5-클로로-1,10-페난트롤린, 5-아민-1,10-페난트롤린(암펜) ), 4,7-디페닐-1,10-페난트롤린(Bphen) 및 5,6-에폭시-5,6-디히드로-1,10-페난트롤린]이 합성된다.
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Complexes Bearing sentence examples within Metal Complexes Bearing
The active sites of these heterogeneous catalysts are often metal surfaces, which consist of a large ensemble of metal atoms, and their properties differ significantly from metal complexes bearing highly developed ligands typically used in homogeneous catalysis.
The active sites of these heterogeneous catalysts are often metal surfaces, which consist of a large ensemble of metal atoms, and their properties differ significantly from metal complexes bearing highly developed ligands typically used in homogeneous catalysis.
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Transition-metal complexes bearing labile ligands can be difficult to isolate and study in solution because of unwanted dinucleation or ligand substitution reactions.
Transition-metal complexes bearing labile ligands can be difficult to isolate and study in solution because of unwanted dinucleation or ligand substitution reactions.
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Complexes Bearing sentence examples within Ruthenium Complexes Bearing
Ruthenium complexes bearing protic diimine ligands are cytotoxic to certain cancer cells upon irradiation with blue light.
Ruthenium complexes bearing protic diimine ligands are cytotoxic to certain cancer cells upon irradiation with blue light.
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Four types of tris-chelate ruthenium complexes bearing acetylacetonato (acac) and tropolonato (trop) ligands were synthesized and optically resolved into Δ and Λ isomers: [Ru(acac)3] (Ru-0), [Ru(acac)2(trop)] (Ru-1), [Ru(acac)(trop)2] (Ru-2), and [Ru(trop)3] (Ru-3).
Four types of tris-chelate ruthenium complexes bearing acetylacetonato (acac) and tropolonato (trop) ligands were synthesized and optically resolved into Δ and Λ isomers: [Ru(acac)3] (Ru-0), [Ru(acac)2(trop)] (Ru-1), [Ru(acac)(trop)2] (Ru-2), and [Ru(trop)3] (Ru-3).
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Complexes Bearing sentence examples within Palladium Complexes Bearing
The synthesis and characterization of novel palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.
The synthesis and characterization of novel palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.
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Two palladium complexes bearing different ligands such as N-heterocyclic carbene (NHC), pyridine and phosphines were synthesized and characterized by FT-IR spectroscopy, X-ray crystallography and quantum-chemical computations.
Two palladium complexes bearing different ligands such as N-heterocyclic carbene (NHC), pyridine and phosphines were synthesized and characterized by FT-IR spectroscopy, X-ray crystallography and quantum-chemical computations.
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Complexes Bearing sentence examples within Iridium Complexes Bearing
Iridium complexes bearing 2-phenylimidazo[4,5-f]-[1,10]-phenanthroline with different substituents (-CH3, -CH(CH3)2, -OCH3, -C6H5) were synthesized and characterized.
Iridium complexes bearing 2-phenylimidazo[4,5-f]-[1,10]-phenanthroline with different substituents (-CH3, -CH(CH3)2, -OCH3, -C6H5) were synthesized and characterized.
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Half-sandwich iridium complexes bearing bidentate urea-phosphorus ligands were found to catalyze the direct reductive amination of aromatic and aliphatic ketones under mild conditions at 0.
Half-sandwich iridium complexes bearing bidentate urea-phosphorus ligands were found to catalyze the direct reductive amination of aromatic and aliphatic ketones under mild conditions at 0.
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Complexes Bearing sentence examples within Manganese Complexes Bearing
Complexes Bearing sentence examples within Cobalt Complexes Bearing
Advances in (spectroscopic) characterization of the unusual electronic structures of open-shell cobalt complexes bearing redox-active ligands, combined with detailed mapping of their reactivity, have uncovered several new catalytic radical-type protocols that make efficient use of the synergistic properties of redox-active ligands, redox-active substrates, and the metal to which they coordinate.
Advances in (spectroscopic) characterization of the unusual electronic structures of open-shell cobalt complexes bearing redox-active ligands, combined with detailed mapping of their reactivity, have uncovered several new catalytic radical-type protocols that make efficient use of the synergistic properties of redox-active ligands, redox-active substrates, and the metal to which they coordinate.
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A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of amine-iminopyridine ligands are selective for Markovnikov hydrosilylations (branched/linear up to >99 : 1), while the cobalt complexes bearing the same type of ligands provide excellent levels of anti-Markovnikov selectivity (linear/branched up to >99 : 1).
A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of amine-iminopyridine ligands are selective for Markovnikov hydrosilylations (branched/linear up to >99 : 1), while the cobalt complexes bearing the same type of ligands provide excellent levels of anti-Markovnikov selectivity (linear/branched up to >99 : 1).
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Complexes Bearing sentence examples within Nickel Complexes Bearing
Three mononuclear heteroleptic nickel complexes bearing the non-innocent o-aminobenzenethiolate (2-amnt) ligand and different diamine ligands, namely, [Ni(2-amnt)(o-phen)] (o-phen = o-phenylenediamine) (1), [Ni(2-amnt)(3,4-daba)] (3,4-daba = 3, 4-diamino benzoic acid) (2) and [Ni(2-amnt)(dmnt)] (dmnt = diaminomaleonitrile) (3), were synthesized and characterized.
nan
Three mononuclear heteroleptic nickel complexes bearing the non-innocent o-aminobenzenethiolate (2-amnt) ligand and different diamine ligands, namely, [Ni(2-amnt)(o-phen)] (o-phen = o-phenylenediamine) (1), [Ni(2-amnt)(3,4-daba)] (3,4-daba = 3, 4-diamino benzoic acid) (2) and [Ni(2-amnt)(dmnt)] (dmnt = diaminomaleonitrile) (3), were synthesized and characterized.
nan
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Associated with stoichiometric experiments, experimental results prove that nickel complexes bearing electron‐withdrawing substituents on ortho‐phenoxy position or electron‐donating substituents on phosphorus atom show higher activity than contrastive catalysts toward ethylene polymerization and ethylene–methyl acrylate (MA) copolymerization.
화학량론적 실험과 관련하여 실험 결과는 오르토-페녹시 위치에 전자 끌기 치환기 또는 인 원자에서 전자 공여 치환기를 보유하는 니켈 착물이 에틸렌 중합 및 에틸렌-메틸 아크릴레이트(MA) 공중합에 대해 대조 촉매보다 더 높은 활성을 나타낸다는 것을 증명합니다.
