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Along with promising devices, by utilizing the understanding of the chalcogen complexation, a new method for CuInSe2 film fabrication was developed with the addition of selenide precursors and elemental selenium which enabled first-ever fabrication of a solution-processed CuInSe2 thin film with thickness above 2 μm and absence of any secondary fine-grain layer.
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CuInSe2 thin films were deposited on ITO glass substrate by one-step electrochemical deposition (ECD) method without and with complexing agents like tetramethyl ammonium hydroxide (TMAH) and triethanolamine (TEA) at different temperatures.
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Along with promising devices, by utilizing the understanding of the chalcogen complexation, a new method for CuInSe2 film fabrication was developed with the addition of selenide precursors and elemental selenium which enabled first-ever fabrication of a solution-processed CuInSe2 thin film with thickness above 2 μm and absence of any secondary fine-grain layer.
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CuInSe2 thin films were deposited on ITO glass substrate by one-step electrochemical deposition (ECD) method without and with complexing agents like tetramethyl ammonium hydroxide (TMAH) and triethanolamine (TEA) at different temperatures.
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Variable magnetic field Hall effect measurements were used to characterize CuInSe2 thin films fabricated through solution processing.
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Initially, near stoichiometric CuInSe2 thin films of [Cu/In] ratio ∼1.
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This study is the first to report reversible oxidation of grain boundaries in CuInSe2 thin films.
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Here, we show by in situ synchrotron X-ray diffraction during annealing of Cu-poor CuInSe2 thin films that stacking faults can be strongly reduced through annealing, without passing through a Cu-rich film composition.
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CuInSe2 thin films are very important semiconductor material for solar cell applications because of chemical stability, direct band gap and high optical absorption coefficient.
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CuInSe2 thin films are very important semiconductor material for solar cell applications because of chemical stability, direct band gap and high optical absorption coefficient.
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