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The negative standard enthalpy change (∆Hº) showed an exothermic process, the positive standard entropy change (∆Sº) displayed an increased disorder and the negative standard Gibbs free energy change (∆Gº) indicated a spontaneous adsorption method.
The negative standard enthalpy change (∆Hº) showed an exothermic process, the positive standard entropy change (∆Sº) displayed an increased disorder and the negative standard Gibbs free energy change (∆Gº) indicated a spontaneous adsorption method.
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The adsorption behavior followed Langmuir adsorption isotherm with a negative value of Gibbs free energy change, suggesting a spontaneous adsorption process.
The adsorption behavior followed Langmuir adsorption isotherm with a negative value of Gibbs free energy change, suggesting a spontaneous adsorption process.
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The adsorption of both azo dyes resulted in negative value of ΔG° which shows spontaneous adsorption of both azo dyes onto adsorbent active sites.
The adsorption of both azo dyes resulted in negative value of ΔG° which shows spontaneous adsorption of both azo dyes onto adsorbent active sites.
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In the pH effect experiment, the highest Sr2+ adsorption capacity was found at pH 9, and it has a spontaneous adsorption mechanism through experiments on temperature, time, and selectivity, and it reaches adsorption equilibrium within a short time and has high selectivity through competitive adsorption with Na+.
In the pH effect experiment, the highest Sr2+ adsorption capacity was found at pH 9, and it has a spontaneous adsorption mechanism through experiments on temperature, time, and selectivity, and it reaches adsorption equilibrium within a short time and has high selectivity through competitive adsorption with Na+.
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Finally, the adsorption kinetics, isotherm and thermodynamic studies suggested that the adsorption behavior of TH over the PAN-Cu/ABN-CNFs should be better described by the correlation coefficients of Avrami fractional-order kinetics and Liu isotherm, while the thermodynamic studies showed a favorable exothermic and spontaneous adsorption mechanism.
Finally, the adsorption kinetics, isotherm and thermodynamic studies suggested that the adsorption behavior of TH over the PAN-Cu/ABN-CNFs should be better described by the correlation coefficients of Avrami fractional-order kinetics and Liu isotherm, while the thermodynamic studies showed a favorable exothermic and spontaneous adsorption mechanism.
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10.1016/j.chemosphere.2019.125700
In addition, the removal efficiency of MTX by the hybrid material was as high as 95% within 5 min, MTX adsorption followed both a pseudo-second-order kinetic model and the Langmuir isotherm, and it is a spontaneous adsorption.
In addition, the removal efficiency of MTX by the hybrid material was as high as 95% within 5 min, MTX adsorption followed both a pseudo-second-order kinetic model and the Langmuir isotherm, and it is a spontaneous adsorption.
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10.1016/j.scitotenv.2019.135172
Thermodynamic analyses confirmed the endothermic and spontaneous adsorption behavior of Hg2+ on SAC in the seawater environment.
Thermodynamic analyses confirmed the endothermic and spontaneous adsorption behavior of Hg2+ on SAC in the seawater environment.
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10.1515/zpch-2019-1443
The negative values of enthalpy (ΔH) and free energy (ΔG) revealed exothermic and spontaneous adsorption of dye at room temperature.
The negative values of enthalpy (ΔH) and free energy (ΔG) revealed exothermic and spontaneous adsorption of dye at room temperature.
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10.1016/j.jpba.2019.112957
Kinetic, isotherm and thermodynamic analyses indicated the fast, effective and spontaneous adsorption of TC by M-LWAC.
Kinetic, isotherm and thermodynamic analyses indicated the fast, effective and spontaneous adsorption of TC by M-LWAC.
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10.1021/acs.langmuir.9b02467
Spontaneous adsorption of dialkylsiloxane chains to MWCNT surfaces (wetting) and the resulting changes in composite structure are implicated as the basis for dispersion and thermal behavior changes.
Spontaneous adsorption of dialkylsiloxane chains to MWCNT surfaces (wetting) and the resulting changes in composite structure are implicated as the basis for dispersion and thermal behavior changes.
