Introduction to Pd Coordination
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The amorphous Pd–P NPs catalyst exhibits the highest activity for electrocatalytic hydrodechlorination and good cycling stability when the Pd–P coordination number is 3 and the Pd–Pd coordination number is 4.
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The Pd/Bi2O3 cluster, of which the hybrid structure is elucidated by combined electron microscopy and microanalysis, features a small Pd-Pd coordination number and more importantly a Pd-Bi spatial correlation ascribed to the heterografting between Pd and Bi terminated Bi2O3 clusters.
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The amorphous Pd–P NPs catalyst exhibits the highest activity for electrocatalytic hydrodechlorination and good cycling stability when the Pd–P coordination number is 3 and the Pd–Pd coordination number is 4.
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The Pd/Bi2O3 cluster, of which the hybrid structure is elucidated by combined electron microscopy and microanalysis, features a small Pd-Pd coordination number and more importantly a Pd-Bi spatial correlation ascribed to the heterografting between Pd and Bi terminated Bi2O3 clusters.
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Aiming at understanding the effects of Pd coordination number and environment on the catalytic performance of C2H2 semi-hydrogenation, DFT calculations were performed to illustrate C2H2 semi-hydrogenation mechanism on the M(M = Cu, Ag, Au) alloyed single-atom Pd catalysts with surface Pd coordination numbers of 7, 8 and 9.
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While there is an increasing research interest in investigating the performance effect of supply chain coordination in Western countries, little attention has been paid to whether and how NPD coordination influences innovation performance in China.
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Measured apparent activation enthalpies and calculated activation barriers for H2O2 and H2O formation both increase as Pd is diluted by Au, even beyond the complete loss of Pd-Pd coordination.
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Herein, we report the direct Pd coordination on the azobenzene linker within a MOF catalyst through a postsynthetic modification method for a Suzuki-Miyaura coupling reaction.
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Furthermore, these results demonstrate that exposure to CO at room temperature, which is often used as a proxy for evaluating the Pd coordination sites available in a catalyst, changes the surface structure.
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As such, the simulation results provide a basis for controlling the impacts of direct lightning strikes on electrical equipment and power grids and thus justify SPD coordination to ensure the reliability of the system.
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