Associated with stoichiometric experiments, experimental results prove that nickel complexes bearing electron‐withdrawing substituents on ortho‐phenoxy position or electron‐donating substituents on phosphorus atom show higher activity than contrastive catalysts toward ethylene polymerization and ethylene–methyl acrylate (MA) copolymerization.
화학량론적 실험과 관련하여 실험 결과는 오르토-페녹시 위치에 전자 끌기 치환기 또는 인 원자에서 전자 공여 치환기를 보유하는 니켈 착물이 에틸렌 중합 및 에틸렌-메틸 아크릴레이트(MA) 공중합에 대해 대조 촉매보다 더 높은 활성을 나타낸다는 것을 증명합니다.
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Complexes Bearing sentence examples within Aluminum Complexes Bearing
Trinuclear aluminum complexes bearing bipyrazoles were synthesized, and their catalytic activity for ε-caprolactone (CL) polymerization was investigated.
nan
Trinuclear aluminum complexes bearing bipyrazoles were synthesized, and their catalytic activity for ε-caprolactone (CL) polymerization was investigated.
nan
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In this contribution, we explored the catalytic ring‐opening polymerization (ROP) of (macro)lactones using salen–aluminum complexes bearing cyclic β‐ketoiminato ligand.
이 기여에서 우리는 고리형 β-케토이미나토 리간드를 함유한 살렌-알루미늄 착물을 사용하여 (매크로)락톤의 촉매 개환 중합(ROP)을 탐구했습니다.
In this contribution, we explored the catalytic ring‐opening polymerization (ROP) of (macro)lactones using salen–aluminum complexes bearing cyclic β‐ketoiminato ligand.
이 기여에서 우리는 고리형 β-케토이미나토 리간드를 함유한 살렌-알루미늄 착물을 사용하여 (매크로)락톤의 촉매 개환 중합(ROP)을 탐구했습니다.
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Complexes Bearing sentence examples within Copper Complexes Bearing
The reaction of copper salts with Schiff base ligand: [4-[(1E)-N-{2-[(Z)-(4-methoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol] derived from the condensation of ethylenediamine, 2-hydroxy-1-(4-hydroxyphenyl)ethenone and 4-methoxybenzaldehyde afforded copper complexes bearing chloride, bromide, thiocyanate, nitrate, and acetate.
nan
The reaction of copper salts with Schiff base ligand: [4-[(1E)-N-{2-[(Z)-(4-methoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol] derived from the condensation of ethylenediamine, 2-hydroxy-1-(4-hydroxyphenyl)ethenone and 4-methoxybenzaldehyde afforded copper complexes bearing chloride, bromide, thiocyanate, nitrate, and acetate.
nan
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Non-heme iron, vanadium, and copper complexes bearing hemicryptophane cavities were evaluated in the oxidation of methane in water by hydrogen peroxide.
헤미크립토판 공동이 있는 비헴 철, 바나듐 및 구리 착물은 과산화수소에 의한 물의 메탄 산화에서 평가되었습니다.
Non-heme iron, vanadium, and copper complexes bearing hemicryptophane cavities were evaluated in the oxidation of methane in water by hydrogen peroxide.
헤미크립토판 공동이 있는 비헴 철, 바나듐 및 구리 착물은 과산화수소에 의한 물의 메탄 산화에서 평가되었습니다.
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Complexes Bearing sentence examples within Arene Complexes Bearing
A series of nine RuII arene complexes bearing tridentate naphthoquinone-based N,O,O-ligands was synthesized and characterized.
A series of nine RuII arene complexes bearing tridentate naphthoquinone-based N,O,O-ligands was synthesized and characterized.
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Thus, we designed bisphosphonate-functionalized ligands for use in a modular two-step complexation process to synthesize six trithiolato-bridged dinuclear ruthenium(II) and osmium(II) arene complexes bearing one to three bisphosphonate-benzylmercaptane derived ligands.
Thus, we designed bisphosphonate-functionalized ligands for use in a modular two-step complexation process to synthesize six trithiolato-bridged dinuclear ruthenium(II) and osmium(II) arene complexes bearing one to three bisphosphonate-benzylmercaptane derived ligands.
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Complexes Bearing sentence examples within Alkyl Complexes Bearing
The mechanism of the aluminum-mediated hydroboration of terminal alkynes was investigated using a series of novel aluminum amidinate hydride and alkyl complexes bearing symmetric and asymmetric ligands.
The mechanism of the aluminum-mediated hydroboration of terminal alkynes was investigated using a series of novel aluminum amidinate hydride and alkyl complexes bearing symmetric and asymmetric ligands.
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A convenient synthetic route has been developed for preparing the novel rigid 4,5-(PR2)2-2,7,9,9-tetramethylacridane-based pincer ligands (acri-RPNP; R = iPr and Ph), and the first rare-earth (Ln = Y, Lu) alkyl complexes bearing the acri-RPNP ligands were synthesized by a salt metathesis reaction (for the isopropyl-substituent acri-iPrPNP complexes, 1-Ln) or direct alkylation (for the phenyl-substituent acri-PhPNP complexes, 2-Ln).
A convenient synthetic route has been developed for preparing the novel rigid 4,5-(PR2)2-2,7,9,9-tetramethylacridane-based pincer ligands (acri-RPNP; R = iPr and Ph), and the first rare-earth (Ln = Y, Lu) alkyl complexes bearing the acri-RPNP ligands were synthesized by a salt metathesis reaction (for the isopropyl-substituent acri-iPrPNP complexes, 1-Ln) or direct alkylation (for the phenyl-substituent acri-PhPNP complexes, 2-Ln).
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Complexes Bearing sentence examples within Pincer Complexes Bearing
Ruthenium-pincer complexes bearing CNN- and PNN-pincer ligands with diethyl- or diisopropylamino side groups, which have previously been reported to be active precatalysts for ester hydrogenation, undergo dehydroalkylation on heating in the presence of tricyclohexylphosphine to release ethane or propane, giving five-coordinate ruthenium(0) complexes containing a nascent imine functional group.
디에틸 또는 디이소프로필아미노 측기가 있는 CNN 및 PNN 집게 리간드를 포함하는 루테늄 집게 착물은 이전에 에스테르 수소화를 위한 활성 예비 촉매로 보고된 바 있으며, 트리시클로헥실포스핀이 있는 상태에서 가열하면 디히드로알킬화되어 에탄 또는 프로판을 방출하여 5가지를 제공합니다. - 초기 이민 작용기를 포함하는 배위 루테늄(0) 착물.