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10.3762/bxiv.2019.60.v1
The investigation of the spontaneous adsorption of IONP@CnX2n+1OEG8Den at the interface between air or air saturated with perfluorohexane and an aqueous phase establishes that exposure to the fluorocarbon gas markedly increases the rate of adsorption of the dendronized IONPs to the gas/water interface and decreases the equilibrium interfacial tension.
The investigation of the spontaneous adsorption of IONP@CnX2n+1OEG8Den at the interface between air or air saturated with perfluorohexane and an aqueous phase establishes that exposure to the fluorocarbon gas markedly increases the rate of adsorption of the dendronized IONPs to the gas/water interface and decreases the equilibrium interfacial tension.
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10.1002/CPLU.201900036
The calculations predict more spontaneous adsorption of 2-propanol on the (111) surface of ZnFe2 O4 than 1-propanol.
The calculations predict more spontaneous adsorption of 2-propanol on the (111) surface of ZnFe2 O4 than 1-propanol.
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10.1021/acs.jpclett.9b01576
The total flux decreases sharply with hydrocarbon content before the critical value while almost holds a constant after the critical value, which is attributed to the spontaneous adsorption of hydrocarbon on the organic surface.
The total flux decreases sharply with hydrocarbon content before the critical value while almost holds a constant after the critical value, which is attributed to the spontaneous adsorption of hydrocarbon on the organic surface.
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10.4152/PEA.201902115
These values showed that exothermic and spontaneous adsorption of the extract on the mild steel followe d the mechanism of physical adsorption.
These values showed that exothermic and spontaneous adsorption of the extract on the mild steel followe d the mechanism of physical adsorption.
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10.1016/J.JHAZMAT.2019.05.096
Thermodynamically, it is endothermic, irreversible and spontaneous adsorption process.
Thermodynamically, it is endothermic, irreversible and spontaneous adsorption process.
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10.1007/s00706-019-02452-0
The deposition performed by spontaneous adsorption of the cobalt pyridinoporphyrazine complex from its aqueous solution led on basal plane HOPG to the formation of a uniform homogeneous film with simultaneous reduction of cobalt centre, while at Au(111) electrode preferential aggregation of pyridinoporphyrazine complex took place without any change of reduction state of cobalt.
The deposition performed by spontaneous adsorption of the cobalt pyridinoporphyrazine complex from its aqueous solution led on basal plane HOPG to the formation of a uniform homogeneous film with simultaneous reduction of cobalt centre, while at Au(111) electrode preferential aggregation of pyridinoporphyrazine complex took place without any change of reduction state of cobalt.
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10.1088/2053-1591/AB0831
Thermodynamic studies revealed an exothermic and spontaneous adsorption process in nature.
Thermodynamic studies revealed an exothermic and spontaneous adsorption process in nature.
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10.1016/j.molliq.2019.111864
Incorporation of nanoparticles in serum containing-media leads to spontaneous adsorption of proteins on the nanoparticle surface thus forming “protein corona”.
Incorporation of nanoparticles in serum containing-media leads to spontaneous adsorption of proteins on the nanoparticle surface thus forming “protein corona”.
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10.1002/jbm.a.36664
7 approximately, were obtained by spontaneous adsorption of INH molecules to HLNTs powder in aqueous medium.
7 approximately, were obtained by spontaneous adsorption of INH molecules to HLNTs powder in aqueous medium.
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10.22146/IJC.38978
19 kJ/mol, respectively, indicating a spontaneous adsorption process.
19 kJ/mol, respectively, indicating a spontaneous adsorption process.
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10.1016/j.jcis.2018.10.047
There was no evidence of spontaneous adsorption of particles onto the oil-water interface without ultrasound, which suggests the presence of a stabilizing force.
There was no evidence of spontaneous adsorption of particles onto the oil-water interface without ultrasound, which suggests the presence of a stabilizing force.
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10.1016/j.colsurfb.2019.110677
This application is directly related to the phenomenon of protein corona, characterized by the spontaneous adsorption of proteins on the nanoparticle surface, which is not fully understood.
This application is directly related to the phenomenon of protein corona, characterized by the spontaneous adsorption of proteins on the nanoparticle surface, which is not fully understood.
