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hydrogen evolving catalyst

We have successfully integrated a covalently bonded hydrogen evolving catalyst (Complex A) into a highly stable photosensitizable UiO-MOF by a facile click reaction synthesis.

Incorporation of iron hydrogenase active sites into a stable photosensitizing metal-organic framework for enhanced hydrogen production

hydrogen evolving catalyst

A facial cobalt(III) polypyridyl complex was characterized by several spectroscopic and electrochemical techniques and utilized as a robust hydrogen evolving catalyst in both organic and aqueous media.

Electrocatalytic proton and water reduction by a Co(III) polypyridyl complex

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hydrogen evolving system

Bubble behavior in a hydrogen evolving system was compared to that under boiling conditions.

Comparison of bubble parameters between boiling and hydrogen evolving systems

hydrogen evolving system

It is concluded that the water CHF condition can be simulated by the non-heating hydrogen evolving system.

Simulation of Critical Heat Flux Phenomenon Using a Non-heating Hydrogen Evolving System

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10.1016/j.expthermflusci.2020.110316

Bubble behavior in a hydrogen evolving system was compared to that under boiling conditions.

Comparison of bubble parameters between boiling and hydrogen evolving systems

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10.1595/205651322x16269403109779

Here, a series of hydrogen evolving photocatalysts based on a ruthenium(II) bipyridyl sensitiser covalently linked to Pt or Pd catalytic centres were adsorbed onto mesoporous NiO and tested for hydrogen evolution in a photoelectrochemical half-cell.

Photoelectrochemical Hydrogen Evolution Using Dye-Sensitised NiO

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10.1021/acs.inorgchem.1c00900

The hydrogen evolving activity of the materials was explored in pH 1.

Hydrogen Evolving Activity of Dithiolene-Based Metal-Organic Frameworks with Mixed Cobalt and Iron Centers.

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10.1080/00958972.2021.1918339

The hydrogen evolving mechanism is discussed and the complexes are compared to their non-alkylated analogs using DFT calculations.

Structural modifications on nickel dithiolene complexes lead to increased metal participation in the electrocatalytic hydrogen evolution mechanism

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10.1016/J.APCATB.2021.120091

Under minimally optimized conditions, the resulting POM@MOF composites can effectively photocatalyze hydrogen production with superior long-term stability and reusability, achieving a hydrogen evolving rate of 3482 and 13051 μmol g−1 h−1 for Ni3PW10@NU-1000 and Ni3P2W16@NU-1000, respectively.

Facile integration of Ni-substituted polyoxometalate catalysts into mesoporous light-responsive metal-organic framework for effective photogeneration of hydrogen

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10.1016/J.NANOEN.2021.106402

Benefitting from high density reactive sites and fluent mass transfer as a result of trimodal porous architecture and strong electronic modulation from NiZn intermetallic, TMP NiZn-Ni/NF primely overcomes the sluggish hydrogen evolving kinetics with superior catalytic performances comparable to Pt/C and many other reported similar electrocatalysts.

Free-standing trimodal porous NiZn intermetallic and Ni heterojunction as highly efficient hydrogen evolution electrocatalyst in the alkaline electrolyte

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10.1016/J.APCATB.2019.117979

We have successfully integrated a covalently bonded hydrogen evolving catalyst (Complex A) into a highly stable photosensitizable UiO-MOF by a facile click reaction synthesis.

Incorporation of iron hydrogenase active sites into a stable photosensitizing metal-organic framework for enhanced hydrogen production

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10.1016/J.POLY.2018.11.053

A facial cobalt(III) polypyridyl complex was characterized by several spectroscopic and electrochemical techniques and utilized as a robust hydrogen evolving catalyst in both organic and aqueous media.

Electrocatalytic proton and water reduction by a Co(III) polypyridyl complex

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10.1016/J.JPOWSOUR.2018.12.034

50 mA cm−2 owing to superior charge transport in hybrid photocathode as compared to pristine Si nanowires for hydrogen evolving reaction at pH∼7.

g-C3N4 nanosheets functionalized silicon nanowires hybrid photocathode for efficient visible light induced photoelectrochemical water reduction

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10.1039/C9TA01220F

1)-textured polycrystalline WSe2 films are developed as hydrogen evolving photoelectrodes and improved through deposition of a thin ammonium thiomolybdate (NH4)2Mo3S13 catalyst film.