Ruthenium-pincer complexes bearing CNN- and PNN-pincer ligands with diethyl- or diisopropylamino side groups, which have previously been reported to be active precatalysts for ester hydrogenation, undergo dehydroalkylation on heating in the presence of tricyclohexylphosphine to release ethane or propane, giving five-coordinate ruthenium(0) complexes containing a nascent imine functional group.
디에틸 또는 디이소프로필아미노 측기가 있는 CNN 및 PNN 집게 리간드를 포함하는 루테늄 집게 착물은 이전에 에스테르 수소화를 위한 활성 예비 촉매로 보고된 바 있으며, 트리시클로헥실포스핀이 있는 상태에서 가열하면 디히드로알킬화되어 에탄 또는 프로판을 방출하여 5가지를 제공합니다. - 초기 이민 작용기를 포함하는 배위 루테늄(0) 착물.
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This paper provides a general overview of palladium pincer complexes, their structural diversity and synthetic protocols to further review the state of the art and recent advances on the organometallic chemistry of palladium pincer complexes bearing aryl and pyridine central backbones with special emphasis on their DCD, PCP, NCN, SCS, OCO, SeCSe, DCD´and DND′ variants and their further applications on cross-coupling and related reactions, such as: Mizoroki-Heck, Suzuki-Miyaura, Sonogashira, Hiyama and Negishi couplings along with the allylation of aldehydes and arylation of azoles and indoles.
이 백서는 팔라듐 집게 착물, 구조적 다양성 및 합성 프로토콜에 대한 일반적인 개요를 제공하여 DCD, PCP에 특히 중점을 둔 아릴 및 피리딘 중심 백본을 포함하는 팔라듐 집게 착물의 유기금속 화학에 대한 최신 기술 및 최근 발전을 추가로 검토합니다. , NCN, SCS, OCO, SeCSe, DCD' 및 DND' 변형 및 교차 커플링 및 관련 반응에 대한 추가 적용: Mizoroki-Heck, Suzuki-Miyaura, Sonogashira, Hiyama 및 Negishi 커플링과 알데히드의 알릴화 및 아졸 및 인돌의 아릴화.
This paper provides a general overview of palladium pincer complexes, their structural diversity and synthetic protocols to further review the state of the art and recent advances on the organometallic chemistry of palladium pincer complexes bearing aryl and pyridine central backbones with special emphasis on their DCD, PCP, NCN, SCS, OCO, SeCSe, DCD´and DND′ variants and their further applications on cross-coupling and related reactions, such as: Mizoroki-Heck, Suzuki-Miyaura, Sonogashira, Hiyama and Negishi couplings along with the allylation of aldehydes and arylation of azoles and indoles.
이 백서는 팔라듐 집게 착물, 구조적 다양성 및 합성 프로토콜에 대한 일반적인 개요를 제공하여 DCD, PCP에 특히 중점을 둔 아릴 및 피리딘 중심 백본을 포함하는 팔라듐 집게 착물의 유기금속 화학에 대한 최신 기술 및 최근 발전을 추가로 검토합니다. , NCN, SCS, OCO, SeCSe, DCD' 및 DND' 변형 및 교차 커플링 및 관련 반응에 대한 추가 적용: Mizoroki-Heck, Suzuki-Miyaura, Sonogashira, Hiyama 및 Negishi 커플링과 알데히드의 알릴화 및 아졸 및 인돌의 아릴화.
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Complexes Bearing sentence examples within Iron Complexes Bearing
Herein we report the synthesis and investigations of the photophysics of mer and fac iron complexes bearing bidentate pyridyl-NHC ligands, coordinating the iron with three ligand-field-enhancing carbene bonds.
여기에서 우리는 3개의 리간드 필드 강화 카르벤 결합으로 철을 조정하여 두자리 피리딜-NHC 리간드를 지닌 mer 및 fac 철 복합체의 광물리학의 합성 및 조사를 보고합니다.
Herein we report the synthesis and investigations of the photophysics of mer and fac iron complexes bearing bidentate pyridyl-NHC ligands, coordinating the iron with three ligand-field-enhancing carbene bonds.
여기에서 우리는 3개의 리간드 필드 강화 카르벤 결합으로 철을 조정하여 두자리 피리딜-NHC 리간드를 지닌 mer 및 fac 철 복합체의 광물리학의 합성 및 조사를 보고합니다.
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Catalytically relevant, S = 1 iron complexes bearing 2-(imino)pyridine ligands, (RPI)FeL2 (RPI = [2-(2,6-R2-C6H3-N═CMe)-C5H4N] where R = iPr or Me, L2 = bis-olefin), were characterized by single-crystal X-ray diffraction, Mößbauer spectroscopy, magnetic measurements, and DFT calculations.
촉매 관련, S = 2-(이미노)피리딘 리간드, (RPI)FeL2(RPI = [2-(2,6-R2-C6H3-N=CMe)-C5H4N]을 포함하는 1개의 철 착물, 여기서 R = iPr 또는 Me, L2 = 비스-올레핀), 단결정 X선 회절, Mößbauer 분광법, 자기 측정 및 DFT 계산으로 특성화되었습니다.
Catalytically relevant, S = 1 iron complexes bearing 2-(imino)pyridine ligands, (RPI)FeL2 (RPI = [2-(2,6-R2-C6H3-N═CMe)-C5H4N] where R = iPr or Me, L2 = bis-olefin), were characterized by single-crystal X-ray diffraction, Mößbauer spectroscopy, magnetic measurements, and DFT calculations.
촉매 관련, S = 2-(이미노)피리딘 리간드, (RPI)FeL2(RPI = [2-(2,6-R2-C6H3-N=CMe)-C5H4N]을 포함하는 1개의 철 착물, 여기서 R = iPr 또는 Me, L2 = 비스-올레핀), 단결정 X선 회절, Mößbauer 분광법, 자기 측정 및 DFT 계산으로 특성화되었습니다.
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Complexes Bearing sentence examples within Nhc Complexes Bearing
Complexes Bearing sentence examples within Oxo Complexes Bearing
Some Mo‐oxo complexes bearing pyridine rings have the capability for dihydrogen production from water.
Some Mo‐oxo complexes bearing pyridine rings have the capability for dihydrogen production from water.
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Iron(V)-oxo complexes bearing negatively charged tetraamido macrocyclic ligands (TAMLs) have provided excellent opportunities to investigate the chemical properties and the mechanisms of oxidation reactions of mononuclear nonheme iron(V)-oxo intermediates.
Iron(V)-oxo complexes bearing negatively charged tetraamido macrocyclic ligands (TAMLs) have provided excellent opportunities to investigate the chemical properties and the mechanisms of oxidation reactions of mononuclear nonheme iron(V)-oxo intermediates.