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10.1016/J.PORGCOAT.2019.04.025
The values of ΔGads are given in negative values in all cases means that spontaneous adsorption of inhibitor on steel surface and strong interaction between the inhibitor molecules and metal surface.
The values of ΔGads are given in negative values in all cases means that spontaneous adsorption of inhibitor on steel surface and strong interaction between the inhibitor molecules and metal surface.
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10.1016/j.envpol.2019.07.118
The adsorption of As(III) by PTFE was an exothermic process, and because the increase in temperature broke the hydrogen bond, the amount of adsorption was decreased, which was not conducive to spontaneous adsorption.
The adsorption of As(III) by PTFE was an exothermic process, and because the increase in temperature broke the hydrogen bond, the amount of adsorption was decreased, which was not conducive to spontaneous adsorption.
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10.1016/j.matpr.2019.05.258
Thermodynamic parameters inferred the spontaneous adsorption of inhibitor molecules on the metal surface.
Thermodynamic parameters inferred the spontaneous adsorption of inhibitor molecules on the metal surface.
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10.1016/j.jhazmat.2019.03.103
The thermodynamic parameter was analyzed further and it showed an exothermic and spontaneous adsorption process.
The thermodynamic parameter was analyzed further and it showed an exothermic and spontaneous adsorption process.
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10.1016/J.JHAZMAT.2019.120979
In addition, thermodynamic study confirmed the endothermic and spontaneous adsorption reactions.
In addition, thermodynamic study confirmed the endothermic and spontaneous adsorption reactions.
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10.3390/molecules24152714
A new G-(H2L)-Pd heterogeneous catalyst has been prepared via a self-assembly process consisting in the spontaneous adsorption, in water at room temperature, of a macrocyclic H2L ligand on graphene (G) (G + H2L = G-(H2L)), followed by decoration of the macrocycle with Pd2+ ions (G-(H2L) + Pd2+ = G-(H2L)-Pd) under the same mild conditions.
A new G-(H2L)-Pd heterogeneous catalyst has been prepared via a self-assembly process consisting in the spontaneous adsorption, in water at room temperature, of a macrocyclic H2L ligand on graphene (G) (G + H2L = G-(H2L)), followed by decoration of the macrocycle with Pd2+ ions (G-(H2L) + Pd2+ = G-(H2L)-Pd) under the same mild conditions.
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10.3389/fchem.2019.00453
The surfaces of Pd-NPs are modified by spontaneous adsorption of gold and characterized by cyclic voltammetry in acidic medium.
The surfaces of Pd-NPs are modified by spontaneous adsorption of gold and characterized by cyclic voltammetry in acidic medium.
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10.1016/J.APSUSC.2018.10.147
Ag surface modification tunes the electronic structure of SiNW considerably, which is further moderated by the spontaneous adsorptions of NO2 on surface Si site and on the modified Ag atom.
Ag surface modification tunes the electronic structure of SiNW considerably, which is further moderated by the spontaneous adsorptions of NO2 on surface Si site and on the modified Ag atom.
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10.1007/s10854-019-02336-3
Firstly, the pre-adsorption of oxygen on SnO2 (110) surface was modeled and analyzed, it was proved that the spontaneous adsorption O2 molecule and O atom could take place more easily on SnO2 (110) reductive surface than SnO2 (110) oxidative surface, and O2 molecule has more obvious tendency to be dissociated when adsorbed on SnO2 (110) reductive surface.
Firstly, the pre-adsorption of oxygen on SnO2 (110) surface was modeled and analyzed, it was proved that the spontaneous adsorption O2 molecule and O atom could take place more easily on SnO2 (110) reductive surface than SnO2 (110) oxidative surface, and O2 molecule has more obvious tendency to be dissociated when adsorbed on SnO2 (110) reductive surface.
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10.1016/J.COLSURFA.2019.05.078
To date the driving force for the spontaneous adsorption of precursors on non-modified PSB had not been investigated.
To date the driving force for the spontaneous adsorption of precursors on non-modified PSB had not been investigated.
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10.1038/s41598-019-51594-y
All adsorbents except SIMRDP have spontaneous adsorption process.
All adsorbents except SIMRDP have spontaneous adsorption process.
