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Enantio- and Diastereodivergent Sequential Catalysis featuring Two Transition Metal-Catalyzed Asymmetric Reactions.



A Cyanide‐free Biocatalytic Process for Synthesis of Complementary Enantiomers of 4‐Chloro‐3‐hydroxybutanenitrile From Allyl Chloride


Enantiomeric Excess sentence examples within asymmetric transfer hydrogenation



Enantioselective Synthesis of Bicyclopentane-Containing Alcohols via Asymmetric Transfer Hydrogenation.



New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2’-Bis(aminomethyl)-1,1’-binaphthyl


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A multi-enzyme cascade for efficient production of d-p-hydroxyphenylglycine from l-tyrosine




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Mg/BOX complexes as efficient catalysts for the enantioselective Michael addition of malonates to β-trifluoromethyl-α,β-unsaturated ketones and their N-tosyl imines



Chiral Phosphotungstate Functionalized with (S)-1-Phenylethylamine: Synthesis, Characterization, and Asymmetric Epoxidation of Styrene.


Enantiomeric Excess sentence examples within Excellent Enantiomeric Excess



Gold-catalysed asymmetric net addition of unactivated propargylic C–H bonds to tethered aldehydes



Construction of polycyclic structures with vicinal all-carbon quaternary stereocenters via an enantioselective photoenolization/Diels–Alder reaction†


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Nafion membranes modified by cationic cyclodextrin derivatives for enantioselective separation



Selective BuChE Inhibitory Activity, Chemical Composition, and Enantiomeric Content of the Essential Oil from Salvia leucantha Cav. Collected in Ecuador


Enantiomeric Excess sentence examples within Product Enantiomeric Excess



Two (Chemo)-Enzymatic Cascades for the Production of Opposite Enantiomers of Chiral Azidoalcohols



Kinetics of enzyme-catalysed desymmetrisation of prochiral substrates: product enantiomeric excess is not always constant


Enantiomeric Excess sentence examples within Variou Enantiomeric Excess



Impact of chirality on the amorphous state of conglomerate forming systems: a case study of N-acetyl-α-methylbenzylamine.



Slow kinetic evolution of nanohelices based on gemini surfactant self-assemblies with various enantiomeric excess; chiral segregation towards a racemic mixture


Enantiomeric Excess sentence examples within Moderate Enantiomeric Excess



Synthesis of pyrano[3,2-c]quinoline derivatives using catalyst prepared from L-proline and p-toluenesulfonic acid



Immobilization of (l)-valine and (l)-valinol on SBA-15 nanoporous silica and their application as chiral heterogeneous ligands in the Cu-catalyzed asymmetric allylic oxidation of alkenes


Enantiomeric Excess sentence examples within Crystal Enantiomeric Excess



Spontaneous and induced chiral symmetry breaking of stereolabile pillar[5]arene derivatives upon crystallisation



Chiral Optical Force Generated by a Superchiral Near-Field of a Plasmonic Triangle Trimer as Origin of Giant Bias in Chiral Nucleation: A Simulation Study


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Application of Aromatic Amide-Derived Atropisomers as Chiral Solvating Agents for Discrimination of Optically Active Mandelic Acid Derivatives in 1 H NMR Spectroscopy.



Efficiently Enantioselective Hydrogenation Photosynthesis of (R)-1-[3,5-Bis(trifluoromethyl)phenyl] ethanol over a CLEs-TiO2 Bioinorganic Hybrid Materials.


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HPLC separation of 2-aryloxycarboxylic acid enantiomers on chiral stationary phases



MCDCalc: Markov Chain Molecular Descriptors Calculator for Medicinal Chemistry.


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10.1016/j.jinorgbio.2020.111338

Zr-based acid-stable nucleotide coordination polymers: An excellent platform for acidophilic enzymes immobilization.



Application of Aromatic Amide-Derived Atropisomers as Chiral Solvating Agents for Discrimination of Optically Active Mandelic Acid Derivatives in 1 H NMR Spectroscopy.


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10.1038/s41467-021-24344-w

A curved host and second guest cooperatively inhibit the dynamic motion of corannulene


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10.1021/acs.jpclett.1c00548

Supramolecular Chirality Suppresses Molecular Chirality: Selective Chiral Recognition in Hierarchically Coassembled Pyridine-Benzimidazole Conjugates with Precise ee% Detection.



The Impact of Computational Uncertainties on the Enantioselectivity Predictions: A Microkinetic Modeling of Ketone Transfer Hydrogenation with a Noyori‐type Mn‐diamine Catalyst



Lipase Assisted (S)-Ketoprofen Resolution from Commercially Available Racemic Mixture


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10.1016/J.MICROC.2021.106214

Dual chiral selectors modified magnetic particles for enantioseparation of tryptophan and mandelic acid enantiomers in aqueous medium


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10.1016/j.procbio.2020.12.017

Lipase from pseudomonas cepacia immobilized into ZIF-8 as bio-catalyst for enantioselective hydrolysis and transesterification



Recent advances in organocatalytic asymmetric aza-Michael reactions of amines and amides



Evaluation of gem-Diacetates as Alternative Reagents for Enzymatic Regio- and Stereoselective Acylation of Alcohols.