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Complexes Bearing sentence examples within Tricarbonyl Complexes Bearing
We describe two-photon excitation with NIR light (800 nm)-induced CO-release from two MnI tricarbonyl complexes bearing 1,8-naphthalimide units (1, 2).
우리는 1,8-나프탈이미드 단위(1, 2)를 포함하는 2개의 MnI 트리카보닐 복합체에서 NIR 광(800 nm)으로 유도된 CO 방출로 2광자 여기를 설명합니다.
We describe two-photon excitation with NIR light (800 nm)-induced CO-release from two MnI tricarbonyl complexes bearing 1,8-naphthalimide units (1, 2).
우리는 1,8-나프탈이미드 단위(1, 2)를 포함하는 2개의 MnI 트리카보닐 복합체에서 NIR 광(800 nm)으로 유도된 CO 방출로 2광자 여기를 설명합니다.
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Here, we report the application of microwave-assisted combinatorial chemistry for the synthesis of 80 rhenium(I) tricarbonyl complexes bearing diimine ligands.
여기에서 우리는 디이민 리간드를 포함하는 80개의 레늄(I) 트리카르보닐 복합체의 합성을 위한 마이크로파 보조 조합 화학의 적용을 보고합니다.
Here, we report the application of microwave-assisted combinatorial chemistry for the synthesis of 80 rhenium(I) tricarbonyl complexes bearing diimine ligands.
여기에서 우리는 디이민 리간드를 포함하는 80개의 레늄(I) 트리카르보닐 복합체의 합성을 위한 마이크로파 보조 조합 화학의 적용을 보고합니다.
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Complexes Bearing sentence examples within Ternary Complexes Bearing
These potentials are in the range of typical (O,O) chelated Co(III) ternary complexes bearing 4 N donor ligands and follow the order being more positive for the tpa containing complexes.
이러한 전위는 4N 도너 리간드를 포함하는 전형적인 (O,O) 킬레이트 Co(III) 삼원 착물의 범위에 있으며 tpa 함유 착물에 대해 더 긍정적인 순서를 따릅니다.
These potentials are in the range of typical (O,O) chelated Co(III) ternary complexes bearing 4 N donor ligands and follow the order being more positive for the tpa containing complexes.
이러한 전위는 4N 도너 리간드를 포함하는 전형적인 (O,O) 킬레이트 Co(III) 삼원 착물의 범위에 있으며 tpa 함유 착물에 대해 더 긍정적인 순서를 따릅니다.
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Nine novel cobalt(III) ternary complexes bearing 4N donor ligands (tris(2-aminoethyl)amine (tren) or tris(2-methylpyridyl)amine (tpa)) and (fluoro)quinolones (quinH) with antibacterial and potential antitumor activity have been synthesized, characterized and screened in various biological assays.
항균 및 잠재적 항종양 활성을 갖는 4N 공여체 리간드(트리스(2-아미노에틸)아민(tren) 또는 트리스(2-메틸피리딜)아민(tpa)) 및 (플루오로)퀴놀론(quinH)을 함유하는 9개의 신규 코발트(III) 삼원 착물은 다양한 생물학적 분석에서 합성, 특성화 및 스크리닝되었습니다.
Nine novel cobalt(III) ternary complexes bearing 4N donor ligands (tris(2-aminoethyl)amine (tren) or tris(2-methylpyridyl)amine (tpa)) and (fluoro)quinolones (quinH) with antibacterial and potential antitumor activity have been synthesized, characterized and screened in various biological assays.
항균 및 잠재적 항종양 활성을 갖는 4N 공여체 리간드(트리스(2-아미노에틸)아민(tren) 또는 트리스(2-메틸피리딜)아민(tpa)) 및 (플루오로)퀴놀론(quinH)을 함유하는 9개의 신규 코발트(III) 삼원 착물은 다양한 생물학적 분석에서 합성, 특성화 및 스크리닝되었습니다.
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Complexes Bearing sentence examples within Rhodium Complexes Bearing
Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions.
음이온성 피롤 기반 PNP형 집게 리간드를 포함하는 로듐 착물이 합성되고 온화한 반응 조건에서 분자 이질소를 트리스(트리메틸실릴)아민으로 변환하기 위한 효과적인 촉매로 작동하는 것으로 밝혀졌습니다.
Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions.
음이온성 피롤 기반 PNP형 집게 리간드를 포함하는 로듐 착물이 합성되고 온화한 반응 조건에서 분자 이질소를 트리스(트리메틸실릴)아민으로 변환하기 위한 효과적인 촉매로 작동하는 것으로 밝혀졌습니다.
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Tests of the catalytic activity of the [Rh(cod)Cl(NHC)] complexes in the transfer hydrogenation of acetophenone with iPrOH shows that the rhodium complexes bearing fluorinated NHCs are better than their non-fluorinated counterparts.
iPrOH를 사용한 아세토페논의 전이 수소화에서 [Rh(cod)Cl(NHC)] 착물의 촉매 활성 테스트는 플루오르화 NHC를 함유하는 로듐 착물이 비불소화 대응물보다 우수함을 보여줍니다.
Tests of the catalytic activity of the [Rh(cod)Cl(NHC)] complexes in the transfer hydrogenation of acetophenone with iPrOH shows that the rhodium complexes bearing fluorinated NHCs are better than their non-fluorinated counterparts.
iPrOH를 사용한 아세토페논의 전이 수소화에서 [Rh(cod)Cl(NHC)] 착물의 촉매 활성 테스트는 플루오르화 NHC를 함유하는 로듐 착물이 비불소화 대응물보다 우수함을 보여줍니다.
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Complexes Bearing sentence examples within Cationic Complexes Bearing
22 µs, while for cationic complexes bearing nitrile, isonitrile and triphenylphosphane units gave comparable results with quantum yields ranging from 11% to 16% and lifetimes from 3.
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22 µs, while for cationic complexes bearing nitrile, isonitrile and triphenylphosphane units gave comparable results with quantum yields ranging from 11% to 16% and lifetimes from 3.
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Cationic complexes bearing phosphines PiPr2ArXyl2 and PCyp2ArXyl2 were the most active of the series.
포스핀 PiPr2ArXyl2 및 PCyp2ArXyl2를 포함하는 양이온성 착물이 시리즈 중 가장 활성이었습니다.
Cationic complexes bearing phosphines PiPr2ArXyl2 and PCyp2ArXyl2 were the most active of the series.
포스핀 PiPr2ArXyl2 및 PCyp2ArXyl2를 포함하는 양이온성 착물이 시리즈 중 가장 활성이었습니다.