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10.1002/jctb.6223
The thermodynamic parameter values suggested that endothermic and spontaneous adsorption occurred.
The thermodynamic parameter values suggested that endothermic and spontaneous adsorption occurred.
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10.1080/12269328.2018.1493955
ΔG values obtained were all negative for both resins indicating a spontaneous adsorption process.
ΔG values obtained were all negative for both resins indicating a spontaneous adsorption process.
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10.3762/bjnano.10.205
The investigation of the spontaneous adsorption of IONP@CnX2 n +1OEG8Den at the interface between air or air saturated with perfluorohexane and an aqueous phase establishes that exposure to the fluorocarbon gas markedly increases the rate of adsorption of the dendronized IONPs to the gas/water interface and decreases the equilibrium interfacial tension.
The investigation of the spontaneous adsorption of IONP@CnX2 n +1OEG8Den at the interface between air or air saturated with perfluorohexane and an aqueous phase establishes that exposure to the fluorocarbon gas markedly increases the rate of adsorption of the dendronized IONPs to the gas/water interface and decreases the equilibrium interfacial tension.
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10.1016/J.JMRT.2018.10.018
Thermodynamic parameters obtained indicate an endothermic and spontaneous adsorption process for lanthanum and exothermic and nonspontaneous adsorption process for cerium.
Thermodynamic parameters obtained indicate an endothermic and spontaneous adsorption process for lanthanum and exothermic and nonspontaneous adsorption process for cerium.
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10.3390/w11112342
The thermodynamic parameters indicated that the experiments proceeded as exothermic and spontaneous adsorption.
The thermodynamic parameters indicated that the experiments proceeded as exothermic and spontaneous adsorption.
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10.1080/10601325.2019.1586444
For thermochemistry parameters at different temperatures, the negative ΔG° showed a spontaneous adsorption process, the negative ΔH° indicated an exothermic process and the positive ΔS° exhibited an increase disorder.
For thermochemistry parameters at different temperatures, the negative ΔG° showed a spontaneous adsorption process, the negative ΔH° indicated an exothermic process and the positive ΔS° exhibited an increase disorder.
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10.1016/j.ijbiomac.2019.12.065
56 mg/g through an endothermic and spontaneous adsorption process that could be used for up to 5 cycles of adsorption process.
56 mg/g through an endothermic and spontaneous adsorption process that could be used for up to 5 cycles of adsorption process.
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10.1007/s10924-019-01372-8
Negative values of ΔGº for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel.
Negative values of ΔGº for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel.
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10.1007/s42247-019-00060-6
05 J mol−1 K−1 for solution containing lead concentration between 5 and 20 mg L−1 indicated an exothermic and spontaneous adsorption process.
05 J mol−1 K−1 for solution containing lead concentration between 5 and 20 mg L−1 indicated an exothermic and spontaneous adsorption process.
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10.1016/J.JTICE.2018.12.017
Thermodynamic analysis implied the physisorption dominated the spontaneous adsorption process.
Thermodynamic analysis implied the physisorption dominated the spontaneous adsorption process.
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10.1016/j.jcis.2018.11.008
The surface charge induced by spontaneous adsorption of hydroxyl ions on MoS2 surfaces favors the exfoliation process.
The surface charge induced by spontaneous adsorption of hydroxyl ions on MoS2 surfaces favors the exfoliation process.
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10.1039/C8RA09279F
Thermodynamic parameters (ΔH° and ΔG°) reflected the exothermic and spontaneous adsorption process.
Thermodynamic parameters (ΔH° and ΔG°) reflected the exothermic and spontaneous adsorption process.
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10.1021/acs.jpcb.9b05110
We show that such spontaneous adsorption can indeed be initiated by the interactions of loose polycation chains of the polyplex with polar head groups of lipids.
We show that such spontaneous adsorption can indeed be initiated by the interactions of loose polycation chains of the polyplex with polar head groups of lipids.
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10.1007/s42823-019-00017-z
As an eco-friendly and versatile adhesive source in nature, dopamine could be easily adhered to surfaces of organic material and inorganic material via polymerization processes and spontaneous adsorption under weak alkaline pH conditions.