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10.1007/s11244-021-01434-z

Restructuring Effects in the Platinum-Catalysed Enantioselective Hydrogenation of Ethyl Pyruvate



Computational Insights into Privileged Stereocontrolling Interactions Involving Chiral Phosphates and Iminium Intermediates.



Enantioselective decarboxylative protonation and deuteration of β-ketocarboxylic acids.



Metal-free Deoxygenation of Chiral Nitroalkanes: an Easy Entry to α-substituted Enantiomerically Enriched Nitriles.


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10.1016/j.ijpharm.2021.120944

Prolonged anesthesia and decreased toxicity of enantiomeric-excess Bupivacaine loaded in Ionic gradient liposomes.



Chiral Arylated Amines via C-N Coupling of Chiral Amines with Aryl Bromides Promoted by Light.


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10.20944/preprints202104.0677.v1

Design of Iridium N-Heterocyclic Carbene Amino Acid Catalysts for Asymmetric Transfer Hydrogenation of Ketones



Radiosynthesis of 1-(2-[18F]Fluoroethyl)-L-Tryptophan using a One-pot, Two-step Protocol.


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10.1016/J.REACTFUNCTPOLYM.2021.104828

Designing of amino functionalized imprinted polymeric resin for enantio-separation of (±)-mandelic acid racemate



Biocatalytic asymmetric synthesis of (R)-1-tetralol using Lactobacillus paracasei BD101.


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10.1016/J.TET.2021.132085

Stereoselective protonation of 2-methyl-1-tetralone lithium enolate catalyzed by salan-type diamines



Production of Optically Active Hexahydrocurcumin by Human Intestinal Bacterium in Vitro.



A noncovalent hybrid of [Pd(phen)(OAc)2] and st-DNA for the enantioselective hydroamination of β-nitrostyrene with methoxyamine.



Enantio-detection via the cavity-assisted three-photon process



Lipase-Catalyzed Kinetic Resolution of Dimethyl and Dibutyl 1-Butyryloxy-1-carboxymethylphosphonates



Effective enantiomeric identification of aromatic amines by tyrosine-modified pillar[5]arenes as chiral NMR solvating agents



Magnetic Molecularly Imprinted Polymers Based on Dehydroabietylamine as Chiral Monomers for the Enantioseparation of RS-Mandelic Acid


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10.1016/J.MCAT.2021.111578

Deracemization of diastereomerically pure syn- and anti-α-substituted β-hydroxyesters by Novozyme 435 lipase and determination of their absolute configuration by NMR spectroscopy



Discrimination of enantiomers of amides with two stereogenic centers enabled by chiral bisthiourea derivatives using 1H NMR spectroscopy.



Modulating the Enantiodiscrimination Features of Inherently Chiral Selectors by Molecular Design: A HPLC and Voltammetry Study Case with Atropisomeric 2,2’‐Biindole‐Based Monomers and Oligomer Films


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10.1007/s11172-021-3165-8

HPLC separation of 2-aryloxycarboxylic acid enantiomers on chiral stationary phases


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10.3390/molecules26133919

Synthesis, Enantiomeric Resolution and Biological Evaluation of HIV Capsid Inhibition Activity for Racemic, (S)- and (R)-PF74


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10.1007/s00726-020-02939-9

Colorimetric recognition of aromatic amino acid enantiomers by gluconic acid-capped gold nanoparticles.



Conformational Landscape, Chirality Recognition and Chiral Analyses: Rotational Spectroscopy of Tetrahydro-2-Furoic Acid···Propylene Oxide Conformers.



Essential Oil and Major Non-Volatile Secondary Metabolites from the Leaves of Amazonian Piper subscutatum


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10.1016/J.INOCHE.2021.108718

Near-infrared laser–assisted [email protected]@L-proline catalyzed asymmetric aldol reaction


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10.1007/s11172-021-3163-x

Novel C2-symmetric phenylglycine derivatives as organocatalysts of the Michael reaction between nitroalkenes and ketones


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10.1080/10826068.2021.1925913

Optimization of asymmetric reduction conditions of 1-(benzo [d] [1,3] dioxol-5-yl) ethanone by Lactobacillus fermentum P1 using D-optimal experimental design-based model.


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10.1016/J.CHEMPR.2021.06.009


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10.33774/chemrxiv-2021-czw58

Molecular Chirality and Cloud Activation Potentials of Dimeric α-Pinene Oxidation Products



Enabling highly (R)-enantioselective epoxidation of styrene by engineering unique non-natural P450 peroxygenases†



Symmetry Breaking and Autocatalytic Amplification in Soai Reaction Confined within UiO‐MOFs under Heterogenous Conditions.