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Complexes Bearing sentence examples within Pd Complexes Bearing
The Pd complexes bearing hydroxy groups exhibited similar catalytic properties to those of the Pd catalyst bearing OMe groups did.
히드록시기를 함유한 Pd 착물은 OMe기를 함유한 Pd 촉매와 유사한 촉매 특성을 나타냈다.
The Pd complexes bearing hydroxy groups exhibited similar catalytic properties to those of the Pd catalyst bearing OMe groups did.
히드록시기를 함유한 Pd 착물은 OMe기를 함유한 Pd 촉매와 유사한 촉매 특성을 나타냈다.
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A series of Pd complexes bearing modified tetradentate pyridinophane ligands RN3CH, containing a C-donor phenyl group, were isolated and characterized.
C-도너 페닐 그룹을 포함하는 변형된 4자리 피리디노판 리간드 RN3CH를 보유하는 일련의 Pd 착물을 분리하고 특성화했습니다.
A series of Pd complexes bearing modified tetradentate pyridinophane ligands RN3CH, containing a C-donor phenyl group, were isolated and characterized.
C-도너 페닐 그룹을 포함하는 변형된 4자리 피리디노판 리간드 RN3CH를 보유하는 일련의 Pd 착물을 분리하고 특성화했습니다.
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Complexes Bearing sentence examples within Al Complexes Bearing
A series of Al complexes bearing diethyl 2-((arylamino)methylene)malonate and diethyl 2-((alkylamino)methylene)malonate ligands (AMM ligands) were synthesized and their application in the ring-opening polymerization of e-caprolactone was studied.
디에틸 2-((아릴아미노)메틸렌)말로네이트 및 디에틸 2-((알킬아미노)메틸렌)말로네이트 리간드(AMM 리간드)를 함유하는 일련의 Al 착물을 합성하고 e-카프로락톤의 개환 중합에서의 적용을 연구하였다.
A series of Al complexes bearing diethyl 2-((arylamino)methylene)malonate and diethyl 2-((alkylamino)methylene)malonate ligands (AMM ligands) were synthesized and their application in the ring-opening polymerization of e-caprolactone was studied.
디에틸 2-((아릴아미노)메틸렌)말로네이트 및 디에틸 2-((알킬아미노)메틸렌)말로네이트 리간드(AMM 리간드)를 함유하는 일련의 Al 착물을 합성하고 e-카프로락톤의 개환 중합에서의 적용을 연구하였다.
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The present study reports the first example of salen-Al complexes bearing electron-rich TPA moieties.
현재의 연구는 전자가 풍부한 TPA 부분을 포함하는 살렌-Al 착물의 첫 번째 예를 보고합니다.
The present study reports the first example of salen-Al complexes bearing electron-rich TPA moieties.
현재의 연구는 전자가 풍부한 TPA 부분을 포함하는 살렌-Al 착물의 첫 번째 예를 보고합니다.
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Complexes Bearing sentence examples within Gold Complexes Bearing
Additionally, the synthesis of phosphine ligated gold complexes bearing pyrido-isoquinoline scaffold from the pyridino-alkynes will be discussed briefly.
Additionally, the synthesis of phosphine ligated gold complexes bearing pyrido-isoquinoline scaffold from the pyridino-alkynes will be discussed briefly.
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Thus prepared PQXs bearing 1,2,3‐triazole pendants were treated with MeI, Ag2O, and AuCl successively, giving polymer‐supported gold complexes bearing 1,2,3‐triazolylidenes as abnormal N‐heterocyclic carbene (aNHC) ligands.
Thus prepared PQXs bearing 1,2,3‐triazole pendants were treated with MeI, Ag2O, and AuCl successively, giving polymer‐supported gold complexes bearing 1,2,3‐triazolylidenes as abnormal N‐heterocyclic carbene (aNHC) ligands.
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Complexes Bearing sentence examples within Alkylidene Complexes Bearing
The catalysts employed were ruthenium-alkylidene complexes bearing a N-heterocyclic carbene as a ligand, which bulkiness proved to be important for the catalysis output.
nan
The catalysts employed were ruthenium-alkylidene complexes bearing a N-heterocyclic carbene as a ligand, which bulkiness proved to be important for the catalysis output.
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New monothiolate ruthenium alkylidene complexes bearing bulky tricyclic N-heterocyclic carbene ligands decorated with two geminal trifluoromethyl groups were synthesized.
두 개의 geminal trifluoromethyl 그룹으로 장식된 부피가 큰 tricyclic N-heterocyclic carbene 리간드를 지닌 새로운 monothiolate rutheniumalkylidene 착물이 합성되었습니다.
New monothiolate ruthenium alkylidene complexes bearing bulky tricyclic N-heterocyclic carbene ligands decorated with two geminal trifluoromethyl groups were synthesized.
두 개의 geminal trifluoromethyl 그룹으로 장식된 부피가 큰 tricyclic N-heterocyclic carbene 리간드를 지닌 새로운 monothiolate rutheniumalkylidene 착물이 합성되었습니다.
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Complexes Bearing sentence examples within Titanium Complexes Bearing
Complexes Bearing sentence examples within Analogou Complexes Bearing
The H2bibenz and o-xylbibenz ligands are shown to be electronically indistinct to dtbubpy but give complexes with higher quantum yields than analogous complexes bearing dtbubpy.
H2bibenz 및 o-xylbibenz 리간드는 dtbubpy와 전자적으로 구별되지 않는 것으로 표시되지만 dtbubpy를 포함하는 유사한 착물보다 양자 수율이 더 높은 착물을 제공합니다.
The H2bibenz and o-xylbibenz ligands are shown to be electronically indistinct to dtbubpy but give complexes with higher quantum yields than analogous complexes bearing dtbubpy.
H2bibenz 및 o-xylbibenz 리간드는 dtbubpy와 전자적으로 구별되지 않는 것으로 표시되지만 dtbubpy를 포함하는 유사한 착물보다 양자 수율이 더 높은 착물을 제공합니다.
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The H2bibenz and o-xylbibenz ligands are shown to be electronically indistinct to dtbubpy but give complexes with higher quantum yields than analogous complexes bearing dtbubpy.
H2bibenz 및 o-xylbibenz 리간드는 dtbubpy와 전자적으로 구별되지 않는 것으로 표시되지만 dtbubpy를 포함하는 유사한 착물보다 양자 수율이 더 높은 착물을 제공합니다.
The H2bibenz and o-xylbibenz ligands are shown to be electronically indistinct to dtbubpy but give complexes with higher quantum yields than analogous complexes bearing dtbubpy.
