Introduction to Pd Ii Complexes
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Differently pyrrole-fused porphyrins 5H and 6H and their PdII complexes 5Pd and 6Pd were also synthesized.
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A series of PdII complexes with bis-(2-pyridylmethyl)glycine as a ligand of formula [PdX(bis-(2-pyridylmethyl)glycine)] where X = Cl, Br, I were prepared and the effect of the halogen nature in the antitumor activity of eight tumorigenic and one non-tumorigenic cell line was evaluated.
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The properties of these ligands were examined by synthesizing RhI , AuI , and PdII complexes.
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The symmetric ligands [Ar-S-CH2-Ph-S-(CH2)-]2, L1 (Ar = o-FPh) and L2 (Ar = p-FPh), and their PdII complexes (1 and 2) were synthesized and structurally characterized.
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Phenyl groups were introduced at the β-positions proximal to the meso-hydroxy moiety in hydroxyporphyrin NiII complexes by oxidized BINAP PdII complexes.
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