Introduction to Crossover Reactions
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Crossover Reactions sentence examples within Polar Crossover Reactions
Radical–polar crossover reactions, that is, single-electron redox events allowing for the interconversion between radical and ionic intermediates, make it possible to connect radical and polar processes in the same synthetic transformation.
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To access uncharted chemical space, the adoption of photoredox catalysis in DELs, including Ni-catalyzed manifolds and radical/polar crossover reactions, has enabled the construction of novel structural scaffolds through regulated odd-electron intermediates.
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Crossover Reactions sentence examples within Frequent Crossover Reactions
An increase in the number of methyl substituents at the 2-position of the cyclic acetal improved the stability of the generated carbocation, which led to copolymerization with both frequent crossover reactions and at high polymerization rates.
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Lactic acid-derived 1,3-dioxolan-4-ones (DOLOs), which do not undergo cationic homopolymerization, were demonstrated to yield copolymers with oxiranes through a cationic copolymerization via frequent crossover reactions.
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Radical–polar crossover reactions, that is, single-electron redox events allowing for the interconversion between radical and ionic intermediates, make it possible to connect radical and polar processes in the same synthetic transformation.
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To access uncharted chemical space, the adoption of photoredox catalysis in DELs, including Ni-catalyzed manifolds and radical/polar crossover reactions, has enabled the construction of novel structural scaffolds through regulated odd-electron intermediates.
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Taking advantage of the stabilization effect of a silyl group, with a bulky but positive nature, a range of less investigated organosilanes could be generally accessed via photoredox-catalysed radical-polar crossover reactions.
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An increase in the number of methyl substituents at the 2-position of the cyclic acetal improved the stability of the generated carbocation, which led to copolymerization with both frequent crossover reactions and at high polymerization rates.
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This proposal has been proven by germylene-exchange crossover reactions in which free 1tBu and [M(CO)5 {Ge(tBu2 bzamC(OEt)Me)CH2 SiMe3 }] (5'M ; M=Cr, W) were formed when complexes 3M were treated at room temperature with the germylene Ge(tBu2 bzam)CH2 SiMe3 (1tmsm ).
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Lactic acid-derived 1,3-dioxolan-4-ones (DOLOs), which do not undergo cationic homopolymerization, were demonstrated to yield copolymers with oxiranes through a cationic copolymerization via frequent crossover reactions.
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In the 2nd part, "radical-metal crossover reactions", metal centered radical species and more generally longer-lived transition metal complexes able to react with radicals are discussed - a field that has flourished recently.
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