Efficient charge transfer at a homogeneously distributed (NH4)2Mo3S13/WSe2 heterojunction for solar hydrogen evolution

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10.1016/J.APSUSC.2019.03.250

The resulting ip-CoP/CF demonstrates improved hydrogen evolving efficiency in both acidic and alkaline conditions.

Engineering inner-porous cobalt phosphide nanowire based on controllable phosphating for efficient hydrogen evolution in both acidic and alkaline conditions

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10.3389/fenrg.2019.00139

It is concluded that the water CHF condition can be simulated by the non-heating hydrogen evolving system.

Simulation of Critical Heat Flux Phenomenon Using a Non-heating Hydrogen Evolving System

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10.1021/jacs.9b07084

Being one of the very few hydrogen evolving electrocatalytic MOFs based on a redox-active metallo-linker, this work explores uncharted terrain for greater catalyst diversity and charge transport pathways.

Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal–Organic Framework Thin Film

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Hydrogen Evolving - Bubble behavior in a hydrogen evolving system was compared to that under boiling conditions. [1] Here, a series of hydrogen evolving photocatalysts based on a ruthenium(II) bipyridyl sensitiser covalently linked to Pt or Pd catalytic centres were adsorbed onto mesoporous NiO and tested for hydrogen evolution in a photoelectrochemical half-cell. [2] The hydrogen evolving activity of the materials was explored in pH 1. [3] The hydrogen evolving mechanism is discussed and the complexes are compared to their non-alkylated analogs using DFT calculations. [4] Under minimally optimized conditions, the resulting POM@MOF composites can effectively photocatalyze hydrogen production with superior long-term stability and reusability, achieving a hydrogen evolving rate of 3482 and 13051 μmol g−1 h−1 for Ni3PW10@NU-1000 and Ni3P2W16@NU-1000, respectively. [5] Benefitting from high density reactive sites and fluent mass transfer as a result of trimodal porous architecture and strong electronic modulation from NiZn intermetallic, TMP NiZn-Ni/NF primely overcomes the sluggish hydrogen evolving kinetics with superior catalytic performances comparable to Pt/C and many other reported similar electrocatalysts. [6] We have successfully integrated a covalently bonded hydrogen evolving catalyst (Complex A) into a highly stable photosensitizable UiO-MOF by a facile click reaction synthesis. [7] A facial cobalt(III) polypyridyl complex was characterized by several spectroscopic and electrochemical techniques and utilized as a robust hydrogen evolving catalyst in both organic and aqueous media. [8] 50 mA cm−2 owing to superior charge transport in hybrid photocathode as compared to pristine Si nanowires for hydrogen evolving reaction at pH∼7. [9] 1)-textured polycrystalline WSe2 films are developed as hydrogen evolving photoelectrodes and improved through deposition of a thin ammonium thiomolybdate (NH4)2Mo3S13 catalyst film. [10] The resulting ip-CoP/CF demonstrates improved hydrogen evolving efficiency in both acidic and alkaline conditions. [11] It is concluded that the water CHF condition can be simulated by the non-heating hydrogen evolving system. [12] Being one of the very few hydrogen evolving electrocatalytic MOFs based on a redox-active metallo-linker, this work explores uncharted terrain for greater catalyst diversity and charge transport pathways. [13]

hydrogen evolving catalyst

We have successfully integrated a covalently bonded hydrogen evolving catalyst (Complex A) into a highly stable photosensitizable UiO-MOF by a facile click reaction synthesis. [1] A facial cobalt(III) polypyridyl complex was characterized by several spectroscopic and electrochemical techniques and utilized as a robust hydrogen evolving catalyst in both organic and aqueous media. [2]

hydrogen evolving system

Bubble behavior in a hydrogen evolving system was compared to that under boiling conditions. [1] It is concluded that the water CHF condition can be simulated by the non-heating hydrogen evolving system. [2]