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10.3390/molecules26164944

Green Multi-Platform Solution for the Quantification of Levodopa Enantiomeric Excess in Solid-State Mixtures for Pharmacological Formulations


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10.1016/j.mcat.2021.111811

Catalytic and molecular insights of the esterification of ibuprofen and ketoprofen with glycerol


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10.1134/S1070428021040138

Selective Hydrogen Transfer in N-(Diphenylmethyl)-1-phenylethan-1-imine



Chiral analysis of pantolactone with molecular rotational resonance spectroscopy.



Enzymatic Asymmetric Reduction of Unfunctionalized C=C Bonds with Archaeal Geranylgeranyl Reductases


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10.1016/J.MEMSCI.2021.119350

Chiral separation of β-cyclodextrin modified graphene oxide membranes with a complete enantioseparation performance


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10.1016/j.chroma.2021.462475

In situ fabrication of chiral covalent triazine frameworks membranes for enantiomer separation.



Gold-Catalyzed Domino Cycloisomerization/Alkoxylation: An Entry to 3,4-Dihydro-1H-[1,4]oxazino[4,3-a]indole.


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10.21577/0103-5053.20210012

Chemoenzymatic Synthesis of Apremilast: A Study Using Ketoreductases and Lipases



l-Cysteine-Modified Graphene Oxide-Based Membrane for Chiral Selective Separation.



Lipase Catalyzed Synthesis of Enantiopure Precursors and Derivatives for β-Blockers Practolol, Pindolol and Carteolol



Straight from the bottle! Wine and juice dicarboxylic acids as templates for supramolecular cage self-assembly.



Highly Enantioselective Iridium(I)‐Catalyzed Hydrocarbonation of Alkenes: A Versatile Approach to Heterocyclic Systems Bearing Quaternary Stereocenters


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10.21203/rs.3.rs-600789/v1

Secretory Expression of Cyclohexanone Monooxygenase by Methylotrophic Yeast for Efficient Omeprazole Sulfide Bio-oxidation


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10.1007/S13369-021-05769-3

Optimization of Biocatalytic Production of Enantiopure (S)-1-(4-Methoxyphenyl) Ethanol with Lactobacillus senmaizuke Using the Box–Behnken Design-Based Model


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10.1016/J.JCAT.2021.08.001

Perovskite La0.7Sr0.3Fe0.8B0.2O3 (B = Ti, Mn, Co, Ni, and Cu) as heterogeneous electrocatalysts for asymmetric electrocarboxylation of aromatic ketones



Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field.


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10.1186/s40643-021-00435-w

Chemoenzymatic access to enantiopure N-containing furfuryl alcohol from chitin-derived N-acetyl-D-glucosamine



Helical springs as a color indicator for determining chirality and enantiomeric excess



Chiral Bifunctional Phosphine Ligand-Enabled Cooperative Cu Catalysis: Formation of Chiral α,β-Butenolides via Highly Enantioselective γ-Protonation.



Enantioselective Recognition of Racemic Amino Alcohols in Aqueous Solution by Chiral Metal‐Oxide Keplerate {Mo132} Cluster Capsules


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10.21203/RS.3.RS-301504/V1

Chiroptical activity of hydroxycarboxylic acids: implications for the origin of biological homochirality



Constitutive Secretory Expression and Characterization of Nitrilase from Alcaligenes faecalis in Pichia pastoris for Production of R-mandelic Acid.


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10.33774/chemrxiv-2021-zqpq8

A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors for Alcohols with Remote γ-Stereocenters



Computational Redesign of an ω-Transaminase from Pseudomonas jessenii for Asymmetric Synthesis of Enantiopure Bulky Amines


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10.1186/s13568-021-01278-6

Effective asymmetric preparation of (R)-1-[3-(trifluoromethyl)phenyl]ethanol with recombinant E. coli whole cells in an aqueous Tween-20/natural deep eutectic solvent solution


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10.1016/j.seppur.2020.117717

A novel chiral polyester composite membrane: Preparation, enantioseparation of chiral drugs and molecular modeling evaluation


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10.1016/j.aca.2020.12.058

Electrochemical enantioselective sensor for effective recognition of tryptophan isomers based on chiral polyaniline twisted nanoribbon.



Enantioselective Antiport in Asymmetric Nanochannels.


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10.1016/j.tet.2021.132315

High-throughput screening of α-chiral-primary amines to determine yield and enantiomeric excess


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10.1186/s40643-021-00430-1

Secretory expression of cyclohexanone monooxygenase by methylotrophic yeast for efficient omeprazole sulfide bio-oxidation



Iridium-catalyzed C3-selective asymmetric allylation of 7-azaindoles with secondary allylic alcohols.


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