H2bibenz 및 o-xylbibenz 리간드는 dtbubpy와 전자적으로 구별되지 않는 것으로 표시되지만 dtbubpy를 포함하는 유사한 착물보다 양자 수율이 더 높은 착물을 제공합니다.
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Complexes Bearing sentence examples within Platinum Complexes Bearing
In this work, six bidentate platinum complexes bearing both bipyrazolate and 1,10 phenanthroline derivative chelates are investigated by DFT and TDDFT study to reveal the interligand hydrogen bonding, planarity enhancement and photo physical properties.
In this work, six bidentate platinum complexes bearing both bipyrazolate and 1,10 phenanthroline derivative chelates are investigated by DFT and TDDFT study to reveal the interligand hydrogen bonding, planarity enhancement and photo physical properties.
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This review covers the chemistry of gold and platinum complexes bearing alkynyl ligands that present antitumor activity.
This review covers the chemistry of gold and platinum complexes bearing alkynyl ligands that present antitumor activity.
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Complexes Bearing sentence examples within Porphyrin Complexes Bearing
A new family of rhodium porphyrin complexes bearing a primary, secondary or benzylic perfluoroalkyl ligand RhIII(btpp)RF [btpp = 5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato dianion] has been successfully synthesized in good yields using commercially available perfluoroalkyl iodides RFI (RF = nC3F7, iC3F7, nC4F9, nC6F13, cC6F11, nC10F21 and C6F5CF2) and the air-stable precursor RhIII(btpp)Cl under basic conditions.
A new family of rhodium porphyrin complexes bearing a primary, secondary or benzylic perfluoroalkyl ligand RhIII(btpp)RF [btpp = 5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato dianion] has been successfully synthesized in good yields using commercially available perfluoroalkyl iodides RFI (RF = nC3F7, iC3F7, nC4F9, nC6F13, cC6F11, nC10F21 and C6F5CF2) and the air-stable precursor RhIII(btpp)Cl under basic conditions.
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To establish a well-defined relationship between the magnitude of g-value dispersion in this unique EPR signal and the strength of the heme-thiolate H-bonding environment, we synthesized and characterized of a series of six-coordinate, aryl-thiolate-ligated Fe(III) porphyrin complexes bearing a tunable intramolecular H-bond.
To establish a well-defined relationship between the magnitude of g-value dispersion in this unique EPR signal and the strength of the heme-thiolate H-bonding environment, we synthesized and characterized of a series of six-coordinate, aryl-thiolate-ligated Fe(III) porphyrin complexes bearing a tunable intramolecular H-bond.
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Complexes Bearing sentence examples within Heterobimetallic Complexes Bearing
Specifically, we will concentrate on the synthesis, characterisation and biological (anticancer) studies of a sub-class of these agents, namely homo and heterobimetallic complexes bearing a bridging phosphane ligand of the type: [LnM1(μ-R2P(CH2)nPR2)M2Lm] (where M1 is platinum or palladium, M2 is any other transition metal, R = alkyl or aryl substituents, Ln or Lm are co-ligands, n = 1-6).
Specifically, we will concentrate on the synthesis, characterisation and biological (anticancer) studies of a sub-class of these agents, namely homo and heterobimetallic complexes bearing a bridging phosphane ligand of the type: [LnM1(μ-R2P(CH2)nPR2)M2Lm] (where M1 is platinum or palladium, M2 is any other transition metal, R = alkyl or aryl substituents, Ln or Lm are co-ligands, n = 1-6).
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Moreover, reduction of the zwitterionic rhodium-aluminum complex with KC8 afforded heterobimetallic complexes bearing an X-type PAlP pincer ligand.
Moreover, reduction of the zwitterionic rhodium-aluminum complex with KC8 afforded heterobimetallic complexes bearing an X-type PAlP pincer ligand.
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Complexes Bearing sentence examples within Type Complexes Bearing
Herein, we explore the photophysical properties of protonation isomers of the linearly π-extended [(tbbpy)2Ru(L)]2+-type complexes bearing a dppz ligand with directly fused imidazole (im) and methyl-imidazole units (mim) as L.
Herein, we explore the photophysical properties of protonation isomers of the linearly π-extended [(tbbpy)2Ru(L)]2+-type complexes bearing a dppz ligand with directly fused imidazole (im) and methyl-imidazole units (mim) as L.
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In this work, the five new Pd PEPPSI-type complexes bearing NHC spectator ligands were synthesized and characterized by a bunch of spectroscopic techniques.
In this work, the five new Pd PEPPSI-type complexes bearing NHC spectator ligands were synthesized and characterized by a bunch of spectroscopic techniques.
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Complexes Bearing sentence examples within Oxovanadium Complexes Bearing
In this work, a series of oxovanadium complexes bearing the ligands (S,E)-(+)-2, 6-dialkyl-N-(2-((2-(4-isopropyl-4,5-dihydrooxazole-2-yl)phenyl)amino)benzylidene)aniline (dialkyl = dimethyl (V1), diethyl (V2), and isopropyl (V3)) have been synthesized and characterized by FTIR spectroscopy and elemental analysis.
In this work, a series of oxovanadium complexes bearing the ligands (S,E)-(+)-2, 6-dialkyl-N-(2-((2-(4-isopropyl-4,5-dihydrooxazole-2-yl)phenyl)amino)benzylidene)aniline (dialkyl = dimethyl (V1), diethyl (V2), and isopropyl (V3)) have been synthesized and characterized by FTIR spectroscopy and elemental analysis.
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A Cambridge Crystallographic Database (CSD) search of oxovanadium complexes bearing side-on (η2) dioxygen ligands show 134 entries in the database.
A Cambridge Crystallographic Database (CSD) search of oxovanadium complexes bearing side-on (η2) dioxygen ligands show 134 entries in the database.
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Complexes Bearing sentence examples within Allyl Complexes Bearing
The synthesis and characterization of silver and palladium allyl complexes bearing imidazo [1,5-a]pyridine-3-ylidene and dipyridoimidazolinylidene ligands is reported.
The synthesis and characterization of silver and palladium allyl complexes bearing imidazo [1,5-a]pyridine-3-ylidene and dipyridoimidazolinylidene ligands is reported.
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The synthesis of twelve new palladium allyl complexes bearing benzimidazole-based NHC (NHC = N-heterocyclic carbene) ligands is reported.
The synthesis of twelve new palladium allyl complexes bearing benzimidazole-based NHC (NHC = N-heterocyclic carbene) ligands is reported.
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Complexes Bearing sentence examples within Chloride Complexes Bearing
Here we describe the multigram synthesis of the most common mononuclear N-heterocyclic carbene gold(I) chloride complexes bearing the N,N'-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) and N,N'-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene (IPr*) ligands.
