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Ruthenium-Catalyzed Oxidative Cross-Coupling Reaction of Activated Olefins with Vinyl Boronates for the Synthesis of (E,E)-1,3-Dienes.


Rhodium(III)-Catalyzed Aerobic Oxidative C-H Olefination of Unsaturated Acrylamides with Unactivated Olefins.

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Electrophilic Amination: An Update


Transition-Metal-Catalyzed Ketone α-Alkylation and Alkenylation with Simple Alkenes and Alkynes through a Dual Activation Strategy

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Hydroalkylation of Unactivated Olefins via Visible-Light-Driven Dual Hydrogen Atom Transfer Catalysis.


Rh(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C-H Activation.


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Ruthenium(II)-Catalyzed Redox-Neutral C-H Alkylation of Arylamides with Unactivated Olefins.



Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis.



Catalytic Regioselective Olefin Hydroarylation(alkenylation) by Sequential Carbonickelation-Hydride Transfer.



Ruthenium-catalyzed formal sp3 C–H activation of allylsilanes/esters with olefins: efficient access to functionalized 1,3-dienes†



Dioxygen-Triggered Oxosulfonylation/Sulfonylation of Terminal Olefins toward β-Keto Sulfones/Sulfones.



Phosphine/Photoredox Catalyzed Anti-Markovnikov Hydroamination of Olefins with Primary Sulfonamides via α-Scission from Phosphoranyl Radicals.



A Copper(I)-Catalyzed Radical-Relay Reaction Enabling the Intermolecular 1,2-Alkylborylation of Unactivated Olefins.



2-Pyridyl Sulfoxide Directed Pd(II)-Catalyzed C–H Olefination of Arenes with Molecular Oxygen as the Sole Oxidant



Reductive Activation and Hydrofunctionalization of Olefins by Multiphoton Tandem Photoredox Catalysis



Regioselective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C-H Alkynylation.



Photocatalytic Anti-Markovnikov Radical Hydro- and Aminooxygenation of Unactivated Alkenes Tuned by Ketoxime Carbonates.



Photo-Initiated Cobalt Catalyzed Radical Olefin Hydrogenation.



Aerobic Oxidative C-H Olefination of Arylamides with Unactivated Olefins via a Rh(III)-Catalyzed C-H Activation.



Palladium-Catalyzed Three-Component Coupling Reaction via Benzylpalladium Intermediate.



Photoredox-catalyzed aminofluorosulfonylation of unactivated olefins†



Catalyst-Free [3 + 3] Annulation/Oxidation of Cyclic Amidines with Activated Olefins: When the Substrate Olefin Is Also an Oxidant.



Phosphine/Photoredox Catalyzed anti-Markovnikov Hydroamination of Olefins with Primary Sulfonamides via a-Scission from Phosphoranyl Radicals



Synthesis of Deuterated (E)-Alkene through Xanthate-Mediated Hydrogen-Deuterium Exchange Reactions.



Ru(II)-Catalyzed Controlled Cross-Dehydrogenative Coupling of Benzamides with Activated Olefins via Weakly Coordinating Primary Amides.



Terminal-Selective C(sp3)–H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins



Unexpected one-pot formation of the 1H-6a,8a-epiminotri- cyclopenta[a,c,e][8]annulene system from cyclopentanone, ammonia and dimethyl fumarate. Synthesis of highly strained polycyclic nitroxide and EPR study



Leaving Group Assisted Strategy for Photoinduced Fluoroalkylations Using N-Hydroxybenzimidoyl Chloride Esters.



Visible-light-induced carbosulfonylation of unactivated alkenes via remote heteroaryl and oximino migration



Photocatalyzed Metal-Free Alkylheteroarylation of Unactivated Olefins via Direct Acidic C(sp3)-H Bond Activation.



Role of Water in the Reaction Mechanism and endo/exo Selectivity of 1,3-Dipolar Cycloadditions Elucidated by Quantum Chemistry and Machine Learning.



Visible-Light-Mediated Regioselective Chlorosulfonylation of Alkenes and Alkynes: Introducing the Cu(II) Complex [Cu(dap)Cl2] to Photochemical ATRA Reactions



Regio‐ and Stereoselective Thianthrenation of Olefins To Access Versatile Alkenyl Electrophiles



Novel biferrocene-based phosphoramidite ligands: The combination of a rather unexplored chiral backbone and a privileged ligand scaffold



Merging Photoredox PCET with Nickel-Catalyzed Cross-Coupling: Cascade Amidoarylation of Unactivated Olefins.



C-H and N-H bond annulation of aryl amides with unactivated olefins by merging cobalt(iii) and photoredox catalysis.



Origin of high stereocontrol in olefin cyclopropanation catalyzed by an engineered carbene transferase.



Direct Intermolecular Anti-Markovnikov Hydroazidation of Unactivated Olefins.



PCET-Enabled Olefin Hydroamidation Reactions with N-Alkyl Amides.



Hydroalkylation of Olefins To Form Quaternary Carbons.



Iron-Catalyzed Hydroamination and Hydroetherification of Unactivated Alkenes.



Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines.



Biocatalytic intramolecular cyclopropanation



Site-selective catalytic deaminative alkylation of unactivated olefins.



Electrochemically Promoted Fluoroalkylation-Distal Functionalization of Unactivated Alkenes.



Intramolecular nitration-aminocarbonylation of unactivated olefins: metal-free synthesis of γ-lactams.



Streamlined Ruthenium(II) Catalysis for One-Pot 2-fold Unsymmetrical C-H Olefination of (Hetero)Arenes.



Synergistic palladium/enamine catalysis for asymmetric hydrocarbon functionalization of unactivated alkenes with ketones.



A ruthenium-catalyzed free amine directed (5+1) annulation of anilines with olefins: diverse synthesis of phenanthridine derivatives.



Ni-catalysed reductive arylalkylation of unactivated alkenes† †Electronic supplementary information (ESI) available: Experimental procedure, spectral data, NMR-data, and HPLC-data. See DOI: 10.1039/c8sc04279a



Visible-Light Photoredox-Catalyzed Cascade Reaction for the Synthesis of Pyrrolo[2,1-a]isoquinoline-Substituted Phosphonates


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