Introduction to Molecular Analogues
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Modifying the quats (quaternary ammonium cationic materials) with PDMS (polydimethylsiloxane) gave the strongest surface affinity, but we believe this diluted the effect of antistatic behavior versus lower molecular analogues due to the lower molar concentration of active groups.
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In this study, we synthesized a series of previously unexplored molecular analogues of halogenated quinone and naphthoquinone to investigate their therapeutic potency against protein glycation, free radical production and acetyl cholinesterase enzyme.
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In the second exercise, the concepts of band structures, band crossing, and k-space are explored using the results of frontier orbital calculations on π-stacked dimers of polycyclic aromatic hydrocarbons, which represent molecular analogues of layered 2D materials.
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We have now synthesized five intramolecular analogues (isoquinolinium linked by a trimethylene tether to alkyl benzenes) that proved to be well suited to demonstrating that emissive exciplexes can be formed in water from purely organic components.
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In this study, we demonstrate the existence of ion pairs in the gas phase and dissect the interaction energies exclusively from measured vaporization enthalpies of different alkylated protic ILs (PILs) and aprotic ILs (AILs) and the molecular analogues of their cations.
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Thermochemistry of the resulting phenazinoid structures was compared to PT and ET energies of corresponding quinoxaline molecular analogues.
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These prototype supported complexes contain small thiolates but still, they are slightly more Z-selective than their molecular analogues.
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Lastly, we describe how catalysis at graphite-conjugated sites proceeds through mechanisms involving concerted electron transfer and substrate activation, in stark contrast to the mechanisms observed for molecular analogues.
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