Here we describe the multigram synthesis of the most common mononuclear N-heterocyclic carbene gold(I) chloride complexes bearing the N,N'-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) and N,N'-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene (IPr*) ligands.
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In this contribution, a class of iron (II) chloride complexes bearing pendant N-donor modified α-diimine ligands were synthesized and used as precatalysts for ethylene polymerization.
In this contribution, a class of iron (II) chloride complexes bearing pendant N-donor modified α-diimine ligands were synthesized and used as precatalysts for ethylene polymerization.
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Complexes Bearing sentence examples within Earth Complexes Bearing
This study confirms that moving towards nitrogen‐coordinated rare‐earth complexes bearing the guanidinate and amidinate ligands can indeed be very appealing in terms of new precursors for ALD of rare earth based materials.
This study confirms that moving towards nitrogen‐coordinated rare‐earth complexes bearing the guanidinate and amidinate ligands can indeed be very appealing in terms of new precursors for ALD of rare earth based materials.
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A family of rare-earth complexes bearing diarylamido-based pincer ligands with phosphino-, phenylthio- and quinolino-sidearms have been synthesized and fully characterized.
A family of rare-earth complexes bearing diarylamido-based pincer ligands with phosphino-, phenylthio- and quinolino-sidearms have been synthesized and fully characterized.
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Complexes Bearing sentence examples within complexes bearing n
The synthesis and characterization of novel palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.
The synthesis and characterization of novel palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.
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The synthesis and reactivity of actinide complexes bearing N-heterocyclic iminato ligands are presented, and promising apposite applications are also presented.
The synthesis and reactivity of actinide complexes bearing N-heterocyclic iminato ligands are presented, and promising apposite applications are also presented.
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Complexes Bearing sentence examples within complexes bearing 2
In this work, a series of six rhenium(I) complexes bearing 2,2′:6′,2″-terpyridine (terpy), 2,6-di(thiazol-2-yl)pyridine (dtpy), and 2,6-di(pyrazin-2-yl)pyridine (dppy) with appended quinolin-2-yl and N-ethylcarbazol-3-yl groups were prepared and spectroscopically investigated to evaluate the photophysical consequences of both the trisheterocyclic core (terpy, dtpy and dppy) and the heterocyclic substituent.
In this work, a series of six rhenium(I) complexes bearing 2,2′:6′,2″-terpyridine (terpy), 2,6-di(thiazol-2-yl)pyridine (dtpy), and 2,6-di(pyrazin-2-yl)pyridine (dppy) with appended quinolin-2-yl and N-ethylcarbazol-3-yl groups were prepared and spectroscopically investigated to evaluate the photophysical consequences of both the trisheterocyclic core (terpy, dtpy and dppy) and the heterocyclic substituent.
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Iridium complexes bearing 2-phenylimidazo[4,5-f]-[1,10]-phenanthroline with different substituents (-CH3, -CH(CH3)2, -OCH3, -C6H5) were synthesized and characterized.
Iridium complexes bearing 2-phenylimidazo[4,5-f]-[1,10]-phenanthroline with different substituents (-CH3, -CH(CH3)2, -OCH3, -C6H5) were synthesized and characterized.
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Complexes Bearing sentence examples within complexes bearing different
Two palladium complexes bearing different ligands such as N-heterocyclic carbene (NHC), pyridine and phosphines were synthesized and characterized by FT-IR spectroscopy, X-ray crystallography and quantum-chemical computations.
Two palladium complexes bearing different ligands such as N-heterocyclic carbene (NHC), pyridine and phosphines were synthesized and characterized by FT-IR spectroscopy, X-ray crystallography and quantum-chemical computations.
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A simple and eco-friendly route to gold-NHC complexes bearing different thiosugars is reported.
A simple and eco-friendly route to gold-NHC complexes bearing different thiosugars is reported.
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Complexes Bearing sentence examples within complexes bearing two
Herein, we present tetracoordinated Ge(II), Sn(II), and Pb(II) complexes bearing two sets of chelating 1,3-di-tert-butyltriazenide ligands.
nan
Herein, we present tetracoordinated Ge(II), Sn(II), and Pb(II) complexes bearing two sets of chelating 1,3-di-tert-butyltriazenide ligands.
nan
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Oxido-alcoholato- and oxido-thiolato-molybdenum(VI) complexes bearing two ene-1,2-dithiolate ligands (cyclohexene-1,2-dithiolate) are prepared as synthetic models of molybdenum(VI) reaction centers of dimethyl sulfoxide reductase family of molybdenum enzymes.
2개의 ene-1,2-dithiolate 리간드(cyclohexene-1,2-dithiolate)를 지닌 Oxido-alcoholato- 및 oxido-thiolato-molybdenum(VI) 착물은 dimethyl sulfoxide reductase family의 몰리브덴(VI) 반응 중심의 합성 모델로 준비됩니다. 몰리브덴 효소.
Oxido-alcoholato- and oxido-thiolato-molybdenum(VI) complexes bearing two ene-1,2-dithiolate ligands (cyclohexene-1,2-dithiolate) are prepared as synthetic models of molybdenum(VI) reaction centers of dimethyl sulfoxide reductase family of molybdenum enzymes.
2개의 ene-1,2-dithiolate 리간드(cyclohexene-1,2-dithiolate)를 지닌 Oxido-alcoholato- 및 oxido-thiolato-molybdenum(VI) 착물은 dimethyl sulfoxide reductase family의 몰리브덴(VI) 반응 중심의 합성 모델로 준비됩니다. 몰리브덴 효소.
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Complexes Bearing sentence examples within complexes bearing either
A facile and effective strategy for the preparation of a series of ferricenium complexes bearing either electron-donating or electron-withdrawing substituents with weakly coordinating anions such as [B(C6F5)4]- or SbF6- is reported.
A facile and effective strategy for the preparation of a series of ferricenium complexes bearing either electron-donating or electron-withdrawing substituents with weakly coordinating anions such as [B(C6F5)4]- or SbF6- is reported.
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Four gadolinium(iii) complexes bearing either one or two polymerizable methacrylamide groups were synthesized, serving as monomers or crosslinkers for the preparation of water-soluble, polymeric CAs using Reversible Addition–Fragmentation Chain Transfer (RAFT) polymerization.
Four gadolinium(iii) complexes bearing either one or two polymerizable methacrylamide groups were synthesized, serving as monomers or crosslinkers for the preparation of water-soluble, polymeric CAs using Reversible Addition–Fragmentation Chain Transfer (RAFT) polymerization.
