Introduction to 18 Crown 6 Ether

Carboxyl Fe3O4 nanoparticles ([email protected]) modified with 18-Crown-6 ether functional groups have been prepared via an amidation reaction and used as bifunctional adsorbent for Cs+.

Ion sensing properties of dibenzo18-crown-6 ether and interactions between multi- walled carbon nanotubes and dibenzo18-crown-6 ether are stated as responsible for enhancing photocurrent intensity during photoelectrochemical measurements.

5 mM 18-crown-6 ether by a single injection.

In this work, we investigate the aqueous proton selective conduction behavior across graphene-embedded 18-crown-6 ether pores using extensive ReaxFF molecular dynamics simulations.

Three new fluorescent enantiopure pyridino-18-crown-6 ethers containing a benzothiazole unit were prepared, and the enantiomeric discrimination of these sensor molecules toward the hydrogen perchlorate salts of 1-phenylethylamine, 1-(1-naphthyl)ethylamine, phenylglycine methyl ester and phenylalanine methyl ester was studied in acetonitrile by fluorescence spectroscopy.

We have determined the microfriction correction factors for series of small molecules (ranging in size from ethanol to 18-crown-6 ether and tetrakis(trimethylsilyl)silane) in a dilute hexane solution by a concerted use of the NMR diffusion measurements and the molecular hydrodynamic calculations.

Co-polymerization of norbornene grafted pyridino-18-crown-6 ether (7) with fluorine-functionalized norbornenes (10 and 11) results in polymers bearing host molecular moieties.

We employed the Mg-sensitive fluorescent dye named DCHQ5, a derivative of diaza-18-crown-6 ethers appended with two 8-hydroxyquinoline groups, to perform fluorescence lifetime imaging in control and Mg deprived SaOS-2 live cells, which contain different concentrations of magnesium.

Here we extensively evaluated the impact of several advances to the WE strategy on the efficiency of computing association and dissociation rate constants (kon, koff) as well as binding affinities (KD) for a set of benchmark systems, listed in order of increasing timescales of molecular association/dissociation processes: methane/methane, Na+/Cl-, and K+/18-crown-6 ether.

A series of polyhalogenated hetarylamines and their co-crystals with 18-crown-6 ether was used to reveal the effect of co-crystallization on the supramolecular structure and fluorescence properties as well as the relationship between these characteristics and peculiarities of the hetarylamine chemical structure (α- or γ-position of the NH2 group, number of Cl and F substituents, pyridine or quinoline framework, presence of a fluorophore fragment).

The nanopores contain walls decorated with 4′-aminobenzo-18-crown-6 ether and single-stranded DNA (ssDNA) molecules located at one pore entrance.

The objective of this work was the exploration of the effect of the second coordination sphere on the magnetic properties of [Ln(NO3)3(H2O)3]·(18C6) (Ln = Dy (1) and Er (2)) compounds comprising co-crystallized 18-crown-6 ethers.

Mono- and dianions of 2-tert-butyl-3a2-azapentabenzo[bc,ef,hi,kl,no]corannulene (1a) were synthesized by chemical reduction with sodium and cesium metals and crystallized as the corresponding salts in the presence of 18-crown-6 ether.

This chemistry is illustrated with 2-(hydroxymethyl-3,5-diiodobenzoate)-18-crown-6 ether, which attaches noncovalently to protonated primary amines in peptides and proteins.

Additionally, the proposed system was applied to compare the performances of three popular potassium ionophores: Valinomycin, dibenzo-18-crown-6 ether (DB18C6) and Potassium Ionophore III (BME-44).

In this work, two new NDI-crown ether cation sensors (aza-15-crown-5 ether NDI, 5, and aza-18-crown-6 ether NDI, 6) have been synthesised and changes in UV-visible and fluorescence spectra upon addition of various cations investigated.

We consider 18-crown-6 ether (18C6) as an additive, which has previously been shown to differentiate between the zeolite EMC-2 (EMT) and faujasite (FAU) frameworks.

Methods The electrophoretic separation was carried out in a running buffer made of 5 mM imidazole, 5 mM 18-crown-6 ether and 6 mM d,l-α-hydroxybutyric acid (HIBA).

To generate a pure solution of potassium from the leach liquor containing K, Ca and Na, it was selectively extracted from leach liquor by using dibenzo-18-crown-6 ether as extractant and m-cresol as diluent.

The synthesis of the (R,R) and (S,S) enantiomers of a new enantiopure monophospha-18-crown-6 ether (1), which contains an anthracene fluorophore unit and methyl groups at its stereogenic centers, was accomplished.

Here, we have used high-pressure powder X-ray diffraction to study the three zeolites: Na-X, RHO and ZK-5, which can all be prepared using 18-crown-6 ether as an organic additive.

Since addition of 18-crown-6 ether did not affect the reaction rates, the measured rate constants correspond to the reactions of the non-paired carbanions.

One particularly promising candidate, an anthracene substituted aza-18-crown-6 ether, is shown to respond in the dry phase with almost no intrinsic background from the unchelated state, and to be amenable to barium sensing through fluorescence microscopy.

Here, the cases for Mz+ = Li+-Cs+, Cd2+, and Pb2+ and L = 18-crown-6 ether (18C6) and benzo-18C6 (B18C6) with A? = Cl?-I? and picrate ion (Pic?) were examined.

Complexes of 18-crown-6 ether (18C6) with four protonated amino acids (AAs) are examined using infrared multiple photon dissociation (IRMPD) action spectroscopy utilizing light generated by the infrared free electron laser at the Centre Laser Infrarouge d'Orsay (CLIO).