As an eco-friendly and versatile adhesive source in nature, dopamine could be easily adhered to surfaces of organic material and inorganic material via polymerization processes and spontaneous adsorption under weak alkaline pH conditions.
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10.1007/s11356-019-06059-0
The negative ΔG° values indicated a spontaneous adsorption process.
The negative ΔG° values indicated a spontaneous adsorption process.
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10.1016/J.ENMM.2019.100233
Thermodynamic investigation showed that the lead ion adsorption process is exothermic and spontaneous in both adsorbents, the degree of spontaneous adsorption process in the magnetic composite of HAp/Fe3O4 is higher, and the energy required for the adsorption process is less than that of HAp.
Thermodynamic investigation showed that the lead ion adsorption process is exothermic and spontaneous in both adsorbents, the degree of spontaneous adsorption process in the magnetic composite of HAp/Fe3O4 is higher, and the energy required for the adsorption process is less than that of HAp.
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10.1016/J.MOLLIQ.2018.12.010
In addition, the thermodynamic data suggested a spontaneous adsorption process with endothermic characteristics.
In addition, the thermodynamic data suggested a spontaneous adsorption process with endothermic characteristics.
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10.1007/s10450-019-00156-9
86 kJ mol −1 , for MB and RB5 removal onto nGO-(NH)R respectively, which evidenced the spontaneous adsorption of both dyes and chemisorption behavior of RB5.
86 kJ mol −1 , for MB and RB5 removal onto nGO-(NH)R respectively, which evidenced the spontaneous adsorption of both dyes and chemisorption behavior of RB5.
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10.1021/acsabm.9b00601
Spontaneous adsorption of poly(lysine)-g-poly(ethylene glycol) comb-like copolymers (PLL-g-PEG) is a versatile mean to coat substrates with polymer layers that resist cell adhesion.
Spontaneous adsorption of poly(lysine)-g-poly(ethylene glycol) comb-like copolymers (PLL-g-PEG) is a versatile mean to coat substrates with polymer layers that resist cell adhesion.
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10.3390/ma12081294
The endothermic and spontaneous adsorption follows a pseudo-second-order kinetic model, and the adsorption equilibrium data fit the Temkin isotherm well.
The endothermic and spontaneous adsorption follows a pseudo-second-order kinetic model, and the adsorption equilibrium data fit the Temkin isotherm well.
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10.1016/j.biortech.2019.122100
Benefiting from a large number of adsorption sites and multiple interactions, PEI@MCNTs possessed high selectivity towards ARS with spontaneous adsorption process.
Benefiting from a large number of adsorption sites and multiple interactions, PEI@MCNTs possessed high selectivity towards ARS with spontaneous adsorption process.
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10.1039/c9sm01551e
-30 mV, spontaneous adsorption occurred, coupled with augmented interfibrillar interactions, yielding stronger and tougher interfacial gels.
-30 mV, spontaneous adsorption occurred, coupled with augmented interfibrillar interactions, yielding stronger and tougher interfacial gels.
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Keywords related to Adsorption
Green Adsorption
Crvi Adsorption
Gate Adsorption
Atomic Adsorption
Flow Adsorption
Cd Adsorption
Sodium Adsorption
Bed Adsorption
Bsa Adsorption
Hydrochloride Adsorption
Physical Adsorption
Dissociative Adsorption
Critical Adsorption
Active Adsorption
Atrazine Adsorption
Pollutant Adsorption
Layer Adsorption
Equilibrium Adsorption
Outstanding Adsorption
Multicomponent Adsorption
Stable Adsorption
Moisture Adsorption
Excess Adsorption
Co Adsorption
Polymer Adsorption
Surfactant Adsorption
Solar Powered Adsorption
Sequential Adsorption
P Adsorption
Orange Adsorption
Removal Adsorption
Dna Adsorption
Sulfate Adsorption
Au Adsorption
Bacterial Adsorption
Ash3 Adsorption
Atom Adsorption
Multi Component Adsorption
Chemical Adsorption
H2 Adsorption
Superb Adsorption
4 Adsorption
Liquid Adsorption
Ammonia Adsorption
Zn Adsorption
Cations Adsorption
Ligand Adsorption
Mercury Adsorption
Oil Adsorption
Li Ion Adsorption
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