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Complexes Bearing sentence examples within complexes bearing tridentate
A series of nine RuII arene complexes bearing tridentate naphthoquinone-based N,O,O-ligands was synthesized and characterized.
A series of nine RuII arene complexes bearing tridentate naphthoquinone-based N,O,O-ligands was synthesized and characterized.
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The electronic structure and photophysical properties of three iridium(III) complexes bearing tridentate chromophoric chelate have been theoretically studied by using the DFT/TDDFT.
The electronic structure and photophysical properties of three iridium(III) complexes bearing tridentate chromophoric chelate have been theoretically studied by using the DFT/TDDFT.
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Complexes Bearing sentence examples within complexes bearing bidentate
In this review, attempts have been made to provide a brief review of the recent developments of neutral Pt(II) organometallic complexes bearing bidentate cyclometalating ligands and β-diketonate ancillary ligands, i.
In this review, attempts have been made to provide a brief review of the recent developments of neutral Pt(II) organometallic complexes bearing bidentate cyclometalating ligands and β-diketonate ancillary ligands, i.
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Half-sandwich iridium complexes bearing bidentate urea-phosphorus ligands were found to catalyze the direct reductive amination of aromatic and aliphatic ketones under mild conditions at 0.
Half-sandwich iridium complexes bearing bidentate urea-phosphorus ligands were found to catalyze the direct reductive amination of aromatic and aliphatic ketones under mild conditions at 0.
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Complexes Bearing sentence examples within complexes bearing chiral
We report an enantioselective hydroarylation reaction of styrenes and 1,3-dienes with arylboronic acids catalyzed by nickel complexes bearing chiral spiro aminophosphine ligands.
우리는 키랄 스피로 아미노포스핀 리간드를 지닌 니켈 복합체에 의해 촉매되는 아릴보론산과 스티렌과 1,3-디엔의 거울상 선택적 수소화 반응을 보고합니다.
We report an enantioselective hydroarylation reaction of styrenes and 1,3-dienes with arylboronic acids catalyzed by nickel complexes bearing chiral spiro aminophosphine ligands.
우리는 키랄 스피로 아미노포스핀 리간드를 지닌 니켈 복합체에 의해 촉매되는 아릴보론산과 스티렌과 1,3-디엔의 거울상 선택적 수소화 반응을 보고합니다.
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A series of methyl aluminum complexes bearing chiral biphenol-type ligands were found to be highly active catalysts in the asymmetric reduction of heterocyclic ketones (S/C = 100 - 500, ee up to 99%).
키랄 비페놀형 리간드를 포함하는 일련의 메틸 알루미늄 착물은 헤테로사이클릭 케톤의 비대칭 환원에서 매우 활성인 촉매인 것으로 밝혀졌습니다(S/C = 100 - 500, ee 최대 99%).
A series of methyl aluminum complexes bearing chiral biphenol-type ligands were found to be highly active catalysts in the asymmetric reduction of heterocyclic ketones (S/C = 100 - 500, ee up to 99%).
키랄 비페놀형 리간드를 포함하는 일련의 메틸 알루미늄 착물은 헤테로사이클릭 케톤의 비대칭 환원에서 매우 활성인 촉매인 것으로 밝혀졌습니다(S/C = 100 - 500, ee 최대 99%).
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Complexes Bearing sentence examples within complexes bearing pyridine
Some Mo‐oxo complexes bearing pyridine rings have the capability for dihydrogen production from water.
nan
Some Mo‐oxo complexes bearing pyridine rings have the capability for dihydrogen production from water.
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A series of polystyrene-supported molybdenum trihalide complexes bearing pyridine-based PNP-type pincer ligand were synthesized and their catalytic reactivity toward reduction of dinitrogen into am.
피리딘 기반 PNP형 집게 리간드를 갖는 폴리스티렌 지지 몰리브덴 트리할라이드 착물 시리즈가 합성되었고 이질소가 am으로 환원되는 촉매 반응성이 합성되었습니다.
A series of polystyrene-supported molybdenum trihalide complexes bearing pyridine-based PNP-type pincer ligand were synthesized and their catalytic reactivity toward reduction of dinitrogen into am.
피리딘 기반 PNP형 집게 리간드를 갖는 폴리스티렌 지지 몰리브덴 트리할라이드 착물 시리즈가 합성되었고 이질소가 am으로 환원되는 촉매 반응성이 합성되었습니다.
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Complexes Bearing sentence examples within complexes bearing tetradentate
In this work, we describe the synthesis, structural and photophysical characterization of four novel Pd(ii) and Pt(ii) complexes bearing tetradentate luminophoric ligands with high photoluminescence quantum yields (ΦL) and long excited state lifetimes (τ) at room temperature, where the results were interpreted by means of DFT calculations.
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In this work, we describe the synthesis, structural and photophysical characterization of four novel Pd(ii) and Pt(ii) complexes bearing tetradentate luminophoric ligands with high photoluminescence quantum yields (ΦL) and long excited state lifetimes (τ) at room temperature, where the results were interpreted by means of DFT calculations.
nan
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High-performance organic light-emitting diodes (OLEDs) were realized by utilizing three robust platinum(II) complexes bearing tetradentate O^N^C^N ligands with a bridging tertiary amine (tetra-Pt-N), a biphenyl group with a spiro linkage (tetra-Pt-S) or a sterically encumbered 2,6-dimethyl-4-tert-butylphenyl moiety (tetra-Pt-M).
고성능 유기발광다이오드(OLED)는 4자리 O^N^C^N 리간드와 가교 3차 아민(tetra-Pt-N)을 갖는 3개의 견고한 백금(II) 착물을 활용하여 실현되었습니다. 스피로 연결(tetra-Pt-S) 또는 입체적으로 방해가 되는 2,6-디메틸-4-tert-부틸페닐 부분(tetra-Pt-M).
High-performance organic light-emitting diodes (OLEDs) were realized by utilizing three robust platinum(II) complexes bearing tetradentate O^N^C^N ligands with a bridging tertiary amine (tetra-Pt-N), a biphenyl group with a spiro linkage (tetra-Pt-S) or a sterically encumbered 2,6-dimethyl-4-tert-butylphenyl moiety (tetra-Pt-M).
고성능 유기발광다이오드(OLED)는 4자리 O^N^C^N 리간드와 가교 3차 아민(tetra-Pt-N)을 갖는 3개의 견고한 백금(II) 착물을 활용하여 실현되었습니다. 스피로 연결(tetra-Pt-S) 또는 입체적으로 방해가 되는 2,6-디메틸-4-tert-부틸페닐 부분(tetra-Pt-M).
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