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10.1016/j.molliq.2019.111769

Isotropic-nematic transition parameters have been calculated for three different systems of ellipses characterized by their major to minor axis ratio κ = 3.

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10.1016/J.POLYMER.2018.11.041

5% SA located in entangled semi-dilute regime could induce the isotropic-nematic transition of GO at low concentration (.

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10.1088/1361-648X/aaf843

This phenomenon leads to a shift in the isotropic-nematic transition temperature.

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10.1088/1361-648X/ab0394

Importantly, our relaxation method is able to follow the thermodynamic behavior provided by other non-phenomenological approaches; we predict the first order character of the isotropic-nematic transition, and we identify the uniaxial-biaxial transition as second order.

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10.1016/j.cis.2019.102076

With increasing NCC concentration, the isotropic phase can undergo a transition to a liquid crystalline state (isotropic-nematic transition) or a transition to a dynamically arrested solid (liquid-solid transition).

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10.1080/02678292.2019.1645366

In the attempt to go beyond a simple Onsager theoretical approach to understand the thermodynamic behavior of this system, we introduced some years ago a general theoretical description, which models the isotropic-nematic transition by properly taking into account molecular self-assembly, and we carefully verified the theoretical predictions against numerical simulations of patchy hard cylinders.

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Isotropic Nematic Transition

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Dec 10, 2023

What is/are Isotropic Nematic Transition?

Isotropic Nematic Transition - Isotropic-nematic transition parameters have been calculated for three different systems of ellipses characterized by their major to minor axis ratio κ = 3. ^[1] 5% SA located in entangled semi-dilute regime could induce the isotropic-nematic transition of GO at low concentration (. ^[2] This phenomenon leads to a shift in the isotropic-nematic transition temperature. ^[3] Importantly, our relaxation method is able to follow the thermodynamic behavior provided by other non-phenomenological approaches; we predict the first order character of the isotropic-nematic transition, and we identify the uniaxial-biaxial transition as second order. ^[4] With increasing NCC concentration, the isotropic phase can undergo a transition to a liquid crystalline state (isotropic-nematic transition) or a transition to a dynamically arrested solid (liquid-solid transition). ^[5] In the attempt to go beyond a simple Onsager theoretical approach to understand the thermodynamic behavior of this system, we introduced some years ago a general theoretical description, which models the isotropic-nematic transition by properly taking into account molecular self-assembly, and we carefully verified the theoretical predictions against numerical simulations of patchy hard cylinders. ^[6]